Abstract
Composites are fabricating by reinforcing waste bambara nut shell powder (BNSP) as a bio-filler into an epoxy resin matrix. The composite is fabricated by varying the mass fractions of filler in the range of 5–35 wt%. The effects of bio-filler content on physical, mechanical, and thermal properties are evaluated. The studies reveal that the tensile strength, tensile modulus, flexural strength, and impact strength increased with increasing bio-filler content. The highest mechanical properties of BNSP-loaded epoxy composites are achieved at bio-filler mass content of 15 wt%, whereas hardness increased for 5–35 wt% with peak value at 35 wt%. The water absorption and thickness swelling of the BNSF/epoxy composites increased with increasing bio-filler contents, while the density decreased with an increase in bio-filler content. The TGA results revealed that an increasing bio-filler content decreased thermal stability, whereas the Tg and Tm of the composites increased with increasing bio-filler content.
Similar content being viewed by others
Data Availability
No datasets were generated or analysed during the current study.
References
Jha A, Kumar A (2019) Biobased technologies for the efficient extraction of biopolymers from waste biomass. Bioprocess Biosyst Eng 42(12):1893–1901. https://doi.org/10.1007/s00449-019-02199-2
Srivastava RK, Shetti NP, Reddy KR, Kwon EE, Nadagouda MN, Aminabhavi TM (2021) Biomass utilization and production of biofuels from carbon neutral materials. Environ Pollut 276:116731. https://doi.org/10.1016/j.envpol.2021.116731
Andrew JJ, Dhakal HN (2022) Sustainable biobased composites for advanced applications: recent trends and future opportunities—a critical review. Compos Part C 7:100220. https://doi.org/10.1016/j.jcomc.2021.100220
Anwajler B, Zdybel E, Tomaszewska-Ciosk E (2023) Innovative polymer composites with natural fillers produced by additive manufacturing (3D printing)—a literature review. Polymers (Basel) 15(17):1–19. https://doi.org/10.3390/polym15173534
Kaur M, Mehta A, Bhardwaj KK, Gupta R (2020) Bionanomaterials from agricultural wastes. Adv Struct Mater 126:243–260. https://doi.org/10.1007/978-981-15-3560-4_10
Phiri R, Mavinkere Rangappa S, Siengchin S, Oladijo OP, Dhakal HN (2023) Development of sustainable biopolymer-based composites for lightweight applications from agricultural waste biomass: a review. Adv Ind Eng Polym Res 6(4):436–450. https://doi.org/10.1016/j.aiepr.2023.04.004
Schirp A, Ibach RE, Pendleton DE, Wolcott MP (2008) Biological degradation of Wood-Plastic Composites (WPC) and strategies for improving the resistance of WPC against biological decay. ACS Symp Ser 982:480–507. https://doi.org/10.1021/bk-2008-0982.ch029
Wang YC, Wong PMH, Kodur V (2007) An experimental study of the mechanical properties of fibre reinforced polymer (FRP) and steel reinforcing bars at elevated temperatures. Compos Struct 80(1):131–140. https://doi.org/10.1016/j.compstruct.2006.04.069
Ashori A, Bahreini Z (2009) Evaluation of calotropis gigantea as a promising raw material for fiber-reinforced composite. J Compos Mater 43(11):1297–1304. https://doi.org/10.1177/0021998308104526
Mohite AS, Jagtap AR, Avhad MS, More AP (2022) Recycling of major agriculture crop residues and its application in polymer industry: a review in the context of waste to energy nexus. Energy Nexus 7:100134. https://doi.org/10.1016/j.nexus.2022.100134
Oladele IO, Omotosho TF, Adediran AA (2020) Polymer-based composites: an indispensable material for present and future applications. Int J Polym Sci 2020:1–12. https://doi.org/10.1155/2020/8834518
Hassan BB, Awopetu OO (2019) Production and characterization of particle boards from common agro wastes in Nigeria. Int J Innov Sci Res Technol 4(1):637–642
Oluwole FA, Abdulrahim AT, Oumarou MB (2007) Development and performance evaluation of impact bambara groundnut sheller. Int Agrophys 21(3):269–274
Alamri H, Low IM (2012) Mechanical properties and water absorption behaviour of recycled cellulose fibre reinforced epoxy composites. Polym Test 31(5):620–628. https://doi.org/10.1016/j.polymertesting.2012.04.002
