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A new [Cu4S6]-cluster compound with intense luminescence and repairasion effect on ischemia–reperfusion flaps

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Abstract

Presented here is the synthesis and property study of a novel Cu(I) compound, namely, [Cu4(2-S-Bim)7(SO4)]n·n(SO4)·n(CH3CN)·2n(H2O) (1, 2-S-Bim=2-mercaptobenzimidazole). In this compound, 2-S-Bim ligand exhibits two different coordination modes: μ2-bridging mode and terminal coordination mode. Six 2-S-Bim ligands in μ2-bridging mode combined four Cu(I) ions together, affording a [Cu4S6] cluster. The remaining two coordination sites of Cu(I) ions in the [Cu4S6] cluster are occupied by one terminal 2-S-Bim ligand and one terminal SO42− anion, thus compound 1 exhibits a 0D isolated cluster-based framework. Moreover, this compound emits intense blue luminescence at room temperature. In addition, the as-produced compound’s application values against ischemia–reperfusion flaps were examined and the specific mechanism was tested simultaneously.

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Scheme 1
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Data Availability

The excitation spectra of the ligand and complex 1 (Fig. S1), the information could be found in the supporting information file.

References

  1. Grover R, Sanders R (1998) Plastic surgery. BMJ 317:397–400

    Article  CAS  Google Scholar 

  2. Davis JS (2016) Plastic and reconstructive surgery. JAMA 316:353

    Article  Google Scholar 

  3. Qiu D, Wang X, Wang X, Jiao Y, Li Y, Jiang D (2019) Risk factors for necrosis of skin flap-like wounds after ED debridement and suture. Am J Emerg Med 37:828–831

  4. Meng HH, Wang CY, Xi W, Song XQ, Wang L (2019) A cationic tetrahedral Zn(ii) cluster based on a new salicylamide imine multidentate ligand: synthesis, structure and fluorescence sensing study. Dalton Trans 48:12326–12325

    Article  CAS  Google Scholar 

  5. Bala S, Bhattacharya S, Goswami A, Adhikary A, Konar S, Mondal R (2014) Designing functional metal-organic frameworks by imparting a hexanuclear copper-based secondary building unit specific properties: structural correlation with magnetic and photocatalytic activity. Cryst Growth & Des 14:6391–6398

    Article  CAS  Google Scholar 

  6. Wang Y, Yang GP, Zhang PF, Ma LL, Wang JM, Li GP, Wang YY (2021) Microporous Cd(II) metal-organic framework for CO2 catalysis, luminescent sensing, and absorption of methyl green. Cryst Growth Des 21:2734–2743

    Article  CAS  Google Scholar 

  7. Ye YS, Yi WM, Zhuang PL, Lu YJ, Liang YC, Chang SH (2021) Two Cu(II)-based coordination polymers: magnetic properties and preventative effect on periodontitis via inhibiting plaque formation. J Phys Chem Solids 148:109690

  8. He T, Zhang YZ, Kong XJ, Lv XL, Xie LH, Li JR (2019) Unique T-shaped ligand as a new platform for metal-organic frameworks. Cryst Growth & Des 19:430–436

    Article  CAS  Google Scholar 

  9. Zhang X, Yang JX, Zhang J, Cheng JK, Sun ML, Yao YG (2011) A new open framework material based on designed semi-rigid T-shaped tricarboxylate ligand. Inorg Chem Commun 14:986–989

    Article  CAS  Google Scholar 

  10. Nakhaei M, Akhbari K, Phuruangrat A (2021) Synthesis and characterization of silver and copper metal-organic hybrid nanomaterials and their biological application. Colloid Polym Sci 299:773–781

    Article  CAS  Google Scholar 

  11. Rogovoy MI, Tomilenko AV, Samsonenko DG, Nedolya NA, Rakhmanova MI, Artem’ev AV (2020) New silver(I) thiazole-based coordination polymers: structural and photophysical investigation. Mendeleev Commun 30:728–730

  12. Singh A, Singh A, Singh N, Jang DO (2017) A 2-mercaptobenzimidazole-based emissive Cu(I) complex for selective determination of iodide with large Stokes shift. Sensor Actuat B-Chem 243:372–379

    Article  CAS  Google Scholar 

  13. Rogovoy MI, Samsonenko DG, Rakhmanova MI, Artem’ev AV (2019) Self-assembly of Ag(I)-based complexes and layered coordination polymers bridged by (2-thiazolyl)sulfides. Inorg Chim Acta 489:19–26

  14. Chen SC, Yu RM, Zhao ZG, Chen SM, Zhang QS, Wu XY, Wang F, Lu CZ (2010) A series of polynuclear complexes of d10 metals with interesting luminescent properties. Cryst Growth Des 10:1155–1160

    Article  CAS  Google Scholar 

  15. Shang J, Wu XY, Wang F, Yang WB, Yu RM, Lu CZ (2012) A new 3D Cu(I) coordination polymer with 4-connected umv topological network. Inorg Chem Commun 22:190–192

    Article  CAS  Google Scholar 

  16. Sun S, Liu LJ, Ma WY, Zhou WX, Li J, Zhang FX (2015) Three complexes of Cu(I) cluster with flexible and rigid ligands: Synthesis, characterization and photoluminescent properties. J Solid State Chem 225:1–7

    Article  CAS  Google Scholar 

  17. Wu Y, Wu X, Fang S, Yang S, Li W, Wang H, Yu X (2017) A novel hexanuclear silver(I) complex with photoluminescence properties. Polyhedron 122:155–160

    Article  CAS  Google Scholar 

  18. Sheldrick GM (2015) Crystal structure refinement with SHELXL. Acta Crystallogr Sect C Struct Chem 71:3–8

    Article  Google Scholar 

  19. van der Sluis P, Spek AL (1990) BYPASS: an effective method for the refinement of crystal structures containing disordered solvent regions. Acta Crystallogr Sect A Crystallogr 46:194–201

    Article  Google Scholar 

  20. Yam VWW, Cheng ECC, Zhu N (2001) A novel polynuclear gold–sulfur cube with an unusually large stokes shift. Angew Chem Int Ed 40:1763–1765

    Article  CAS  Google Scholar 

  21. Xu H, Yip JHK (2003) Novel luminescent tetranuclear and pentanuclear copper(I)−dithiolates. Inorg Chem 42:4492–4494

    Article  CAS  Google Scholar 

  22. Zheng SL, Chen XM (2004) Recent advances in luminescent monomeric, multinuclear, and polymeric Zn(II) and Cd(II) coordination complexes. Aust J Chem 57:703–712

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Hand and Foot Surgery Department, Tianjin Baodi Hospital, Baodi Clinical College of Tianjin Medical University, Tianjin, China

    Junli Dong

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  1. Junli Dong
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Correspondence to Junli Dong.

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Dong, J. A new [Cu4S6]-cluster compound with intense luminescence and repairasion effect on ischemia–reperfusion flaps. Polym. Bull. 80, 1615–1623 (2023). https://doi.org/10.1007/s00289-022-04113-5

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  • DOI: https://doi.org/10.1007/s00289-022-04113-5

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