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Ultra-low dielectric performance of polymer electrospun nanofiber mats

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Abstract

Nanofiber membranes of five different kinds of polymers have been prepared. The results of dielectric constant (k) measurements reveal that k-values of the polymers can be reduced dramatically by the electrospinning technique. The effects of the polymer types, the densities of the membranes, and the diameters of the fibers on the reducing of k-values have been investigated. It turns out that the unique microporous structures in the electrospun fiber films play an important role in decreasing the k-values of the polymer films. We anticipate that such a facile and general method may be applied to prepare ultra-low-dielectric-constant materials with potential application in the field of microelectronics.

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References

  1. M. Ree, J. Yoon, K. Heo, J. Mater. Chem. 16, 685 (2006)

    Article  Google Scholar 

  2. K. Tsuchiya, H. Ishii, Y. Shibasaki, H. Ando, M. Ueda, Macromolecules 37, 4794 (2004)

    Article  ADS  Google Scholar 

  3. R. Ishii, T. Ikeda, T. Itoh, T. Ebina, T. Yokoyama, T. Hanaoka, F. Mizukami, J. Mater. Chem. 16, 4035 (2006)

    Article  Google Scholar 

  4. T.H. Lee, J.H. Kim, B.S. Bae, J. Mater. Chem. 16, 1657 (2006)

    Article  Google Scholar 

  5. G.D. Fu, W.C. Wang, S. Li, E.T. Kang, K.G. Neoh, W.T. Tseng, D.J. Liaw, J. Mater. Chem. 13, 2150 (2003)

    Article  Google Scholar 

  6. H.J. Treichel, J. Electron. Mater. 30, 290 (2001)

    Article  ADS  Google Scholar 

  7. Y.Q. Huang, J. Economy, Macromolecules 39, 1850 (2006)

    Article  ADS  Google Scholar 

  8. G.D. Fu, Z. Shang, L. Hong, E.T. Kang, K.G. Neoh, Adv. Mater. 17, 2622 (2005)

    Article  Google Scholar 

  9. S. Li, Z.J. Li, Y.S. Yan, Adv. Mater. 15, 1528 (2003)

    Article  Google Scholar 

  10. Q.R. Huang, W. Volksen, E. Huang, M. Toney, C.W. Frank, R.D. Miller, Chem. Mater. 14, 3676 (2002)

    Article  Google Scholar 

  11. B. Krause, G.H. Koops, N.F.A. van der Vegt, M. Wessling, M. Wubbenhorst, J. van Turnhout, Adv. Mater. 14, 1041 (2002)

    Article  Google Scholar 

  12. C.M. Yang, A.T. Cho, F.M. Pan, T.G. Tsai, K.J. Chao, Adv. Mater. 13, 1099 (2001)

    Article  Google Scholar 

  13. S. Baskaran, J. Liu, K. Domansky, N. Kohler, X.H. Li, C. Coyle, G.E. Fryxell, S. Thevuthasan, R.E. Williford, Adv. Mater. 12, 291 (2000)

    Article  Google Scholar 

  14. S. Banerjee, G. Majer, M. Burger, Macromolecules 32, 4279 (1999)

    Article  ADS  Google Scholar 

  15. A.C. Misra, G. Tesoro, G. Hougham, S.M. Pendarkar, Polymer 33, 1078 (1992)

    Article  Google Scholar 

  16. T. Matsuura, M. Ishizawa, Y. Hasuda, S. Nishi, Macromolecules 25, 3540 (1992)

    Article  ADS  Google Scholar 

  17. S. Ando, T. Matsuura, S. Nishi, Polymer 33, 2934 (1992)

    Article  Google Scholar 

  18. B.J. Liu, W. Hu, C.H. Chen, Z.H. Jiang, W.J. Zhang, Z.W. Wu, Polym. Adv. Technol. 14, 221 (2003)

    Article  Google Scholar 

  19. B.D. Lee, Y.H. Park, Y.T. Hwang, W.T. Oh, J.H. Yoon, M.H. Ree, Nat. Mater. 4, 147 (2005)

    Article  ADS  Google Scholar 

  20. J.L. Hedrick, K.R. Carter, J.W. Labadie, R.D. Miller, W. Volksen, C.J. Hawker, D.Y. Yoon, T.P. Russell, J.E. McGrath, R.M. Briber, Adv. Polym. Sci. 141, 1 (1999)

    Article  Google Scholar 

  21. S. Mikoshiba, S. Hayase, J. Mater. Chem. 9, 591 (1999)

    Article  Google Scholar 

  22. S. Yang, P.A. Mirau, C.S. Pai, O. Nalamasu, E. Reichmanis, E.K. Lin, H.J. Lee, D.W. Gidley, J. Sun, Chem. Mater. 13, 2762 (2001)

    Article  Google Scholar 

  23. H.G. Chen, L. Xie, H.B. Lu, Y.L. Yang, J. Mater. Chem. 17, 1258 (2007)

    Article  Google Scholar 

  24. J.Y. Liu, Y. Min, J.Y. Chen, C. Wang, Macromol. Rapid Commun. 28, 215 (2007)

    Article  Google Scholar 

  25. A. Greiner, J.H. Wendorff, Angew. Chem. Int. Ed. 46, 5670 (2007)

    Article  Google Scholar 

  26. J.R. Kim, S.W. Choi, S.M. Jo, W.S. Lee, B.C. Kim, Electrochim. Acta 50, 69 (2004)

    Article  Google Scholar 

  27. K. Maex, M.R. Baklanov, D. Shamiryan, F. Iacopi, S.H. Brongersma, Z.S. Yanovitskaya, J. Appl. Phys. 93, 8793 (2003)

    Article  ADS  Google Scholar 

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Correspondence to Ce Wang.

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Li, Y., Lu, X., Liu, X. et al. Ultra-low dielectric performance of polymer electrospun nanofiber mats. Appl. Phys. A 100, 207–212 (2010). https://doi.org/10.1007/s00339-010-5577-4

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  • DOI: https://doi.org/10.1007/s00339-010-5577-4

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