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Synthesis of cyclic poly(methyl methacrylate) by the intramolecular cyclization of α-amino, ω-carboxyl heterodifunctional poly(methyl methacrylate)

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Summary

α-Amino, ω-carboxyl heterodifunctional poly(methyl methacrylate) was prepared by a living anionic polymerization of methyl methacrylate using N,N'-diphenylethylenediamine monolithium amide and succinic anhydride as an initiator and terminator, respectively. Its intramolecular cyclization was carried out to obtain a well-defined cyclic poly(methyl methacrylate).

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Authors and Affiliations

  1. Department of Chemistry for Materials, Mie University, Tsu 514-8507, Japan, , , , , , JP

    Masataka Kubo, Hisatomu Yamamoto, Takahiro Uno & Takahito Itoh

  2. The Agricultural High-Tech Research Center, Meijo University, Nagoya 468-8502, Japan, , , , , , JP

    Hiroaki Sato

Authors
  1. Masataka Kubo
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  2. Hisatomu Yamamoto
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  3. Takahiro Uno
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  4. Takahito Itoh
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  5. Hiroaki Sato
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Additional information

Received: 27 June 2001/Accepted: 16 July 2001

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Kubo, M., Yamamoto, H., Uno, T. et al. Synthesis of cyclic poly(methyl methacrylate) by the intramolecular cyclization of α-amino, ω-carboxyl heterodifunctional poly(methyl methacrylate). Polymer Bulletin 47, 25–30 (2001). https://doi.org/10.1007/s002890170017

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  • DOI: https://doi.org/10.1007/s002890170017

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