Skip to main content
Log in

Effect of crystallization and packing pressure on the development of residual stresses on injection molded polypropylene samples

  • Original Paper
  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

Thermoplastics processing usually involves the non-uniform cooling of molten polymer, which results in the presence of residual stresses in the final product. The magnitude of these stresses can be high enough to induce severe shape changes in the product, as well as changes in the overall material performance. Because of this, it is important to be able to accurately predict and measure them. In this study, the effect of coupling a kinetic model of crystallization on the prediction of thermal and pressure-induced residual stresses using the residual temperature field and formation pressure concepts is investigated. In addition, the effect of packing pressure on the deflection of injection molded polymer plates after ejection is reported. Simulation results were compared with experimental data, and it was found that considering crystallization in the prediction of residual stresses decreased the % error between predicted deflection and experimental results, from 0.52–7.34 to 3.056.3%. Also, good agreement between experimental results and the simulations performed using the residual temperature and pressure fields concepts in 2D while including a kinetic model of crystallization with different packing pressures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Thakkar BS, Broutman LJ (1980) The influence of residual stresses and orientation on the properties of amorphous polymers. Polym Eng Sci 20(18):1214–1219

    Article  CAS  Google Scholar 

  2. Chaoui K, Chudnovsky A, Moet A (1987) Effect of residual stress on crack propagation in MDPE pipes. J Mater Sci 22:3873–3879

    Article  CAS  Google Scholar 

  3. Hornberger LE, Devries KL (1987) The effect of residual stress on the mechanical properties of glassy polymers. Polym Eng Sci 27(19):1473–1478

    Article  CAS  Google Scholar 

  4. Guevara-Morales A, Figueroa-López U (2014) Residual stresses in injection molded products. J Mater Sci 49:4399–4415

    Article  CAS  Google Scholar 

  5. Baaijens FPT (1991) Calculation of residual stresses in injection molded products (in English). Rheola Acta 30(3):284–299. https://doi.org/10.1007/BF00366642

    Article  CAS  Google Scholar 

  6. Daly HB, Nguyen K, Sanschagrin B, Cole K (1998) Build-up and measurement of molecular orientation, crystalline morphology, and residual stresses in injection molded parts: a review. J Inject Molding Technol (USA) 2(2):59–85

    CAS  Google Scholar 

  7. Isayev AI, Crouthamel DL (1984) Residual stress development in the injection molding of polymers. Polymer-Plastics Technol Eng 22(2):177–232. https://doi.org/10.1080/03602558408070038

    Article  CAS  Google Scholar 

  8. Kamal MR, Lai-Fook RA, Hernandez-Aguilar JR (2002) Residual thermal stresses in injection moldings of thermoplastics: a theoretical and experimental study. Polym Eng Sci 42(5):1098–1114. https://doi.org/10.1002/pen.11015

    Article  CAS  Google Scholar 

  9. Jansen KMB, Pantani R, Titomanlio G (1998) As-molded shrinkage measurements on polystyrene injection molded products. Polym Eng Sci 38(2):254–264. https://doi.org/10.1002/pen.10186

    Article  CAS  Google Scholar 

  10. Jansen KMB, Van Dijk DJ, Freriksen MJA (1998) Shrinkage anisotropy in fiber reinforced injection molded products. Polym Compos 19(4):325–334. https://doi.org/10.1002/pc.10105

    Article  CAS  Google Scholar 

  11. Wagner J, Phillips PJ (2001) The mechanism of crystallization of linear polyethylene, and its copolymers with octene, over a wide range of supercoolings. Polymer. 42(21):8999–9013

    Article  CAS  Google Scholar 

  12. Phillips R, Manson JE (1997) Prediction and analysis of nonisothermal crystallization of polymers. J Polym Sci Part B: Polym Phys 35(6):875–888

    Article  CAS  Google Scholar 

  13. Tropsa V, Ivankovic A, Williams JG (2000) Predicting residual stresses due to solidification in cast plastic plates. Plast, Rubber Compos 29(9):468–474

    Article  CAS  Google Scholar 

  14. Tropsa V (2001) Predicting residual stresses due to solidification in cast plastic plates, PhD, Mechanical Engineering Department, Imperial College of Science, Technology and Medicine, London, UK

  15. Jansen K (1994) Residual stresses in quenched and injection moulded products. Int Polym Proc 9(1):82–89

    Article  CAS  Google Scholar 

  16. Estrella-Guayasamin M, Figueroa-López U, Guevara-Morales A (2019) Prediction of residual stresses in injection-molded plates using the residual temperature field concept. Polym Eng Sci 59(11):2220–2230. https://doi.org/10.1002/pen.25225

    Article  CAS  Google Scholar 

  17. Zhang X, Fujii M (2003) Measurements of the thermal conductivity and thermal diffusivity of polymers. Polym Eng Sci 43(11):1755–1764

    Article  CAS  Google Scholar 

  18. Choe CR, Lee KH (1989) Nonisothermal crystallization kinetics of poly (etheretherketone) (PEEK). Polym Eng Sci 29(12):801–805

    Article  CAS  Google Scholar 

  19. Tobin MC (1974) Theory of phase transition kinetics with growth site impingement. I. homogeneous nucleation. J Polym Sci 12:399–406

    CAS  Google Scholar 

  20. Zoetelief WF, Douven LFA, Ingen Housz AJ (1996) Residual thermal stresses in injection molded products. Polym Eng Sci 36(14):1886–1896

    Article  CAS  Google Scholar 

  21. Huang M-C, Tai C-C (2001) The effective factors in the warpage problem of an injection-molded part with a thin shell feature. J Mater Process Technol 110(1):1–9. https://doi.org/10.1016/S0924-0136(00)00649-X

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors would like to gratefully acknowledge the financial support from the Mexican National Council for Science and Technology (CONACyT).

Author information

Authors and Affiliations

Authors

Contributions

ME-G: Investigation, other contributions. UF-L: Conceptualization, Methodology, Supervision, Formal Analysis. AG-M: Conceptualization, Methodology, Supervision, Formal Analysis, Writing–Review and Editing. RAG-L: Formal Analysis, Writing Original draft and Editing.

Corresponding authors

Correspondence to U. Figueroa-López, A. Guevara-Morales or R. A. García-León.

Ethics declarations

Conflict of Interest

The authors declare that they have no conflicts of interest to this work.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Estrella-Guayasamin, M., Figueroa-López, U., Guevara-Morales, A. et al. Effect of crystallization and packing pressure on the development of residual stresses on injection molded polypropylene samples. Polym. Bull. 80, 4355–4369 (2023). https://doi.org/10.1007/s00289-022-04276-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-022-04276-1

Keywords

Navigation