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Octenyl succinate acidolysis carboxymethyl sesbania gum with high esterification degree: preparation, characterization and performance

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Abstract

High esterification of acidolysis carboxymethyl sesbania gum was successfully accomplished by using 1-butyl-3-methylimidazolium chloride (ionic liquid) as a solvent, octenyl succinic anhydride as an esterifying agent, pyridine as a catalyst. The goal derivatives were characterized by FT-IR, TGA, SEM, XRD and so on. The experimental results indicated that octenyl succinate acidolysis carboxymethyl sesbania gum as a novel hydrophobic material had a very well emulsifying capacity (79.5%) and stability (78.9%). The effect of acidolysis on the crystalline structure of sesbania gum (SG) was different from the carboxymethylation. The esterification entirely destroyed the crystalline structure. The surface of SG particles would become rougher and rougher with the successive completion of carboxymethylation, acidolysis and esterification. The energy storage modulus of SG and SG derivatives increased with the increase in angular frequency, but the energy storage modulus of carboxymethyl sesbania gum increased in a different way. The peaks of C=O and C=C bonds appeared at 1735.0 cm−1 and 1630.0 cm−1 due to introduction of the carboxymethyl and octenyl succinate groups into SG molecular chains. Not only does SG show excellent performance in promoting the hydrophilicity and permeability due to containing large amounts of hydroxide radicals, but also SG is non-toxic and biodegradable.

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  1. School of Environmental and Chemical Engineering, Shenyang University of Technology, Shenyang, 110870, China

    Hongbo Tang, Yihan Liu, Yanping Li & Xiaojun Liu

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  1. Hongbo Tang
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Correspondence to Hongbo Tang.

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Tang, H., Liu, Y., Li, Y. et al. Octenyl succinate acidolysis carboxymethyl sesbania gum with high esterification degree: preparation, characterization and performance. Polym. Bull. 80, 3819–3841 (2023). https://doi.org/10.1007/s00289-022-04218-x

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  • DOI: https://doi.org/10.1007/s00289-022-04218-x

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