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Characterisation of gel permeation chromatography column by fractal geometry

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Summary

General aspects of fractal geometry are treated, and a mathematic model for characterisation of chromatographic gel behaviour is presented. The fractal dimension of the porous gel within a Waters Styragel HT 5 chromatography column, df= 2.3, as well as the linear dimension of pores, L = 0.3 μm, have been determined.

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Authors and Affiliations

  1. Department of Polymer Physics, University "Politehnica" of Bucharest, 149 Calea Victoriei, Sector 1, Bucharest, Romania, , , , , , RO

    A. G. Boborodea, Cristina Stere & D. S. Vasilescu

  2. Department of Chemistry and Materials, Manchester Metropolitan University, John Dalton Building, Chester Street, Manchester, M1 5GD, UK, , , , , , GB

    M. Clemens

Authors
  1. A. G. Boborodea
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  2. M. Clemens
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  3. Cristina Stere
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  4. D. S. Vasilescu
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Additional information

Received: 27 January 1999/Revised version: 15 January 2000/Accepted: 13 April 2000

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Boborodea, A., Clemens, M., Stere, C. et al. Characterisation of gel permeation chromatography column by fractal geometry. Polymer Bulletin 44, 525–532 (2000). https://doi.org/10.1007/s002890070074

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  • DOI: https://doi.org/10.1007/s002890070074

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