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Phthalate debranched Canna edulis Ker starch with high degree of substitution: preparation, characterization and property

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Abstract

Debranched Canna edulis Ker starch (DCEKS) was effectively esterified in 1-butyl-3- methylimidazolium chloride (ionic liquid) to shorten the esterification time of phthalic anhydride and enhance the substitution degree. The results indicated that the esterification of phthalic anhydride obviously improved the thermal stability of CEKS, while the debranching slightly increased the thermal stability of CEKS. DCEKS was still a semicrystalline polymer like CEKS, and its crystalline structure was not changed by the debranching, but phthalate debranched Canna edulis Ker starch (PDCEKS) was almost an amorphous polymer due to the high esterification in the ionic liquid. The esterification decreased the average size of DCEKS, whereas the debranching increased the average size. The esterification was unevenly completed on DCEKS particles. Both debranching and esterification could result in a decrease in the freeze–thaw stability, swelling power and viscosity of CEKS. The stretching vibration of benzene rings appeared at the wave numbers of 1598 cm−1, 1077 cm−1 and 640 cm−1.

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Acknowledgements

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Authors and Affiliations

  1. School of Environmental and Chemical Engineering, Shenyang University of Technology, Shenyang, 110870, China

    Tang Hongbo, Zhao Qian, Li Yanping & Liu Xiaojun

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  1. Tang Hongbo
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  2. Zhao Qian
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  3. Li Yanping
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  4. Liu Xiaojun
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Correspondence to Tang Hongbo.

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Hongbo, T., Qian, Z., Yanping, L. et al. Phthalate debranched Canna edulis Ker starch with high degree of substitution: preparation, characterization and property. Polym. Bull. 79, 9485–9501 (2022). https://doi.org/10.1007/s00289-021-03941-1

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  • DOI: https://doi.org/10.1007/s00289-021-03941-1

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