Abstract
Polyazomethine polymers were prepared from the polycondensation of terephthaldehye with different diamines, namely, benzidine, 2,3-diaminopyridine, 1,4-diaminoanthraquinone and 3,5 diamino-1,2,4-triazole. The electrical conductivities of the polymers were studied with doping with H2SO4 and 5% I2 together with the undoped polymers. The crystallinity and morphology of the polymers were studied using XRD and scanning electron microscopy. A comparative study of the electrical conductivities of oligomers of polyazomethines and those of their corresponding polymers was performed.
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References
Hall HK (1988) J Macromol Sci Chem A25: 729
Patil AO, Heeger AJ, Wudl F, (1988) Chem Rev 88: 192
Li X, Jiao Y, Li S (1991) Eur Polym J 27: 1345
Dao LH, Leclerc M, Guay J, Chevalier JW (1989) Syn Met 29: E377
Amin M, Mounir M, El-Shekeil A, Darwish KA, Abu Elez M, (1993) Makromol. Chem 208: 17
Amin M, El-Shekeil A, Mounir M, Darwish KA, Abu Elez M, (1991) Makromol. Chem 193: 13
El-Shekeil A, Skanidy S, Al-Yusufy F (1996) Poly Intl, in press
Snell JM, Weissberger H (1963) Organic Synthesis, Collective v. III, 788–789.
Brewster, Vander, Werf, Mc Ewen (1977) Unitized Experiments in Organic Chemistry, 4th Edition
Abd-Alla MA, Aly KI (1990) High Perf Polym 2: 4
Everaerts A, Roberts S, Hall H K (1986) J Pol Sci Chem 24: 1703
Tager A (1972) Physical Chemistry of Polymers, Mir Publishers, Moscow USSR
Al-Dujaili AH, Shalash RJ, Yasagh TS (1990) Eur Polym J 26(9): 948
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El-Shekeil, A.G., Hamid, SA.M.K. & Ali, D.A. Synthesis and characterization of some polyazomethine conducting polymers and oligomers. Polymer Bulletin 39, 1–7 (1997). https://doi.org/10.1007/s002890050112
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DOI: https://doi.org/10.1007/s002890050112