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Spontaneous copolymerization of N-(2-hydroxyethyl)ethyleneimine with isatoic anhydride

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Summary

The polymerization of isatoic anhydride (electrophilic monomer) with N-(2-hydroxyethyl)ethyleneimine (nucleophilic monomer) was studied in the absence of added initiator at different feed monomer concentrations, temperature, and time of copolymerization. The copolymers were characterized by FT-IR, 1H-NMR and 13C-NMR spectroscopy, and TGA. Based on spectroscopic data and copolymer composition, a copolymer structure was suggested.

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Authors and Affiliations

  1. Departamento de Polímeros, Facultad de Ciencias Químicas, Universidad de Concepción, Casilla 3-C, Concepción, Chile

    S. A. Pooley, G. S. Canessa, B. L. Rivas & E. Espejo

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  1. S. A. Pooley
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  2. G. S. Canessa
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  3. B. L. Rivas
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  4. E. Espejo
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Pooley, S.A., Canessa, G.S., Rivas, B.L. et al. Spontaneous copolymerization of N-(2-hydroxyethyl)ethyleneimine with isatoic anhydride. Polymer Bulletin 39, 407–414 (1997). https://doi.org/10.1007/s002890050166

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  • DOI: https://doi.org/10.1007/s002890050166

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