Abstract
The internal gettering (IG) effects involved with a rapid thermal anneal (RTA) in germanium-doped Czochralski silicon (GCz-Si) wafer have been investigated. It was found that germanium doping could enhance the oxygen precipitation in bulk while shrinking the denuded zone width near the surface through pre-RTA at high temperature plus low–high temperature conventional furnace anneals. Rapid cooling rate after RTA was clarified to be beneficial for oxygen precipitation for GCz-Si wafer. It was suggested that the germanium doping could increase the vacancy concentration in Cz-Si during RTA by forming the germanium–vacancy complexes. In contrast to that in Cz-Si wafer, the smaller-sized higher-density oxygen precipitates were presented in the nucleation anneals, then followed RTA pretreatment while more oxygen precipitates survived during ramping processes after nucleation anneals in the GCz-Si wafer. Enhanced heterogeneous nucleation and reduced critical radius of precipitates associated with the germanium–vacancy complexes have been proposed for the oxygen precipitation enhancement.
Similar content being viewed by others
References
K. Honda, A. Ohsawa, N. Toyokura, Appl. Phys. Lett. 46, 582 (1985)
T. Y Tan, E.E. Gardner, W.K. Tice, Appl. Phys. Lett. 30, 175 (1977)
K. Sueoko, M. Akatsuka, M. Yonemura, T. Ono, E. Asayama, Y. Koike, S. Sasamistu, Solid State Phenom. 82–84, 49 (2002)
M.L. Polignano, G.F. Cerofolini, H. Bender, C. Claeys, J. Appl. Phys. 64, 869 (1988)
M. Aoki, T. Itakura, N. Sasaki, Appl. Phys. Lett. 66, 2709 (1995)
J.L. Benton, P.A. Stolk, D.J. Eaglesham, D.C. Jacobson, J.Y. Cheng, J.M. Poate, N.T. Ha, T.E. Haynes, S.M. Myers, J. Appl. Phys. 80, 3275 (1996)
Q. Sun, K.H. Yao, H.C. Gatos, J. Lagowski, J. Appl. Phys. 71, 3760 (1992)
X. Yu, D. Yang, X. Ma, J. Yang, D. Que, J. Appl. Phys. 92, 194 (2002)
X. Yu, D. Yang, X. Ma, H. Li, Y. Shen, D. Tian, L. Li, D. Que, J. Cryst. Growth 250, 359 (2003)
H. Li, D. Yang, X. Ma, X. Yu, D. Que, J. Appl. Phys. 96, 4161 (2004)
J. Chen, D. Yang, H. Li, X. Ma, D. Que, J. Appl. Phys. 99, 073509 (2006)
R. Flaster, D. Gambaro, M. Olmo, M. Cornara, H. Korb, Mater. Res. Soc. Symp. Proc. 510, 27 (1998)
X. Ma, L. Fu, D. Tian, D. Yang, J. Appl. Phys. 98, 084502 (2005)
J. Chen, D. Yang, X. Ma, H. Li, D. Que, J. Appl. Phys. 101, 033526 (2007)
D. Yang, X. Yu, X. Ma, J. Xu, L. Li, D. Que, J. Cryst. Growth 243, 371 (2002)
V.V. Voronkov, R. Falster, J. Cryst. Growth 194, 76 (1998)
M. Pagani, R.J. Falster, G.R. Fisher, G.C. Ferrero, M. Olmo, Appl. Phys. Lett. 70, 1572 (1997)
A. Borghesi, B. Pivac, A. Sassella, A. Stella, J. Appl. Phys. 77, 4169 (1995)
R. Falster, V.V. Voronkov, F. Quast, Phys. Status Solidi B 222, 219 (2000)
R. Flaster, V.V. Voronkov, Mater. Sci. Eng. B 73, 87 (2000)
S. McHugo, E. Weber, M. Mizuno, F. Kirscht, Appl. Phys. Lett. 66, 2840 (1995)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chen, J., Yang, D., Ma, X. et al. Rapid-thermal-anneal-based internal gettering for germanium-doped Czochralski silicon. Appl. Phys. A 94, 905–910 (2009). https://doi.org/10.1007/s00339-008-4847-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-008-4847-x