Applied Physics A

, Volume 104, Issue 1, pp 219–228 | Cite as

(Chicken feathers keratin)/polyurethane membranes

  • V. Saucedo-Rivalcoba
  • A. L. Martínez-Hernández
  • G. Martínez-Barrera
  • C. Velasco-Santos
  • V. M. Castaño
Article

Abstract

Actually, chicken feathers are considered as waste from the poultry industry; however, 90% of feather structure is constituted by a protein called keratin. In this research, the properties of feather keratin and polyurethane are combined in order to synthesize hybrid synthetic–natural membranes. Both polymers are linked by urethane bonds which are similar to peptide bonds found in proteins. Keratin is incorporated onto the polyurethane matrix by dissolving protein in a salt solution (urea and 2-mercaptoethanol) at different concentrations: 11, 13, 15, 17, 19, and 21% (w/w). In order to know the effect of urea on membranes, keratin is incorporated to polyurethane in two ways; as keratin salt solution and after dialyzing. Both membrane types were characterized by Scanning Electron Microscopy (SEM) to observe their morphologic changes. Fourier Transformed Infrared Spectroscopy (FT-IR), Termogravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) were used to study membrane structures. Results show that keratin is grafted in polyurethane and, therefore, there is an influence of amino acids through the amino and carboxylic groups (NH and COOH) into the synthetic polymer structure. According with characterization results, the obtained membranes are functional materials that can be useful in diverse applications, among them the separation process can be emphasized.

List of abbreviation and symbols

%

percent(s)

% (w/w)

percent (weight/weight)

FT-IR

Fourier transform infrared

TGA

thermogravimetric analysis

DSC

differential scanning calorimetry

PU

polyurethane

TDI

Toluene diisocyanate

PPG

poly(propilenglycol)

M

molar

mM

milimolar

°C

degrees Celsius

kV

kilovolts

mBar

milibar

nm

nanometer(s)

°C/min

degrees Celsius per minute

μm

micrometer(s)

ATR

attenued total reflectance

PUcoKES

polyurethane keratin salt

PUcoKED

polyurethane dialyzed keratin

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Copyright information

© Springer-Verlag 2010

Authors and Affiliations

  • V. Saucedo-Rivalcoba
    • 1
    • 3
  • A. L. Martínez-Hernández
    • 2
  • G. Martínez-Barrera
    • 1
  • C. Velasco-Santos
    • 2
  • V. M. Castaño
    • 3
  1. 1.Laboratorio de Investigación y Desarrollo de Materiales Avanzados (LIDMA), Facultad de QuímicaUniversidad Autónoma del Estado de MéxicoTolucaMéxico
  2. 2.Ingeniería en Materiales, Departamento de Metal-MecánicaInstituto Tecnológico de QuerétaroQuerétaroMéxico
  3. 3.Centro de Física Aplicada y Tecnología AvanzadaUniversidad Nacional Autónoma de MéxicoQuerétaroMéxico

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