Abstract
In the equilibrium immiscible Ag–Co system characterized by a large positive heat of formation (28 kJ/mol), interesting structural phase transitions were observed in Ag–Co multilayered films upon 200-keV xenon-ion irradiation at 300 K within a dose range of 5×1014 to 9×1015 Xe+/cm2. The formation of a new metastable HCP phase and observation of other structural phase transitions upon ion irradiation were quite in accordance with first principles and thermodynamic calculations. It was observed that in the as-deposited Ag–Co multilayered films, the stress from the Co layers resulted in a condensation effect on the Ag lattice, and that after irradiation to a dose of 5×1014 Xe+/cm2, the Ag lattice recovered to its original size along with the hcp Co transforming into its high-temperature-stabilized fcc structure. Besides, the mechanism of the metastable phase formation as well as the observed structural phase transitions induced by ion irradiation is discussed in terms of thermodynamics and growth kinetics.
Similar content being viewed by others
References
Y.Q. Lu, Y.Y. Zhu, Y.F. Chen, S.N. Zhu, N.B. Ming, Y.J. Feng: Science 284, 1822 (1999)
B.X. Liu, W.S. Lai, Q. Zhang: Mater. Sci. Eng. R 29, 1 (2000)
B.X. Liu, W.L. Johnson, M.A. Nicolet, S.S. Lau: Appl. Phys. Lett. 42, 45 (1983)
B.X. Liu, W.L. Johnson, M.A. Nicolet, S.S. Lau: Nucl. Instrum. Methods 209–210, 229 (1983)
L.S. Hung, M. Nastasi, J. Gyulai, J.W. Mayer: Appl. Phys. Lett. 42, 672 (1983)
Z.C. Li, D.P. Yu, B.X. Liu: Phys. Rev. B 65, 245403 (2002)
R.F. Zhang, B.X. Liu: J. Mater. Res. 18, 1499 (2003)
F.R. de Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, A.K. Niessen: Cohesion in Metals: Transition Metal Alloys (North-Holland, Amsterdam 1989)
R.F. Zhang, B.X. Liu: Appl. Phys. Lett. 81, 1219 (2002)
J.A. Alonso, L.J. Gallego, J.A. Simozar: Nuovo Cimento 12, 587 (1990)
M.V. Thompson: Defects and Radiation Damage in Metals (Cambridge University Press 1969) Chaps. 4 and 5
B.X. Liu: Phys. Status Solidi A 94, 11 (1986)
B.X. Liu, Z.J. Zhang: Phys. Rev. B 49, 12519 (1994)
B.X. Liu, Z.J. Zhang: J. Mater. Res. 9, 375 (1994)
L.T. Kong, R.F. Zhang, Z.C. Li, B.X. Liu: Phys. Rev. B 68, 134446 (2003)
H. Bakker: Enthalpies in Alloys: Miedema’s Semi-Empirical Model (Trans Tech, Zurich 1998)
J.M. Lopez, J.A. Alonso: Z. Naturforsch. 40, 1199 (1985)
K. Zhang, R. Gupta, K.P. Lieb, Y. Luo, G.A. Muller: Europhys. Lett. 64, 668 (2003)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
61.82.Bg; 64.60.My; 64.70.Kb
Rights and permissions
About this article
Cite this article
Yan, H., Liu, B. Structural phase transition induced by ion irradiation in the equilibrium immiscible Ag–Co system. Appl. Phys. A 81, 1435–1439 (2005). https://doi.org/10.1007/s00339-004-3181-1
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-004-3181-1