Skip to main content
SpringerLink
Log in

Crystal structure and dielectric properties of a new complex perovskite oxide Ba2LaSbO6

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The crystal structure and dielectric properties of a new perovskite material Ba2LaSbO6 are reported. Ba2LaSbO6 was synthesized for the first time by conventional solid state reaction process. X-ray diffraction (XRD) measurements and Rietveld analysis revealed that, contrary to the other Ba2RESbO6 (RE = Rare-Earth other than La) complex perovskites, which are cubic, Ba2LaSbO6 crystallizes in a monoclinic system having space group P21/n. Dielectric properties of Ba2LaSbO6 at frequencies up to 40 GHz and in temperatures ranging from 50 to 350 K were determined by analyzing the resonant modes in cavities totally filled with the measured material. The dielectric constant (ε′)=15.8±0.2% and at 77 K loss factor (tgδ)≈9×10-4. Preliminary studies reveal that at the processing temperatures, Ba2LaSbO6 do not react with YBa2Cu3O7-δ (YBCO) and Bi2Sr2CaCu2Ox [Bi (2212)] superconductors. Having appropriate dielectric properties along with chemical stability with superconductors Ba2LaSbO6 can be used as a precursor as substrate for deposition of various passive HTS devices, or as an insulator in the active SIS structures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Kimura, Y. Tokura: Ann. Rev. Mater. Sci. 30, 451 (2000)

    Article  ADS  Google Scholar 

  2. F. Litchenberg, A. Herrnberger, K. Weidenman, J. Mannhart: Prog. Solid State Chem. 29, 1 (2001)

    Article  Google Scholar 

  3. J.A. Aguiar, D.A.L. Tellez, Y. P Yadava, J.M. Ferreira: Phys. Rev. B 58, 2454 (1998)

    Article  ADS  Google Scholar 

  4. N.M. Alford, S.J. Penn, T. W Button: Supercond. Sci. Technol. 10, 169 (1997)

    Article  ADS  Google Scholar 

  5. V.J. Fratello, G.W. Berkstresser, C.D. Brandle, A.J. Ven Graitis: J. Crystal Growth 166, 878 (1996)

    Article  ADS  Google Scholar 

  6. Y.P. Yadava, D.A. Landinez Tellez, M.T. De Mello, J.M. Ferreira, J. Albino Aguiar: Appl. Phys A. 66, 455 (1998)

    Article  ADS  Google Scholar 

  7. R. Jose, A.M. John, J. Kurian, P.K. Sajith, J. Koshy: J. Mater. Res. 12, 2976 (1997)

    Article  ADS  Google Scholar 

  8. M. Tagata, K. Kageyama: J. Am. Ceram. Soc. 72, 1955 (1989)

    Article  Google Scholar 

  9. R. Zurmuhlen, J. Petzelt, S. Kamba, G. Kozlov, A. Volkov, B. Gorshurov, D.C. Dube, A. Tagantsev, N. Setter: J. Appl. Phys. 77, 5251 (1995)

    Google Scholar 

  10. H. Sreemoolanadhan, R. Ratheesh, M.T. Sebastian, P. Mohanan: Mater. Lett. 33, 161 (1997)

    Article  Google Scholar 

  11. J. Konopka, A. Konopka, P. Waldow, R. Jose, M. Wolcyrz: J. Appl. Phys. 94, 3451 (2003)

    Article  ADS  Google Scholar 

  12. G. Blasse: J. Inorg. Nucl. Chem. 27, 993 (1965)

    Article  Google Scholar 

  13. P.G. Casedo, A. Mendiola, I. Rasines: Z. Anorg. Allg. Chem. 510, 194 (1985)

    Article  Google Scholar 

  14. J.A. Alonso, C. Cascales, P.G. Casedo, I. Rasines: J. Solid State Chem. 128, 247 (1997)

    Article  ADS  Google Scholar 

  15. J. Kurian, J. Koshy, P.R.S. Wariar, Y.P. Yadava, A.D. Damodaran: J. Solid State Chem. 116, 193 (1995)

    Article  ADS  Google Scholar 

  16. J. Konopka, I. Wolff: IEEE Trans. Microwave Theory Tech. 40, 2418 (1992)

    Article  ADS  Google Scholar 

  17. Cerius 2 Modelling Environment, Release 4.0, San Diego, Molecular Simulations Inc. (1999)

  18. A.A. Bokov, N.P. Protsenko, Z.G. Ye: J. Phys. Chem. Solids 61, 1519 (2000)

    Article  ADS  Google Scholar 

  19. A.F. Wells: Structural Inorganic Chemistry, 5th ed. (Clarendon Press, Oxford, U. K.1986) p. 279

  20. F.S. Galaso, M. Darby: J. Phys. Chem. 66, 131 (1962)

    Article  Google Scholar 

  21. R.E. Collin: Foundations for Microwave Engineering (McGraw, New York, 1996)

Download references

Author information

Authors and Affiliations

  1. Single Molecule Bioanalysis Laboratory, National Institute of Advanced Industrial Science and Technology, 2217-14 Hayashi, 761-0395, Kagawa, Japan

    R. Jose & M. Ishikawa

  2. Institute Fizyki, Polish Academy of Sciences, Al. Lotników 32/46, 02-668, Warszawa, Poland

    J. Konopka & A. Konopka

  3. Marine Resources and Environment Research Institute, National Institute of Advanced Industrial Science and Technology, 2217-14 Hayashi, 761-0395, Kagawa, Japan

    X. Yang

  4. Council of Scientific and Industrial Research, Regional Research Laboratory, Trivandrum, India, 695 019

    R. Jose & J. Koshy

Authors
  1. R. Jose
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Konopka
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. X. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Konopka
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Ishikawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. J. Koshy
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. Jose.

Additional information

PACS

61.66.Fn; 61.10.Nz; 77.22.-d; 74.72.-h

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jose, R., Konopka, J., Yang, X. et al. Crystal structure and dielectric properties of a new complex perovskite oxide Ba2LaSbO6. Appl. Phys. A 79, 2041–2047 (2004). https://doi.org/10.1007/s00339-004-2672-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-004-2672-4

Keywords

Search

Navigation