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Enhanced thermal and structural properties of UHMWPE/CNT nanocomposite sheets prepared by using melt compounding technique

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In this study thermal and structural properties characterization were performed for prepared ultra-high molecular weight polyethylene/carbon nanotube (UHMWPE/CNT) nanocomposite sheets by using a melt compounding method. The sheets were prepared by using six types of CNTs; pristine single walled CNTs (SWCNTs) and multi-walled CNTs (MWCNTs), oxidized- SWCNT and MWCNT, and amide- SWCNT and MWCNT. Thermogravimetric analysis results revealed that the addition of CNTs increased the nanocomposites thermal stability (17 °C) being produced by P-MWCNT. Differential scanning calorimetry and x-ray diffraction (XRD) results show no significant crystalline structure changes compared with the pure polymer, and increase in crystallinity (4%) for O-SWCNTs additions (4%). Scanning electron microscope images showed improved bridging in the polymer matrix by using oxidized and functionalized CNTs compared with pristine CNTs. These findings suggest that the durability of UHMWPE is enhanced by this nano-modification method, improving its suitability for many lightweight, high strength material applications.

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This research was funded by “King Abdullah II Design and Development Bureau” and the “Deanship of academic research (DAR)/ The University of Jordan”, Amman, Jordan.

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Authors and Affiliations



Conceptualization, AAB and RAZ; methodology, AB; formal analysis, RAZ and AB; investigation, AAB and RAZ; resources, YM; data curation, AK and AB; writing—original draft preparation, AB; writing—review and editing, YM, RAZ, AK and AAB; visualization, RAZ and YM; supervision, AAB and RAZ; project administration, AAB, RAZ and YM; funding acquisition, YM and AAB. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Abeer Al Bawab or Rund Abu-Zurayk.

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Al Bawab, A., Bozeya, A., Makableh, Y.F. et al. Enhanced thermal and structural properties of UHMWPE/CNT nanocomposite sheets prepared by using melt compounding technique. Polym. Bull. 80, 12433–12445 (2023).

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