Abstract
In order to develop a femtosecond laser ablation (fsLA) ion source for TOF mass spectrometry, we have analyzed time-resolved images of laser-induced fluorescence from Sm+ ions produced by fsLA of a solid samarium in electric fields. The polarity and the strength of electric fields had a remarkable effect on the expansion of Sm+ ions. Moreover, accelerating electric fields elongated the duration of the ion emission from the samarium surface in fsLA, which degraded time-focusing of the ions. We have found that suppression the continuous ion emission caused by fsLA in electric fields is most important in TOF measurements.
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Kato, T., Kurata-Nishimura, M., Kobayashi, T. et al. Ion extraction from the surface ablated materials in electric fields using an intense femtosecond laser pulse. Appl. Phys. A 92, 809–812 (2008). https://doi.org/10.1007/s00339-008-4583-2
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DOI: https://doi.org/10.1007/s00339-008-4583-2