Skip to main content

Single-crystalline ZnS tubular structures: preparation and characterization

Abstract

Single-crystalline ZnS tubular structures have been successfully synthesized via thermal evaporation of ZnS powders mixed with a small amount of SnO2 at 1180 °C in a high-temperature tube furnace. Structure and microstructure of the ZnS tubes have been characterized by means of scanning electron microscopy and various techniques in a transmission electron microscope. It is found that the as-synthesized ZnS tubes are straight and uniform with lengths of several hundred micrometers. The outer diameters of these tubular structures range from several hundred nanometers to a few micrometers. As a part of the as-synthesized product, ZnS/Zn2SnO4 cables are also observed. A growth mechanism of these novel structures is proposed on the basis of transmission electron microscopy.

This is a preview of subscription content, access via your institution.

References

  1. S. Iijima, Nature 354, 56 (1991)

  2. A.M. Morales, C.M. Lieber, Science 279, 208 (1998)

    Google Scholar 

  3. N.G. Chopra, R.J. Luken, K. Cherrey, V.H. Crespi, M.L. Cohen, S.G. Louie, A. Zettl, Science 269, 966 (1995)

    Google Scholar 

  4. A. Rothschild, J. Sloan, R. Tenne, J. Am. Chem. Soc. 122, 5169 (2000)

    Google Scholar 

  5. P. Yan, Y. Xie, Y.T. Qian, X.M. Liu, Appl. Phys. Lett 75, 2455 (1999)

    Google Scholar 

  6. Z.W. Pan, Z.R. Dai, Z.L. Wang, Science 291, 1947 (2001)

  7. J.Q. Hu, X.L. Ma, N.G. Shang, Z.Y. Xie, N.B. Wang, C.S. Lee, S.T. Lee, J. Phys. Chem. B 106, 3823 (2002)

    Google Scholar 

  8. T.Y. Tan, S.T. Lee, U. Gösele, Appl. Phys. A 74, 423 (2002)

    Google Scholar 

  9. Y.N. Xia, P.D. Yang, Y.G. Sun, Y.Y. Wu, B. Mayers, B. Gates, Y.D. Yin, F. Kim, Y.Q. Yan: Adv. Mater. 15, 353 (2003)

    Article  CAS  Google Scholar 

  10. J.A. Ascencio, P. Santiago, L. Rendon, U. Pal, Appl. Phys. A 78, 5 (2004)

    Google Scholar 

  11. Y.Q. Zhu, W.K. Hsu, H.W. Kroto, D.R.M. Walton, Chem. Commun. 21, 2184 (2001)

    Google Scholar 

  12. S.M. Liu, L.M. Gan, L.H. Liu, W.D. Zhang, H.C. Zeng, Chem. Mater. 14, 1391 (2002)

    Google Scholar 

  13. J. Goldberger, R.R. He, Y.F. Zhang, S. Lee, H.Q. Yan, H.J. Choi, P.D. Yang: Nature 422, 599 (2003)

    Article  CAS  PubMed  Google Scholar 

  14. R.T. Lv, C.B. Cao, Y.J. Guo, H.S. Zhu, J. Mater. Sci. 39, 1575 (2004)

    Google Scholar 

  15. P. Santiago, J.A. Ascencio, D. Mendoza, M. Perez-Alvarez, A. Espinosa, C. Reza-sangerman, P. Schabes-Retchkiman, G.A. Camacho-Bragado, M. Jose-Yacaman, Appl. Phys. A 78, 513 (2004)

    Google Scholar 

  16. G.S. Wu, L.D. Zhang, B.C. Cheng, T. Xie, X.Y. Yuan, J. Am. Chem. Soc. 126, 5976 (2004)

    Google Scholar 

  17. T.W. Ebbesen, P.M. Ajayan: Nature 358, 220 (1992)

    Article  CAS  Google Scholar 

  18. O.R. Lourie, C.R. Jones, B.M. Bartlett, P.C. Gibbons, R.S. Ruoff, W.E. Buhro, Chem. Mater. 12, 1808 (2000)

    Google Scholar 

  19. J.Q. Hu, Y. Bando, Appl. Phys. Lett. 82, 1401 (2003)

    Google Scholar 

  20. H. Zhang, X.Y. Ma, J. Xu, D.R. Yang, J. Cryst. Growth 263, 372 (2004)

    Google Scholar 

  21. M. Nath, A. Govindaraj, C.N.R. Rao, Adv. Mater. 13, 283 (2001)

    Google Scholar 

  22. J. Yang, Y.C. Liu, H.M. Lin, C.C. Chen, Adv. Mater. 16, 713 (2003)

    Google Scholar 

  23. P.D. Rack, P.H. Holloway, Mater. Sci. Eng. Res. 21, 171 (1998)

    Google Scholar 

  24. S. Kishimoto, A. Kato, A. Naito, Y. Sakamoto, S. Iida, Phys. Status Solidi B 229, 391 (2002)

    Google Scholar 

  25. L. Sun, C. Liu, C. Liao, C. Yan, J. Mater. Chem. 9, 1655 (1999)

    Google Scholar 

  26. X. Jiang, Y. Xie, J. Lu, L. Zhu, W. He, Y. Qian, Chem. Mater. 13, 1213 (2001)

    Google Scholar 

  27. B. Elidrissi, M. Addou, M. Regragui, A. Bougrine, A. Kachouane, J.C. Bernecde, Mater. Chem. Phys. 68, 175 (2001)

    Google Scholar 

  28. S. Yamaga, A. Yoshikawa, H. Kassi, J. Cryst. Growth 86, 252 (1988)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to X.L. Ma.

Additional information

PACS

81.07.De; 68.37.Lp; 81.15.Gh; 68.37.Hk; 81.70.Jb

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Li, Y., Ma, X. Single-crystalline ZnS tubular structures: preparation and characterization. Appl. Phys. A 80, 1689–1692 (2005). https://doi.org/10.1007/s00339-005-3224-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-005-3224-2

Keywords

  • Microstructure
  • Microscopy
  • Electron Microscopy
  • Scanning Electron Microscopy
  • Thin Film