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Stable organoboron polymers prepared by hydroboration polymerization of dienes with tripylborane

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Summary

Hydroboration polymerization between diene monomers and 2,4,6-triisopropylphenylborane (tripylborane) gave organoboron main-chain polymers. The polymerization was carried out by adding a diene monomer to a THF solution of tripylborane at room temperature under nitrogen. The obtained polymers were found to be more stable compared with the polymers prepared from thexylborane or mesitylborane.

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Authors and Affiliations

  1. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan, , , , , , JP

    Mamoru Miyata, Frauke Meyer & Yoshiki Chujo

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  1. Mamoru Miyata
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  2. Frauke Meyer
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  3. Yoshiki Chujo
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Received: 27 November 2000/Accepted: 11 December 2000

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Miyata, M., Meyer, F. & Chujo, Y. Stable organoboron polymers prepared by hydroboration polymerization of dienes with tripylborane. Polymer Bulletin 46, 23–28 (2001). https://doi.org/10.1007/s002890170084

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  • DOI: https://doi.org/10.1007/s002890170084

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