Abstract
The nanocrystalline ZnO thin films were deposited by pulsed laser deposition on quartz and i-Si (100) substrates at different substrate temperatures (473 K–873 K) and at different mixed partial pressures (0.05, 0.01, and 0.5 mbar) of Ar+O2. The structural studies from XRD spectra reveals that the films deposited at 0.05 mbar and at lower substrate temperatures were c-axis oriented with predominant (002) crystallographic orientation. At 873 K along with (002) orientation, additional crystallographic orientations were also observed in case of films deposited at 0.01 and 0.5 mbar pressures. The composition of Zinc and Oxygen in ZnO films from EDAX reveals that the films deposited at lower partial pressures were have high at.% of O2 whereas higher partial pressures and substrate temperatures had high at.% Zn. The surface microstructure of the films show that the films deposited at lower partial pressures (0.05 mbar ) and at lower substrate temperatures (473 K) were found to have nanoparticles of size 15 nm where as films deposited at 873 K have nanorods. The length of these nanorods increases with increasing Ar+O2 partial pressure to 0.5 mbar. The optical energy gap of the film deposited at lower partial pressure and substrate temperature was 3.3 eV and decrease with the increase of substrate temperatures. The films deposited at 0.5 mbar and at 873 K emitted an intense luminescence at a wavelength of 390 nm. The measured thickness of deposited films by spectroscopic ellipsometry is around 456 nm.
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Acknowledgements
The authors are thankful to A.K. Ray Chaudhari, Director, SNBNCBS, Kolkata, India, for allowing us to do SEM measurements and the technicians, Piyali Bose, Pallab, and Shaktinath Das for their valuable help during this course of work. The corresponding author is thankful to Professor K. Krishna Murthy, Director, P.G. Centre, P.B. Siddartha College of Arts and Science, Vijayawada, Andhra Pradesh, India, for sanction of on duty leave for few days.
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Srinivasarao, K., Rajinikanth, B., Pandurangarao, K. et al. Physical investigations on pulsed laser deposited nanocrystalline ZnO thin films. Appl. Phys. A 108, 247–254 (2012). https://doi.org/10.1007/s00339-012-6895-5
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DOI: https://doi.org/10.1007/s00339-012-6895-5