Abstract
Aligned arrays of N2-encapsulated multilevel branched carbon nanotubes were synthesized using a simple one step CVD method by pyrolysis of ferrocene and acetonitrile. Electron energy loss spectroscopy (EELS) and elemental mapping studies reveal that gaseous nitrogen was encapsulated in the carbon nanotubes. Batch-type pyrolysis of catalysts induced flow fluctuation of the reaction gases, resulting in the growth of branched junctions. Molecular nitrogen extruded rapidly along conical catalyst particles inducing N2 encapsulation inside the branched nanotubes.
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References
S.M. Sze, Physics of Semiconductor Devices (Wiley, New York, 1981)
S. Reitzenstein, L. Worschech, P. Hartmann, M. Kamp, A. Forchel, Phys. Rev. Lett. 89, 226804 (2002)
S. Ami, C. Joachim, Phys. Rev. B 65, 155419 (2002)
A.M. Song, A. Lorke, A. Kriele, J.P. Kotthaus, W. Wegscheider, M. Bichler, Phys. Rev. Lett. 80, 3831 (1998)
C. Papadopoulos, A. Rakitin, J. Li, A.S. Vedeneev, J.M. Xu, Phys. Rev. Lett. 85, 3476 (2000)
A.G. Milnes, D.L. Feucht, Heterojunctions and Metal–Semiconductor junctions (Academic, New York, 1972)
A.N. Andriotis, M. Menon, D. Srivastava, L. Chemozatonskii, Phys. Rev. Lett. 87, 066802 (2001)
S. Chen, B. Trauzettel, R. Egger, Phys. Rev. Lett. 89, 226404 (2002)
V. Meunier, M.B. Nardelli, J. Bernholc, T. Zacharia, J.-C. Charlier, Appl. Phys. Lett. 81, 5234 (2002)
A.N. Andriotis, M. Menon, D. Srivastava, L. Chemozatonskii, Appl. Phys. Lett. 79, 266 (2001)
C. Papadopoulos, A.J. Yin, J.M. Xu, Appl. Phys. Lett. 85, 1769 (2004)
P.R. Bandaru, C. Daraio, S. Jin, A.M. Rao, Nature Mater. 4, 663 (2005)
M. Terrones, F. Banhart, N. Grobert, J.C. Charlier, H. Terrones, P.M. Ajayan, Phys. Rev. Lett. 89, 075505 (2002)
D. Zhou, S. Seraphin, Chem. Phys. Lett. 238, 286 (1995)
B.C. Satishkumar, P.J. Thomas, A. Govindaraj, C.R. Rao, Appl. Phys. Lett. 77, 2530 (2000)
O.T. Heyning, P. Bernier, M. Glerup, Chem. Phys. Lett. 43, 409 (2005)
J.M. Ting, C.C. Chang, Appl. Phys. Lett. 80, 324 (2002)
F.L. Deepak, A. Govindaraj, C.N.R. Rao, Chem. Phys. Lett. 345, 5 (2001)
C.N.R. Rao, A. Govindaraj, Acc. Chem. Res. 35, 998 (2002)
W.Z. Li, J.G. Wen, Z.F. Ren, Appl. Phys. Lett. 79, 1879 (2001)
B. Gan, J. Ahn, A. Zhang, S.F. Yoon, Rusli, Q.F. Huang, H. Yang, M.B. Yu, W.Z. Li, Diam. Relat. Mater. 9, 897 (2000)
S.H. Tsai, C.T. Shiu, W.J. Jong, H.C. Shih, Carbon 38, 1879 (2000)
J. Li, C. Papadopoulos, J. Xu, Nature 402, 253 (1999)
N. Gothard, C. Daraio, J. Gaillard, R. Zidan, S. Jin, A.M. Rao, Nano. Lett. 4, 213 (2004)
D.C. Wei, Y.Q. Liu, L.C. Cao, L. Fu, X.L. Li, Y. Wang, G. Yu, D.B. Zhu, Nano. Lett. 6, 186 (2006)
M. Reyes-Reyes, N. Grobert, R. Kamalakaran, T. Seeger, D. Golberg, M. Ruhle, Y. Bando, H. Terrones, M. Terrones, Chem. Phys. Lett. 396, 167 (2004)
J. Casanovas, J.M. Ricart, J. Rubio, F. Illas, J.M. Jimenez-Mateos, J. Am. Chem. Soc. 118, 8071 (1996)
M. Terrones, H. Terrones, N. Grobert, W.K. Hsu, Y.Q. Zhu, Y.P. Hara, H.W. Kroto, D.R. Walton, P. Kohler-Redlich, M. Ruhle, J.P. Zhang, A.K. Cheetham, Appl. Phys. Lett. 75, 3932 (1999)
R. Che, L.-M. Peng, Q. Chen, X.F. Duan, Z.N. Gu, Appl. Phys. Lett. 82, 3319 (2003)
F. Banhart, Rep. Prog. Phys. 62, 1181 (1999)
D. Ugarte, Nature 359, 707 (1992)
B.W. Smith, M. Monthioux, D.E. Luzzi, Nature 396, 323 (1998)
Y. Zhang, S. Iijima, Philos. Mag. Lett. 80, 427 (2000)
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07.78.+s; 61.46.+w; 81.07.De; 81.15.Gh
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Su, J., Yu, Y. & Che, R. Aligned array of N2-encapsulated multilevel branched carbon nanotubes. Appl. Phys. A 90, 135–139 (2008). https://doi.org/10.1007/s00339-007-4229-9
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DOI: https://doi.org/10.1007/s00339-007-4229-9