Skip to main content
Log in

Electromechanical properties of lanthanum-doped lead hafnate titanate thin films for integrated piezoelectric MEMS applications

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

This paper focuses on the deposition and electromechanical characterization of lanthanum-doped lead hafnate titanate (PLHT) thin films as key material in piezoelectric microelectromechanical systems (pMEMS). PLHT (x/30/70) and PLHT(x/45/55) films with a thickness between 150 nm and 250 nm were deposited by chemical solution deposition (CSD). Thereby x varies between 0 and 10% La content. The electrical characterization shows that undoped (x=0) PLHT exhibit ferroelectric behavior similar to PZT of the same composition. La doping results in reduced ferroelectric properties and also affects the electromechanical properties. Measurements using a double beam laser interferometer yield a piezoelectric coefficient d 33 of 60 pm/V, which stays constant with an increasing electric field. This leads to a linear displacement compared to undoped PLHT or conventional PZT films used for MEMS applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D.L. Polla, L.F. Francis, MRS Bull. 21, 59–65 (1996)

    Google Scholar 

  2. P. Muralt, M. Kohli, T. Maeder, A. Kholkin, K. Brooks, N. Setter, R. Luthier, Sens. Actuators A 48, 157–165 (1995)

    Article  Google Scholar 

  3. P. Muralt, A. Kholkin, M. Kohli, T. Maeder, K.G. Brooks, R. Luthier, Integr. Ferroelectr. 11, 213–220 (1995)

    Article  Google Scholar 

  4. M.-A. Dubois, P. Muralt, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 45, 1169–1177 (1998)

    Article  Google Scholar 

  5. W.P. Robbins, Integr. Ferroelectr. 11, 179–190 (1995)

    Article  Google Scholar 

  6. D.L. Polla, SPIE 2046, 24–27 (1997)

    Article  Google Scholar 

  7. M. Arik, S.M. Zurn, A. Bar-Cohen, Y. Nam, D. Markus, D. Polla, in Proc. of Int. Conf. on Modelling and Simulation of Microsystems, Semiconductors, Sensors and Actuators (1999), pp. 651–654

  8. Y. Nemirovsky, A. Nemirovsky, P. Muralt, N. Setter, Sens. Actuators A 56, 239–249 (1996)

    Article  Google Scholar 

  9. N. Ledermann, J. Baborowski, A. Seifert, B. Willing, S. Hiboux, P. Muralt, N. Setter, M. Forster, Integr. Ferroelectr. 35, 177–184 (2001)

    Article  Google Scholar 

  10. K.M. Johnson, J. Appl. Phys. 33, 2826 (1962)

    Article  ADS  Google Scholar 

  11. L.M. Sheppard, Ceram. Bull. 71, 85 (1992)

    Google Scholar 

  12. F. De Flaviis, N.G. Alexpopoulos, M. Staffsud, IEEE Trans. Microwave Theory Tech. 45, 963–969 (1997)

    Article  Google Scholar 

  13. P. Padmini, T.R. Taylor, M.J. Lefevre, A.S. Nagra, R.A. York, J.S. Speck, Appl. Phys. Lett. 75, 3186–3188 (1999)

    Article  Google Scholar 

  14. S. Tappe, U. Böttger, R. Waser, Integr. Ferroelectr. 53, 455–464 (2003)

    Google Scholar 

  15. C. Kügeler, A. Hennings, U. Böttger, R. Waser, J. Electroceram. (online) (2008). doi:10.1007/s10832-008-9457-7

    Google Scholar 

  16. J. Frantti, Y. Fujioka, S. Ericsson, S. Hull, M. Kakihana, Inorg. Chem. 44, 9267–9278 (2005)

    Article  Google Scholar 

  17. C. Muller, J.-L. Baudour, V. Madigou, F. Bouree, J.-M. Kiat, C. Favotto, M. Roubin, Acta Cryst. B 55, 8–16 (1999)

    Article  Google Scholar 

  18. C. Muller, J.-L. Baudour, C. Bedoya, F. Bouree, J.-L. Soubeyroux, M. Roubin, Acta Cryst. B 56, 27–38 (2000)

    Article  Google Scholar 

  19. C. Bedoya, C. Muller, J.-L. Baudour, F. Bouree, J.-L. Soubeyroux, M. Roubin, J. Phys. Condens. Matter 13, 6453–6470 (2001)

    Article  ADS  Google Scholar 

  20. J. Frantti, Y. Fujioka, S. Ericsson, S. Lantto, M. Kakihana, J. Electroceram. 13, 299–303 (2004)

    Article  Google Scholar 

  21. G. Fantozzi, H. Idrissi, C. Favotto, M. Roubin, J. Eur. Ceram. Soc. 20, 1671–1676 (2000)

    Article  Google Scholar 

  22. C. Heremans, H.L. Tuller, J. Europ. Ceram. Soc. 19, 1133–1137 (1999)

    Article  Google Scholar 

  23. P.J. Schorn, T. Schneller, U. Böttger, R. Waser, J. Am. Ceram. Soc. 88, 1312–1314 (2005)

    Article  Google Scholar 

  24. R.W. Schwarz, T. Schneller, R. Waser, C. R., Chim. 7, 433–461 (2004)

    Google Scholar 

  25. T. Schneller, R. Waser, J. Sol-Gel Sci. Technol. 42, 337–352 (2007)

    Article  Google Scholar 

  26. P. Gerber, A. Roelofs, O. Lohse, C. Kügeler, S. Tiedke, U. Böttger, R. Waser, Rev. Sci. Instrum. 74, 2613–2615 (2003)

    Article  ADS  Google Scholar 

  27. C. Bedoya, C. Muller, A. Kowalski, E. Nigrelli, J.-Y. Leblais, M. Roubin, J. Mater. Sci.: Mater. Electron. 12, 543–550 (2001)

    Article  Google Scholar 

  28. T. Schneller, H. Kohlstedt, A. Petraru, R. Waser, J. Guo, J. Denlinger, T. Learmonth, P.-A. Glans, K.E. Smith, J. Sol-Gel Sci. Technol. 48, 239–252 (2008)

    Article  Google Scholar 

  29. S.-Y. Chen, I.-W. Chen, J. Am. Ceram. Soc. 77, 2332–2336 (1994)

    Article  Google Scholar 

  30. K.G. Brooks, I.M. Reaney, R. Klissurska, Y. Huang, L. Bursill, N. Setter, J. Mater. Res. 9, 2540–2553 (1994)

    Article  ADS  Google Scholar 

  31. P. Gerber, U. Böttger, R. Waser, J. Appl. Phys. 100, 124105 (2006)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. Kügeler.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kügeler, C., Böttger, U. & Schneller, T. Electromechanical properties of lanthanum-doped lead hafnate titanate thin films for integrated piezoelectric MEMS applications. Appl. Phys. A 94, 739–745 (2009). https://doi.org/10.1007/s00339-008-5045-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-008-5045-6

PACS

Navigation