Prasad L, Singh G, Yadav A, Kumar V, Kumar A (2019) Properties of functionally gradient composites reinforced with waste natural fillers. Acta Period Technol 50:250–259. https://doi.org/10.2298/APT1950250P
Eze WU, Kuzmin A, Ugbaja MI, Bayero AH (2022) Effect of nano-structured Bambara nut shell (Vigna subterranea (L.) Verdc) as effect of nano-structured Bambara nut shell (Vigna subterranea (L.) Verdc) as filler on the physical, mechanical and morphological properties of epoxy matrix. J Mater Environ Sci 13(10):1155–1170
Gital DY, Raji A (2022) Development of polymer—Bambaranut shell composite for structural board application. Eur J Mater Sci Eng 7(1):15–27. https://doi.org/10.36868/ejmse.2022.07.01.015
Imoisili PE, Jen TC (2022) Mechanical and acoustic performance of plantain (Musa paradisiacal) fibre reinforced epoxy bio-composite. J Nat Fibers 19(15):11658–11665. https://doi.org/10.1080/15440478.2022.2036289
Chukwutoo C, Emeka C, Onwusoronye U, Nnaemeka S (2023) Advanced industrial and engineering polymer research modelling creep responses of plantain fibre reinforced HDPE (PFRHDPE) for elevated temperature applications. Adv Ind Eng Polym Res 6(1):49–61. https://doi.org/10.1016/j.aiepr.2022.06.001
Imoisili PE, Jen TC (2020) Mechanical and water absorption behaviour of potassium permanganate (KMnO4) treated plantain (Musa paradisiaca) fibre/epoxy bio-composites. Integr Med Res 9(4):8705–8713. https://doi.org/10.1016/j.jmrt.2020.05.121
Imoisili PE, Jen TC (2020) Performance characteristics of unsaturated polyester reinforced with high frequency microwave treated natural fibre performance characteristics of unsaturated polyester reinforced with high frequency microwave treated natural. Int Conf Eng Sustain World 1107(012029):1–8. https://doi.org/10.1088/1757-899X/1107/1/012029
Imoisili PE, Jen TC (2021) Modelling and optimization of the impact strength of plantain (Musa paradisiacal) fibre/MWCNT hybrid nanocomposite using response surface methodology. J Mater Res Technol. https://doi.org/10.1016/j.jmrt.2021.05.101
Jawaid M, Siengchin S (2019) Hybrid composites: a versatile materials for future. Appl Sci Eng Prog 12(4):223. https://doi.org/10.14416/j.asep.2019.09.002
Rangappa SM, Siengchin S, Dhakal HN (2020) Green-composites: ecofriendly and sustainability. Appl Sci Eng Prog 13(3):183–184. https://doi.org/10.14416/j.asep.2020.06.001
Siengchin S (2023) A review on lightweight materials for defence applications: present and future developments. Def Technol 24:1–17. https://doi.org/10.1016/j.dt.2023.02.025
Waluyo J et al (2023) Characterization of biochar briquettes from coconut shell with the effect of binder: molasses, cow manure and horse manure. Evergreen 10(1):539–545. https://doi.org/10.5109/6782158
Nath S, Jena H, Priyanka SD (2019) Analysis of mechanical properties of jute epoxy composite with cenosphere filler. SILICON 11(2):659–671. https://doi.org/10.1007/s12633-018-9941-x
Nukala SG, Kong I, Patel VI, Kakarla AB, Kong W, Buddrick O (2022) Development of biodegradable composites using polycaprolactone and bamboo powder. Polymers (Basel) 14(19):1–17. https://doi.org/10.3390/polym14194169
Chandrika VS et al (2022) Natural fiber incorporated polymer matrix composites for electronic circuit board applications. Adv Mater Sci Eng 2022:1–9. https://doi.org/10.1155/2022/3035169
de Oliveira N, Júnior J, Perissé Duarte Lopes F, Tonini Simonassi N, Souza D, Neves Monteiro S, Fontes Vieira CM (2023) Evaluation of the physical properties of composite panels with eucalyptus sawdust waste and castor oil-based polyurethane. J Mater Res Technol 23:1084–1093. https://doi.org/10.1016/j.jmrt.2023.01.067
de Oliveira Júnior JN, Lopes FPD, Simonassi NT, Oliveira MP, Gonçalves FG, Vieira CMF (2023) Evaluation of hot pressing processing by physical properties of ecofriendly composites reinforced by eucalyptus sawdust and chamotte residues. Polymers (Basel) 15(8):1–12. https://doi.org/10.3390/polym15081931
