Skip to main content
Log in

Highly oriented La2/3Ca1/3MnO3 films grown on silicon-on-insulator substrates by pulsed laser deposition

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

High quality La2/3Ca1/3MnO4(LCMO) thin films have been deposited on silicon-on-insulator (SOI) substrates only buffered by yt tria-stabilized zirconia (YSZ) by using the pulsed laser deposition (PLD) technique. The results obtained from X-ray diffraction (XRD), reflection high energy electron diffraction (RHEED), scanning electron microscopy (SEM) and magnetization investigations indicate that the LCMO films are highly oriented both in-plane and out-of-plane. The Curie temperature T c is close to 260 K and the insulator–metal (I–M) transition appears around 220 K. The conducting mechanism at low temperatures is dominated by the electron–magnon scattering. A tensile stress from the film–substrate lattice mismatch results in magnetic ‘easy axes’ in the film plane and the magnetic anisotropy energy increases with cooling. A maximum magnetoresistance (MR) is observed near 190 K, with the external magnetic field either parallel or vertical to the LCMO film plane. Moreover, the large intrinsic high-field magnetoresistance (HFMR) and the very small extrinsic low-field magnetoresistance (LFMR) again reveal that the LCMO films on SOI substrates are highly oriented thin films of good crystallinity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Imada, A. Fujimori, Y. Tokura, Metal-insulator transitions. Rev. Mod. Phys. 70, 1039–1263 (1998)

    Article  ADS  Google Scholar 

  2. S. Jin, T.H. Tiefel, M. McCormack, R.A. Fastnacht, L.H. Chen, Thousandfold change in resistivity in magnetoresistive La–Ca–Mn–O films. Science 264, 413–415 (1994)

    Article  ADS  Google Scholar 

  3. P. Schiffer, A.P. Ramirez, W. Bao, S.-W. Cheong, Low temperature magnetoresistance and the magnetic phase diagram of La1−x Ca x MnO3. Phys. Rev. Lett. 75, 3336–3339 (1995)

    Article  ADS  Google Scholar 

  4. T.L. Chen, X.M. Li, R. Dong, Q. Wang, L.D. Chen, Field-induced resistance-switching of La0.7Ca0.3MnO3−δ films epitaxially grown on Ir/MgO buffered Si (001) substrates. Thin Solid Films 488, 98–102 (2005)

    Article  ADS  Google Scholar 

  5. C. Zener, Interaction between the d-shells in the transition metals. II. Ferromagnetic compounds of manganese with perovskite structure. Phys. Rev. 82, 403–405 (1951)

    Article  ADS  Google Scholar 

  6. G. Campillo, A. Berger, J. Osorio, J.E. Pearson, S.D. Bader, E. Baca, P. Prieto, Substrate dependence of magnetic properties of La0.67Ca0.33MnO3 films. J. Magn. Magn. Mater. 237, 61–68 (2001)

    Article  ADS  Google Scholar 

  7. C. Kwon, M.C. Robson, K.-C. Kim, J.Y. Gu, S.E. Lofland, S.M. Bhagat, Z. Trajanovic, M. Rajeswari, T. Venkatesan, A.R. Kratz, R.D. Gomez, R. Ramesh, Stress-induced effects in epitaxial (La0.7Sr0.3)MnO3 films. J. Magn. Magn. Mater. 172, 229–236 (1997)

    Article  ADS  Google Scholar 

  8. D. Rubi, S. Duhalde, M.C. Terzzoli, G. Leyva, G. Polla, P. Levy, F. Parisi, R.R. Urbano, Structural and electrical characterization of La0.5Ca0.5MnO3 thin films grown by pulsed laser deposition. Physica B 320, 86–89 (2002)

    Article  ADS  Google Scholar 

  9. Q. Huang, A. Santoro, J.W. Lynn, R.W. Erwin, J.A. Borchers, J.L. Peng, K. Ghosh, R.L. Greene, Structure and magnetic order in La1−x Ca x MnO3 (0<x≤0.33). Phys. Rev. B 58, 2684–2691 (1998)

    Article  ADS  Google Scholar 

  10. R. Hull, Properties of Crystalline Silicon (INSPEC, London, 1999)

    Google Scholar 

  11. D. Kumar, S. Chattopadhyay, W.M. Gilmore, C.B. Lee, J. Sankar, A. Kvit, A.K. Sharma, J. Narayan, S.V. Pietambaram, R.K. Singh, Structural and magnetoresistance properties of La2/3Ca1/3MnO3 thin films on buffered silicon substrates. Appl. Phys. Lett. 78, 1098–1100 (2001)

    Article  ADS  Google Scholar 

  12. P.J. Kung, D.B. Fenner, D.M. Potrepka, J.I. Budnick, Growth and characterization of magnetoresistive La–Ca–Mn–O films on Si(100) and Si(111) substrates. Appl. Phys. Lett. 69, 427–429 (1996)

    Article  ADS  Google Scholar 

  13. W. Zhang, W. Boyd, M. Elliot, W. Herrenden-Harkerand, The effects of oxygen content on the magnetoresistive behavior in La–Ca–Mn–O films grown on Si. Appl. Phys. Lett. 69, 3929–3931 (1996)

