Abstract
Motivated by the successful use of strontium titanate with different doping metals for memory cells on the basis of resistive switching and the recent findings on the major importance of oxygen vacancy redistribution in this compound, the present work shows the possibility of a non-volatile resistance change memory based on vacancy-doped SrTiO3. The formation of corresponding metal/SrTiO3−δ junctions (δ>0) in an electric field will be discussed as well as the switching between ohmic and Schottky-type contact behavior. A notable hysteresis in the current–voltage characteristics is used to carry out Write, Read, and Erase operations exemplifying the memory cell properties of such junctions. But whereas the electric field-induced formation of Schottky-type junctions is explainable by oxygen vacancy redistribution, the resistive switching needs to be discussed in terms of vacancies serving as electron trap states at the metal/oxide interface.
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B.J. Choi, D.S. Jeong, S.K. Kim, C. Rohde, S. Choi, J.H. Oh, H.J. Kim, C.S. Hwang, K. Szot, R. Waser, B. Reichenberg, S. Tiedke, Resistive switching mechanism of TiO2 thin films grown by atomic-layer deposition. J. Appl. Phys. 98, 033715 (2005)
A. Sawa, Resistive switching in transition metal oxides. Mater. Today 11, 28–36 (2008)
K. Szot, W. Speier, G. Bihlmayer, R. Waser, Switching the electrical resistance of individual dislocations in single-crystalline SrTiO3. Nat. Mater. 5, 312–320 (2006)
T. Fujii, M. Kawasaki, A. Sawa, H. Akoh, Y. Kawazoe, Y. Tokura, Hysteretic current–voltage characteristics and resistance switching at an epitaxial oxide Schottky junction SrRuO3/SrTi0.99Nb0.01O3. Appl. Phys. Lett. 86, 012107 (2005)
C. Park, Y. Seo, J. Jung, D.W. Kim, Electrode-dependent electrical properties of metal/Nb-doped SrTiO3 junctions. J. Appl. Phys. 103, 054106 (2008)
A. Beck, J.G. Bednorz, C. Gerber, C. Rossel, D. Widmer, Reproducible switching effect in thin oxide films for memory applications. Appl. Phys. Lett. 77, 139–141 (2000)
S.Q. Liu, N.J. Wu, A. Ignatiev, Electric-pulse-induced reversible resistance change effect in magnetoresistive films. Appl. Phys. Lett. 76, 2749–2751 (2000)
M. Hamaguchi, K. Aoyama, S. Asanuma, Y. Uesu, T. Katsufuji, Electric-field-induced resistance switching universally observed in transition-metal-oxide thin films. Appl. Phys. Lett. 88, 142508 (2006)
A. Baikalov, Y.Q. Wang, B. Shen, B. Lorenz, S. Tsui, Y.Y. Sun, Y.Y. Xue, C.W. Chu, Field-driven hysteretic and reversible resistive switch at the Ag-Pr0.7Ca0.3MnO3 interface. Appl. Phys. Lett. 83, 957–959 (2003)
S.H. Jeon, B.H. Park, J. Lee, B. Lee, S. Han, First-principles modeling of resistance switching in perovskite oxide material. Appl. Phys. Lett. 89, 042904 (2006)
M. Janousch, G.I. Meijer, U. Staub, B. Delley, S.F. Karg, B.P. Andreasson, Role of oxygen vacancies in Cr-doped SrTiO3 for resistance-change memory. Adv. Mater. 19, 2232–2232 (2007)
K. Szot, R. Dittmann, W. Speier, R. Waser, Nanoscale resistive switching in SrTiO3 thin films. Phys. Status Solidi (RRL) 1, R86–R88 (2007)
S.F. Alvarado, F. La Mattina, J.G. Bednorz, Electroluminescence in SrTiO3:Cr single-crystal nonvolatile memory cells. Appl. Phys. A 89, 85–89 (2007)
Y. Watanabe, J.G. Bednorz, A. Bietsch, C. Gerber, D. Widmer, A. Beck, S.J. Wind, Current-driven insulator-conductor transition and nonvolatile memory in chromium-doped SrTiO3 single crystals. Appl. Phys. Lett. 78, 3738–3740 (2001)
D.D. Cuong, B. Lee, K.M. Choi, H.-S. Ahn, S. Han, J. Lee, Oxygen vacancy clustering and electron localization in oxygen-deficient SrTiO3: LDA + U study. Phys. Rev. Lett. 98, 115503 (2007)
J.H. Haeni, P. Irvin, W. Chang, R. Uecker, P. Reiche, Y.L. Li, S. Choudhury, W. Tian, M.E. Hawley, B. Craigo, A.K. Tagantsev, X.Q. Pan, S.K. Streiffer, L.Q. Chen, S.W. Kirchoefer, J. Levy, D.G. Schlom, Room-temperature ferroelectricity in strained SrTiO3. Nature 430, 758–761 (2004)
M. Itoh, R. Wang, Y. Inaguma, T. Yamaguchi, Y.-J. Shan, T. Nakamura, Ferroelectricity induced by oxygen isotope exchange in strontium titanate perovskite. Phys. Rev. Lett. 82, 3540–3543 (1999)