Kuram E (2022) Advances in development of green composites based on natural fibers: a review. Emerg Mater 5(3):811–831. https://doi.org/10.1007/s42247-021-00279-2
Mpotokwane SM, Gaditlhatlhelwe E, Sebaka A, Jideani VA (2008) Physical properties of bambara groundnuts from Botswana. J Food Eng 89(1):93–98. https://doi.org/10.1016/j.jfoodeng.2008.04.006
Alaneme GU, Mbadike EM (2021) Experimental investigation of Bambara nut shell ash in the production of concrete and mortar. Innov Infrastruct Solut 6(2):1–14. https://doi.org/10.1007/s41062-020-00445-1
Okonkwo EG et al (2020) Mechanical and thermomechanical properties of clay-Bambara nut shell polyester bio-composite. Int J Adv Manuf Technol 108(7–8):2483–2496. https://doi.org/10.1007/s00170-020-05570-w
Loganathan L, Saravanakumar SS (2021) Physico—chemical and tensile properties of green bio-films from poly(vinyl alcohol)/nano ground nutshell filler. J Nat Fibers 00(00):1–12. https://doi.org/10.1080/15440478.2020.1863289
Huang L et al (2015) Spherical and flake-like BN filled epoxy composites: morphological effect on the thermal conductivity, thermo-mechanical and dielectric properties. J Mater Sci Mater Electron 26(6):3564–3572. https://doi.org/10.1007/s10854-015-2870-1
Zhang H et al (2019) Optimization of boron nitride sphere loading in epoxy: Enhanced thermal conductivity and excellent electrical insulation. Polymers (Basel) 11(8):1–14. https://doi.org/10.3390/polym11081335
Azeez TO, Olaitan SA, Atuanya CU, Onukwuli DO, Akagu CC, Menkiti MC (2013) Effect of filler weight fraction on the mechanical properties of Bambara groundnut (Okpa) husk polyethylene composite. Int J Curr Res 5(7):1714–1717
Kuranchie C, Yaya A, Bensah YD (2021) The effect of natural fibre reinforcement on polyurethane composite foams—a review. Sci Afr 11:e00722. https://doi.org/10.1016/j.sciaf.2021.e00722
Nanda T, Singh K, Shelly D, Mehta R (2021) Advancements in multi-scale filler reinforced epoxy nanocomposites for improved impact strength: a review. Crit Rev Solid State Mater Sci 46(4):281–329. https://doi.org/10.1080/10408436.2020.1777934
Alshammari BA, Wilkinson AN, Alotaibi BM, Alotibi MF (2022) Influence of carbon micro-and nano-fillers on the viscoelastic properties of polyethylene terephthalate. Polymers (Basel) 14(12):1–17. https://doi.org/10.3390/polym14122440
Masłowski M, Miedzianowska J, Strzelec K (2018) Influence of wheat, rye, and triticale straw on the properties of natural rubber composites. Adv Polym Technol 37(8):2866–2878. https://doi.org/10.1002/adv.21958
Nair MM, Shetty N, Alva PP, Shetty SD (2021) Effect of sawdust impregnation on long coir fibers reinforced with epoxy matrix. Int J Adv Appl Sci. https://doi.org/10.21833/ijaas.2018.03.010
Panneer R (2017) Effect of composition of fibers on properties of hybrid composites. Int J Manuf Mater Mech Eng 7(4):28–43. https://doi.org/10.4018/IJMMME.2017100103
Sałasińska K et al (2022) The effect of manufacture process on mechanical properties and burning behavior of epoxy-based hybrid composites. Materials (Basel) 15(1):1–15. https://doi.org/10.3390/ma15010301
Acknowledgements
The authors are grateful to our respective universities for creating the enabling environment for this work.
Author information
Authors and Affiliations
Contributions
AOO, JUI involved in conceptualization; FNA, COI involved in experimental design; MAA, PUN involved in carrying out measurements and manuscript composition; MOC involved in writing; FNA, AOO involved in editing and supervision. All the authors have read and agreed to the final published version of this manuscript.
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that there is no known competing interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Ogah, A.O., Archibong, F.N., Allen, M.A. et al. Evaluation of physical, mechanical and thermal properties of epoxy composites filled with bio-fiber derived from Bambara nut shell filler. Polym. Bull. (2024). https://doi.org/10.1007/s00289-024-05227-8
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00289-024-05227-8