Abstract
We describe a study of the time dynamics of the spectral position of six major peaks in the Raman spectrum of single-crystal congruent lithium niobate, following the process of electric-field repoling. All of the peaks observed show a small (<1 cm-1) frequency shift after repoling. Two peaks are shifted to higher frequencies while the other four are shifted to lower frequencies. The shift generally recovers over time towards the original value. The 153 cm-1 and 432 cm-1 peaks are seen to recover to their original positions before poling, with time constants of approximately 8 h and 4 h, respectively, whereas the higher frequency peak at 872 cm-1 does not appear to recover at all. The other peaks exhibit incomplete recovery. We compare the measured values of temporal recovery with published relaxation times for internal electric fields, and make an additional comparison with our measured etch-rate data for the -z face of lithium niobate as a function of delay time following repoling.
Similar content being viewed by others
References
M. Yamada, N. Nada, M. Saitoh, K. Watanabe: Appl. Phys. Lett. 62, 435 (1993)
L.E. Myers, R.C. Eckardt, M.M. Fejer, R.L. Byer, W.R. Bosenberg, J.W. Pierce: J. Opt. Soc. Am. B 12, 2102 (1995)
R.S. Weis, T.K. Gaylord: Appl. Phys. A 32, 191 (1985)
V. Gopalan, T.E. Mitchell: J. Appl. Phys. 83, 941 (1998)
V. Gopalan, T.E. Mitchell, Y. Furukawa, K. Kitamura: Appl. Phys. Lett. 72, 1981 (1998)
I.E. Barry, G.W. Ross, P.G.R. Smith, R.W. Eason, G. Cook: Mater. Lett. 37, 246 (1998)
C.L. Sones, S. Mailis, W.S. Brocklesby, R.W. Eason, J.R. Owen: J. Mater. Chem. 12, 295 (2002)
C. Kittel: Introduction to Solid State Physics (Wiley, New York 1996)
Y. Repelin, E. Husson, F. Bennani, C. Proust: J. Phys. Chem. Solids 60, 819 (1999)
W.D. Johnston, I.P. Kaminow: Phys. Rev. 168, 1045 (1968)
D.R. Lide: CRC Handbook of Chemistry and Physics, 75th edn. (CRC Press, Boca Raton 1994)
T.C. Damen, S.P.S. Porto, B. Tell: Phys. Rev. 142, 570 (1966)
A. Ridah, P. Bourson, M.D. Fontana, G. Malovichko: J. Phys. Condens. Matter 9, 9687 (1997)
E. Laubacher, Y. Guan, P. Yaney: Abstract for the OSS00 Meeting of the American Physical Society, Ohio Section Spring Meeting, May 2000 University of Cincinnati, Cincinnati, Ohio USA
J.H. Ro, M. Cha: Appl. Phys. Lett. 77, 2391 (2000)
V. Gopalan, M.C. Gupta: Ferroelectrics 198, 49 (1997)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
77.84.Dy; 78.30; 77.80.Dj
Rights and permissions
About this article
Cite this article
Scott, J., Mailis, S., Sones, C. et al. A Raman study of single-crystal congruent lithium niobate following electric-field repoling. Appl. Phys. A 79, 691–696 (2004). https://doi.org/10.1007/s00339-003-2249-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-003-2249-7