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Polymer-metal complexes: Synthesis, characterization, and properties of poly(maleic acid) metal complexes with Cu(II), Co(II), Ni(II), and Zn(II)

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SUMMARY

Polymer metal complexes of poly(maleic acid) and Cu(II), Co(II), Ni(II), and Zn(II) were synthesized. Elemental analysis, as well as magnetic, spectral and thermal properties, in addition to electrical conductivities of the chelates were investigated, and possible structures have been assigned to the polychelates. Semi-empirical calculations at the PM3 level were carried out on the geometrical arrangement of the polychelates.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Concepción, Casilla 160-C, Concepción, Chile, , , , , , CL

    B. L. Rivas, G. V. Seguel & C. Ancatripai

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  1. B. L. Rivas
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  2. G. V. Seguel
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  3. C. Ancatripai
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Received: 19 November 1999/Revised version: 22 March 2000/Accepted: 31 March 2000

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Rivas, B., Seguel, G. & Ancatripai, C. Polymer-metal complexes: Synthesis, characterization, and properties of poly(maleic acid) metal complexes with Cu(II), Co(II), Ni(II), and Zn(II). Polymer Bulletin 44, 445–452 (2000). https://doi.org/10.1007/s002890070064

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  • DOI: https://doi.org/10.1007/s002890070064

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