N.A. Pertsev, A.K. Tagantsev, N. Setter, Phase transitions and strain-induced ferroelectricity in SrTiO3 epitaxial thin films. Phys. Rev. B 61, R825–R829 (2000)
D. Choi, D. Lee, H. Sim, M. Chang, H. Hwang, Reversible resistive switching of SrTiO x thin films for nonvolatile memory applications. Appl. Phys. Lett. 88, 082904 (2006)
S. Karg, G.I. Meijer, D. Widmer, J.G. Bednorz, Electrical-stress-induced conductivity increase in SrTiO3 films. Appl. Phys. Lett. 89, 072106 (2006)
A. Inoue, K. Izumisawa, H. Uwe, Fabrication of Schottky Junction Between Au and SrTiO3. Jpn. J. Appl. Phys. 40, 3153–3156 (2001)
M.C. Ni, S.M. Guo, H.F. Tian, Y.G. Zhao, J.Q. Li, Resistive switching effect in SrTiO3−δ /Nb-doped SrTiO3 heterojunction. Appl. Phys. Lett. 91, 183502 (2007)
C. Park, D.-W. Kim, Interface resistance switching characteristics of metal/Nb-doped SrTiO3 junctions. J. Korean Phys. Soc. 50, 1294–1297 (2007)
T. Shimizu, H. Okushi, Intrinsic electrical properties of Au/SrTiO3 Schottky junctions. J. Appl. Phys. 85, 7244–7251 (1999)
J.R. Contreras, H. Kohlstedt, U. Poppe, R. Waser, C. Buchal, N.A. Pertsev, Resistive switching in metal–ferroelectric–metal junctions. Appl. Phys. Lett. 83, 4595–4597 (2003)
R. Oligschlaeger, R. Waser, R. Meyer, S. Karthäuser, R. Dittmann, Resistive switching and data reliability of epitaxial (Ba,Sr)TiO3 thin films. Appl. Phys. Lett. 88, 042901 (2006)
A. Sawa, T. Fujii, M. Kawasaki, Y. Tokura, Hysteretic current–voltage characteristics and resistance switching at a rectifying Ti/Pr0.7Ca0.3MnO3 interface. Appl. Phys. Lett. 85, 4073–4075 (2004)
S. Tsui, A. Baikalov, J. Cmaidalka, Y.Y. Sun, Y.Q. Wang, Y.Y. Xue, C.W. Chu, L. Chen, A.J. Jacobson, Field-induced resistive switching in metal-oxide interfaces. Appl. Phys. Lett. 85, 317–319 (2004)
Q. Fu, T. Wagner, Interaction of nanostructured metal overlayers with oxide surfaces. Surf. Sci. Rep. 62, 431–498 (2007)
J. Blanc, D.L. Staebler, Electrocoloration in SrTiO3: vacancy drift and oxidation–reduction of transition metals. Phys. Rev. B 4, 3548–3557 (1971)
D.C. Meyer, A.A. Levin, S. Bayer, A. Gorbunov, W. Pompe, P. Paufler, An electrical field-induced structural effect in strontium titanate at room temperature. Appl. Phys. A 80, 515–522 (2005)
M. Bobeth, N. Farag, A.A. Levin, D.C. Meyer, W. Pompe, A.E. Romanov, Reversible electric field-induced structure changes in the near-surface region of strontium titanate. J. Ceram. Soc. Jpn. 114, 1029–1037 (2006)
D.C. Meyer, A.A. Levin, T. Leisegang, E. Gutmann, P. Paufler, M. Reibold, W. Pompe, Reversible tuning of a series of intergrowth phases of the Ruddlesden-Popper type SrO(SrTiO3) n in an (001) SrTiO3 single-crystalline plate by an external electric field and its potential use for adaptive X-ray optics. Appl. Phys. A 84, 31–35 (2006)
H. Stöcker, M. Zschornak, T. Leisegang, I. Shakhverdova, S. Gemming, D.C. Meyer, Electric field mediated switching of mechanical properties of strontium titanate at room temperature. Cryst. Res. Technol. 45, 13–17 (2009)
T. Leisegang, H. Stöcker, A.A. Levin, T. Weißbach, M. Zschornak, E. Gutmann, K. Rickers, S. Gemming, D.C. Meyer, Switching Ti valence in SrTiO3 by a dc electric field. Phys. Rev. Lett. 102, 087601 (2009)
M. Mrovec, J.M. Albina, B. Meyer, C. Elsässer, Schottky barriers at transition-metal/SrTiO3 (001) interfaces. Phys. Rev. B 79, 245121 (2009)
K. Szot, M. Pawelczyk, J. Herion, C. Freiburg, J. Albers, R. Waser, J. Hulliger, J. Kwapulinski, J. Dec, Nature of the surface layer in ABO3-type perovskites at elevated temperatures. Appl. Phys. A 62, 335–343 (1996)
M.J. Rozenberg, I.H. Inoue, M.J. Sánchez, Nonvolatile memory with multilevel switching: a basic model. Phys. Rev. Lett. 92, 178302 (2004)
C. Vamala, S. Manandhar, J. Kelber, Pt interactions with annealed and chemically-etched Nb-doped SrTiO3 (001) surfaces: Metal/oxide surface chemical effects on band bending behavior. Surf. Sci. 603, 33–39 (2009)
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Stöcker, H., Zschornak, M., Seibt, J. et al. Formation of Schottky-type metal/SrTiO3 junctions and their resistive properties. Appl. Phys. A 100, 437–445 (2010). https://doi.org/10.1007/s00339-010-5848-0
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DOI: https://doi.org/10.1007/s00339-010-5848-0