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Conjugate electrospun photochromic adjustable magnetic bifunctional Janus-structure nanofibers array

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Abstract

Using conjugate electrospinning technology to prepare Janus-structure nanofiber array and endow it with multifunctional characteristics is a very meaningful research topic. Here, photochromic adjustable magnetic bifunctional {[Eu(BA)3phen (EBP) + Tb(BA)3phen (TBP)]/polyvinylpyrrolidone (PVP)}//[Fe3O4/PVP] Janus-structure nanofiber array (defined as PM-JNA) is constructed by conjugate electrospinning. Janus-structure nanofibers are arranged in a micro-orientation, and most nanofibers have a special Janus structure. This structure confines the magnetic material and fluorescent material in two nanofibers, respectively, reduces the influence of magnetic material on fluorescence intensity, and significantly improves the fluorescence performance of the specimen. The using of conjugate electrospinning solves the problem of mutual diffusion of spinning liquid in the spinneret in parallel electrospinning and improves the separation efficiency of fluorescent substances and magnetic substances. Adjustable magnetic and luminous colors can be obtained by changing the contents of Fe3O4, EBP and TBP. Janus-structure nanofibers have been widely used in biological monitoring, medical imaging, nanodevices and multifunctional materials.

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Acknowledgements

This work was financially sponsored by Natural Science Foundation of Jilin Province of China (YDZJ202201ZYTS388, YDZJ202101ZYTS130, YDZJ202101ZYTS059), Science and Technology Research Project of the Education Department of Jilin Province (JJKH20230327KJ), National Natural Science Foundation of China (52173155), Natural Science Foundation of Chongqing, China (cstc2021jcyj-msxmX1076, cstc2021jcyj-msxmX0798) and the Open Project Program of Key Laboratory of Preparation and Application of Environmentally Friendly Materials (Jilin Normal University), Ministry of Education, China (No. 2019015).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Ji Lin Jian Zhu University, Changchun, 130018, China

    Haina Qi & Xuejian Zhang

  2. Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, Changchun University of Science and Technology, Changchun, 130022, China

    Guoyi Wang, Yaolin Hu, Hong Shao, Qianli Ma, Dan Li, Wensheng Yu & Xiangting Dong

  3. Key Laboratory of Preparation and Application of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Changchun, 130103, China

    Limin Chang

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Qi, H., Wang, G., Hu, Y. et al. Conjugate electrospun photochromic adjustable magnetic bifunctional Janus-structure nanofibers array. Polym. Bull. 81, 2685–2700 (2024). https://doi.org/10.1007/s00289-023-04854-x

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