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Review on the properties of the ferrorelaxor polymers and some new recent developments

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Abstract

It has been found that by introducing defects into the P(VDF-TrFE) copolymers, it is possible to convert the polymer from a normal ferroelectric to a relaxor ferroelectric. A new class of ferroelectric polymers, i.e., the terpolymers of P(VDF-TrFE-CFE) or of P(VDF-TrFE-CTFE), was developed from the normal ferroelectric PVDF-TrFE polymer by employing proper defect modifications which eliminate detrimental effects associated with a normal first order F–P transition while maintaining high material responses. Relevant studies show that this class of electroactive polymers offers unique properties in comparison with other ferroelectric polymers. The syntheses of these relaxor ferroelectric polymers have been done by a combination of the suspension polymerization process and an oxygen-activated initiator at a temperature of 40°C. Films from cast solution can be made in different lengths and thicknesses. Stretching of these films increases the performance as well as the mechanical properties. These relaxor-ferroelectric terpolymers P(VDF-TrFE-CFE), P(VDF-TrFE-CTFE) are multifunctional, i.e., electrostrictive material, dielectric for electric energy storage. The terpolymer exhibits high electrostrictive strain (>7%) with relatively high modulus (>0.4 GPa). Examples of devices applications using unimorphe systems are presented. Micropump and Optical device concerning a liquid-filled varifocal lens on a chip are described.

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References

  1. G.A. Samara, F. Bauer, The effects of pressure on the β molecular relaxation and phase transitions of the ferroelectric copolymer P(VDF0.7TrFe0.3). Ferroelectrics 135, 385 (1992) and references therein

    Article  Google Scholar 

  2. H.S. Nalwa, Ferroelectric Polymers (Dekker, New York, 1995)

    Google Scholar 

  3. Q.M. Zhang, J. Zhao, T. Shrout, N. Kim, L.E. Cross, A. Amin, B.M. Kulwicki, Characteristics of the electromechanical response and polarization of electric field biased ferroelectrics. J. Appl. Phys. 77, 2549–2555 (1995)

    Article  ADS  Google Scholar 

  4. Q.M. Zhang, V. Bharti, X. Zhao, Giant electrostriction and relaxor ferroelectric behavior in electron-irradiated poly(vinylidene fluoride-trifluoroethylene) copolymer. Science 280, 2101–2104 (1998)

    Article  ADS  Google Scholar 

  5. F. Bauer, E. Fousson, Q.M. Zhang, L.M. Lee, Ferroelectric copolymers and terpolymers for electrostrictors: synthesis and properties. IEEE Trans. Dielectr. Electr. Insul. 20, 293–297 (2004)

    Article  Google Scholar 

  6. F. Xia, Z.-Y. Cheng, H. Xu, Q.M. Zhang, G. Kavarnos, R. Ting, G. Abdul-Sedat, K.D. Belfield, High electromechanical responses in terpolymer of poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene). Adv. Mater. 14, 1574–1577 (2002)

    Article  Google Scholar 

  7. C. Huang, R. Klein, H. Li, Q.M. Zhang, F. Bauer, Z.-Y. Cheng, Poly(vinylidene floride-trifluoroethylene) based high performance electroactive polymers. IEEE Trans. Dielectr. Electr. Insul. 20, 299–311 (2004)

    Article  Google Scholar 

  8. R. Klein, F. Xia, Q.M. Zhang, Influence of composition on ferroelectric properties of P(VDF-TrFE-CFE) terpolymers. Appl. Phys. 97, 94–105 (2005)

    Google Scholar 

  9. A. Petchsuk, Ferroelectric terpolymer, based on semicrystalline VDF/TRFE/CHLORO-containing termonomers: synthesis, electrical properties, and functionalization reactions. MS Thesis, The Pennsylvania State University, 2003

  10. V. Bobnar, B. Vodopivec, M. Kosec, A. Levstik, B. Hilczer, Q.M. Zhang, Dielectric properties of relaxor-like vinylidene fluoride-trifluoroethylene-base electroactive polymers. Macromolecules 36, 4436–4442 (2003)

    Article  ADS  Google Scholar 

  11. M.A. Bachmann, J.B. Lando, A reexamination of the crystal structure of phase II of poly(vinylidene fluoride). Macromolecules 14, 40 (1981)

    Article  ADS  Google Scholar 

  12. Q.M. Zhang C. Huang, F. Xia, J. Su, Electrostrictive polymers for mechanical energy harvesting, in Electroactive Polymer Actuators as Artificial Muscles, ed. by Y. Bar-Cohen (SPIE Optical Engineering Press, Bellingham, 2004), Chap. 4

    Google Scholar 

  13. F. Bauer, E. Fousson, Q.M. Zhang, Recent advances in highly electrostrictive P(VDF-TrFE-CFE) terpolymers. IEEE Trans. Dielectr. Electr. Insul. 13, 1149–1154 (2006)

    Google Scholar 

  14. F. Bauer et al., Brevet 05 08050, US Patent 2007/0167590 A1

  15. L.E. Cross, Ferroelectric ceramics: Materials and applications issues. Ceram. Trans. 68, 15 (1996)

    Google Scholar 

  16. S.E. Park, T. Shrout, Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals. J. Appl. Phys. 82, 1804 (1997)

    Article  ADS  Google Scholar 

  17. F. Xia, S. Tadigadapa, Q.M. Zhang, Electroactive polymer based microfluidic pump. Sens. Actuators A 125, 346–352 (2006)

    Article  Google Scholar 

  18. S.T. Choi, J.Y. Lee, J.O. Kwon, S. Lee, W. Kim, Liquid-filled varifocal lens on a chip, in MOEMS and Miniaturized Systems VIII. SPIE Photonics West Proceedings, vol. 7208 (Society of Photographic Instrumentation Engineers, Bellingham, 2009), 72080P

    Google Scholar 

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Acknowledgements

Without the exceptional work and help of Professor Qiming Zhang, this paper could not be written. These new applications of the terpolymer could not be presented too.

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  1. Piézotech S.A.S., 9, rue de Colmar, 68220, Hésingue, France

    François Bauer

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  1. François Bauer
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Correspondence to François Bauer.

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Dedicated to Professor Reimund Gerhard.

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Bauer, F. Review on the properties of the ferrorelaxor polymers and some new recent developments. Appl. Phys. A 107, 567–573 (2012). https://doi.org/10.1007/s00339-012-6831-8

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  • DOI: https://doi.org/10.1007/s00339-012-6831-8

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