Applied Physics A

, 83:163 | Cite as

Synchrotron X-ray diffraction and imaging of ancient Chinese bronzes

  • M.L. Young
  • F. Casadio
  • S. Schnepp
  • J. Almer
  • D.R. Haeffner
  • D.C. Dunand
Article

Abstract

High-energy synchrotron X-ray diffraction and imaging experiments were performed at the Advanced Photon Source on two ancient Chinese bronzes from the Art Institute of Chicago with the goal to nondestructively study their microstructure. The first object, a bronze fragment from an early Western Zhou dynasty vessel (Hu, 11th/10th century B.C.), was investigated with spatially-resolved diffraction to reveal the depth and composition of the surface corrosion layer as well as the composition and grain size of the underlying bronze core. The second object, a bronze dagger-axe (Ge, 3rd/2nd century B.C.) with a silver-inlaid sheath, was studied under both diffraction and imaging conditions. It was found to have been cast as a single object, answering longstanding scholars’ questions on whether the ceremonial object concealed an interior blade.

References

  1. 1.
    G. Harbottle, B.M. Gordon, K.W. Jones, Nucl. Instrum. Methods Phys. Res. B 14, 116 (1986)CrossRefADSGoogle Scholar
  2. 2.
    M. Schreiner, B. Fruhmann, D. Jembrih-Simburger, R. Linke, Powder Diffr. 19, 1 (2004)CrossRefGoogle Scholar
  3. 3.
    M.F. Araujo, T. Pinheiro, P. Valerio, A. Barreiros, A. Simionovici, S. Bohic, A. Melo, J. Phys. IV 104, 523 (2003)CrossRefGoogle Scholar
  4. 4.
    D. Grolimund, M. Senn, M. Trottmann, M. Janousch, I. Bonhoure, A.M. Scheidegger, M. Marcus, Spectrochim. Acta B 59, 1627 (2004)CrossRefADSGoogle Scholar
  5. 5.
    K. Janssens, G. Vittiglio, I. Deraedt, A. Aerts, B. Vekemans, L. Vincze, F. Wei, I. Deryck, O. Schalm, F. Adams, A. Rindby, A. Knochel, A. Simionovici, A. Snigirev, X-ray Spectrom. 29, 73 (2000)CrossRefGoogle Scholar
  6. 6.
    A. De Ryck, A. Adriaens, E. Pantos, F. Adams, Analyst 128, 1104 (2003)CrossRefADSGoogle Scholar
  7. 7.
    B. Newbury, B. Stephenson, J.D. Almer, M. Notis, G.S. Cargill, G.B. Stephenson, D.R. Haeffner, Powder Diffr. 19, 12 (2004)CrossRefADSGoogle Scholar
  8. 8.
    G.B. Stephenson, B. Stephenson, D.R. Haeffner, MRS Bull. 26, 19 (2001)Google Scholar
  9. 9.
    R.J. Gettens, J. Chem. Educ. 28, 67 (1951)CrossRefGoogle Scholar
  10. 10.
    R.J. Gettens, The Freer Chinese Bronzes. In Freer Gallery of Art: Oriental Studies, No. 7. Smithsonian Institution, Washington (1969) pp. 127–131Google Scholar
  11. 11.
    B. Kanngiesser, W. Malzer, I. Reiche, Nucl. Instrum. Methods Phys. Res. B 211, 259 (2003)CrossRefADSGoogle Scholar
  12. 12.
    I. Constantinides, A. Adriaens, F. Adams, Appl. Surf. Sci. 189, 90 (2002)CrossRefADSGoogle Scholar
  13. 13.
    C. Debiemme-Chouvy, F. Ammeloot, E.M.M. Sutter, Appl. Surf. Sci. 174, 55 (2001)CrossRefADSGoogle Scholar
  14. 14.
    I. Mabille, A. Bertrand, E.M.M. Sutter, C. Fiaud, Corros. Sci. 45, 855 (2003)CrossRefGoogle Scholar
  15. 15.
    L. Robbiola, J.-M. Blengino, C. Fiaud, Corros. Sci. 40, 2083 (1998)CrossRefGoogle Scholar
  16. 16.
    S.F. Nielsen, A. Wolf, H.F. Poulsen, M. Ohler, U. Lienert, R.A. Owen, J. Synchrotron. Radiat. 7, 103 (2000)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  • M.L. Young
    • 1
  • F. Casadio
    • 2
  • S. Schnepp
    • 2
  • J. Almer
    • 3
  • D.R. Haeffner
    • 3
  • D.C. Dunand
    • 1
  1. 1.Department of Materials Science and EngineeringNorthwestern UniversityEvanstonUSA
  2. 2.The Art Institute of ChicagoChicagoUSA
  3. 3.Advanced Photon SourceArgonne National LaboratoryArgonneUSA

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