Abstract
In recent years, water purification by membrane desalination techniques has been growing drastically; after all, water scarcity is a significant issue to deal with in some parts of the world. To put one step forward toward resolving the issue of water scarcity, the best way is to upgrade the current desalination technique and membranes so that the output of clear water will be improved. In this review, we will focus on enhancing some crucial properties of the Polyamide (PA) and Polyimide (PI) membranes by incorporating some functional additives. Ag NPs (Silver nanoparticles), Cu NPs (Copper nanoparticles), GO (Graphene oxide), SWCNT (Single-walled carbon nanotube), and MWCNT (multi-walled carbon nanotube) are some of the additives which can be used with PA/PI active layer to improve some essential properties of membrane-like antifouling, biofouling, low water flux, selectivity, permeability, hydrophilicity, hydrophobicity, etc. The deposition of such additives onto the surface of the Polyimide/Polyamide coat or membrane can be done using interfacial polymerization or phase inversion. Membrane filtration can be done using reverse osmosis and electrodialysis techniques. A thin-film composite membrane comprising PA and MWCNTs, yielded a water flux of almost 25.9 L m−2 h−1, with a salt rejection of 98.1% exhibiting excellent hydrophilicity with a water contact angle of 59.6°.
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Abbreviations
- aCN/AP:
-
Silver phosphate-loaded acidified graphitic carbon nitride
- Ag:
-
Silver
- Ag NPs:
-
Silver nanoparticles
- AgNO3 :
-
Silver nitrate
- CNT:
-
Carbon nanotube
- Cu:
-
Copper
- CuCl2·2H2O:
-
Dehydrated copper chloride
- CuNPs:
-
Copper nanoparticles
- DAPPC:
-
1,4-Bis(3-aminopropyl)-piperazine propane carboxylate
- ED:
-
Electrodialysis
- GO:
-
Graphene oxide
- GO NPs:
-
Graphene oxide nanoparticles
- GOQD:
-
Graphene oxide quantum dots
- IP:
-
Interfacial polymerization
- MED:
-
Multi-effect desalination
- MOF:
-
Metal organic framework
- MSF:
-
Multistage flash desalination
- MTFN:
-
Multifunctional thin-film nanocomposite
- MMM:
-
Mix matrix membrane
- MPD:
-
M-phenylene diamine
- MWCNT:
-
Muti-walled carbon nanotube
- Na2SO3 :
-
Sodium sulfite
- Na2SO4 :
-
Sodium sulfate
- NaCl:
-
Sodium chloride
- PA:
-
Polyamide
- PAN:
-
Polyacrylonitrile
- PEI:
-
Polyethyleneimine
- PES:
-
Polyethersulfone
- PI:
-
Polyimide
- PIP:
-
Piperazine
- PSF:
-
Polysulfone
- PVDF:
-
Polyvinylidene fluoride
- PVP:
-
Polyvinyl pyrrolidone
- RO:
-
Reverse osmosis
- SPI:
-
Sulfonated polyimide
- SWCNT:
-
Single-walled carbon nanotube
- T (\(^\circ{\rm C} )\) :
-
Temperature
- TFC:
-
Thin-film nanocomposite
- TiO2 :
-
Titanium dioxide
- TMC:
-
Trimesoyl chloride
- TNT:
-
Titania nanotubes
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Acknowledgements
The author would like to acknowledge Dr. S. P. Bhosle, Principal & Head, Maharashtra Institute of Technology, Aurangabad, Dr. Aniruddha Chatterjee, Head of Department, Plastic and polymer engineering, Maharashtra Institute of Technology, Aurangabad and Mrs. Suranjana Mandal, Associate Professor, Maharashtra Institute of Technology, Aurangabad and Dr. CP Ramanarayanan, Vice Chancellor of DIAT (DU), Pune, for their continuous encouragement and support. Authors wish to extend special thanks to Dr. Amrita Nighojkar, Miss. Niranjana Jaya Prakash, Mr. Jigar Patadiya, and Miss. Alsha Subash for their unwavering and continuous technical support throughout the review writing. The authors are thankful to the editors and anonymous reviewers who has helped in enhancing the quality of the manuscript.
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Y A Ghodke contributed in Material preparation, data collection analysis and writing of the article. N Mayilswamy contributed to material preparation and writing of the article. B Kandasubramanian made substantial contribution to conceptualization, discussion and reviewed the manuscript before submission.
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Ghodke, Y.A., Mayilswamy, N. & Kandasubramanian, B. Polyamide (PA)- and Polyimide (PI)-based membranes for desalination application. Polym. Bull. 80, 10661–10695 (2023). https://doi.org/10.1007/s00289-022-04559-7
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DOI: https://doi.org/10.1007/s00289-022-04559-7