    Article  ADS  Google Scholar 

  14. A.R. Powell, S.S. Iyer, F.K. LeGoues, New approach to the growth of low dislocation relaxed SiGe material. Appl. Phys. Lett. 64, 1856–1858 (1994)

    Article  ADS  Google Scholar 

  15. L. Kang, Z.F. Di, S.Z. Yang, Y.J. Feng, P.H. Wu, Epitaxial growth of YBa2Cu3O7/CeO2/YSZ thin films on silicon-on-insulator substrates. Supercond. Sci. Technol. 15, 320–323 (2002)

    Article  ADS  Google Scholar 

  16. J. Li, P. Wang, J.Y. Xiang, X.H. Zhu, W. Peng, Y.F. Chen, D.N. Zheng, Z.W. Li, Large low-field magnetoresistance observed in twinned La2/3Ca1/3MnO3 thin films epitaxially grown on yttria-stabilized zirconia-buffered silicon on insulator substrates. Appl. Phys. Lett. 86, 112514 (2005)

    Article  ADS  Google Scholar 

  17. J. Li, P. Wang, W. Peng, J.Y. Xiang, X.H. Zhu, Y.F. Chen, F.B. Wang, D.N. Zheng, Growth and characterization of La2/3Ca1/3MnO3 thin films on ‘silicon on insulator’ substrates. Appl. Phys. A 83, 313–319 (2006)

    Article  ADS  Google Scholar 

  18. P. Wang, J. Li, W. Peng, K. Chen, P.L. Lang, J.Y. Xiang, Y.F. Chen, X.P. Xu, H.Y. Tian, D.N. Zheng, Epitaxial growth of YBa2Cu3O7−δ thin films on silicon-on-insulator substrates by pulsed laser deposition. Supercond. Sci. Technol. 17, 804–807 (2004)

    Article  ADS  Google Scholar 

  19. P. Wang, J. Li, W. Peng, Y.F. Chen, D.N. Zheng, Investigation of the strain relaxation and ageing effect of YBa2Cu3O7−δ thin films grown on silicon-on-insulator substrates with yttria-stabilized zirconia buffer layers. Supercond. Sci. Technol. 19, 51–56 (2006)

    Article  ADS  Google Scholar 

  20. K.H. Wong, Y.S. Leung, Heteroepitaxial growth of La0.7Ca0.3MnO3/SrTiO3/TiN/Si by pulsed laser deposition. Thin Solid Films 354, 55–58 (1999)

    Article  ADS  Google Scholar 

  21. J. Kawashima, Y. Yamada, I. Hirabayashi, Critical thickness and effective thermal expansion coefficient of YBCO crystalline film. Physica C 306, 114–118 (1998)

    Article  ADS  Google Scholar 

  22. J.-H. Kim, S.I. Khartsev, A.M. Grishin, Epitaxial colossal magnetoresistive La0.67(Sr,Ca)0.33MnO3 films on Si. Appl. Phys. Lett. 82, 4295–4297 (2003)

    Article  ADS  Google Scholar 

  23. K. Kubo, N. Ohata, A quantum theory of double exchange. I. J. Phys. Soc. Jpn. 33, 21–32 (1972)

    Article  ADS  Google Scholar 

  24. E.S. Vlakhov, R.A. Chakalov, R.I. Chakalova, K.A. Nenkov, K. Dörr, A. Handstein, K.-H. Müller, Influence of the substrate on growth and magnetoresistance of La0.7Ca0.3MnO z thin films deposited by magnetron sputtering. J. Appl. Phys. 83, 2152–2157 (1998)

    Article  ADS  Google Scholar 

  25. W. Zhang, X. Wang, M. Elliott, I.W. Boyd, Stress effect and enhanced magnetoresistance in La0.67Ca0.33MnO3−δ films. Phys. Rev. B 58, 14143–14146 (1998)

    Article  ADS  Google Scholar 

  26. J. O’Donnell, M.S. Rzchowski, J.N. Eckstein, I. Bozovic, Magnetoelastic coupling and magnetic anisotropy in La0.67Ca0.33MnO3 films. Appl. Phys. Lett. 72, 1775–1777 (1998)

    Article  ADS  Google Scholar 

  27. X.W. Wu, M.S. Rzchowski, H.S. Wang, Q. Li, Strain-induced magnetic properties of Pr0.67Sr0.33MnO3 thin films. Phys. Rev. B 61, 501–505 (2000)

    Article  ADS  Google Scholar 

  28. N.D. Mathur, G. Burnell, S.P. Isaac, T.J. Jackson, B.S. Teo, J.L. MacManus Driscoll, L.F. Cohen, J.E. Evetts, M.G. Blamire, Large low-field magnetoresistance in La0.7Ca0.3MnO3 induced by artificial grain boundaries. Nature 387, 266–268 (1997)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. N. Zheng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, P., Li, J., Lang, P.L. et al. Highly oriented La2/3Ca1/3MnO3 films grown on silicon-on-insulator substrates by pulsed laser deposition. Appl. Phys. A 102, 449–455 (2011). https://doi.org/10.1007/s00339-010-6174-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-010-6174-2

Keywords

Navigation