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Polymeric nanocomplexes based on polyaluminophenylsiloxanes

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Abstract

In the present work, polyaluminophenylsiloxanes have been obtained by two methods: the first one consisted in the exchange of sodium phenylsilanolate with aluminum chloride in an anhydrous medium (dimethyl sulfoxide-toluene), while the second one—in the reaction of aluminum acetylacetonate with polyphenylsiloxane under the conditions of mechanochemical activation. The polymers were purified by re-precipitation in the first case and by toluene extraction in the second case. The obtained aluminophenylsiloxanes have been studied by the methods of gel chromatography, diffractometry, and IR and 13C, 29Si, and 27Al NMR spectroscopy. It has been shown that the interaction under the conditions of mechanochemical activation proceeded in two directions: the Si–O–Si bond splitting reaction and the condensation reaction. A comparison of the physical and chemical characteristics of polyaluminophenylsiloxanes has been carried out, and it has been demonstrated that the structure of the PAlPhSi is structurally more homogeneous; aluminophenylsiloxy fragments were present along with siloxyaluminoacetylacetone fragments in PAl(acac)PhSi, which significantly complicated the polymer structure.

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References

  1. Voronkov MG, Malyutina EA, Roman VK (1984) Heterosiloxanes. Nauka, Novosibirsk (In Russian)

    Google Scholar 

  2. Zhdanov AA, Levitskii MM (1989) Advances in the field of organometallic polymers. Nauka, Moscow (In Russian)

    Google Scholar 

  3. Levitskii MM, Zavin BG, Bilyachenko AN (2007) Chemistry of metallasiloxanes. current trends and new concepts. Usp Khim 76:907–926. https://doi.org/10.1070/RC2007v076n09ABEH003691 (In Russian)

    Article  CAS  Google Scholar 

  4. Voronkov MG, Shapkin NP (1990) Phosphorus-containing polymetalloorganosiloxanes. J Organomet Chem 289:169–186

    Article  Google Scholar 

  5. Zavin BG, Sergienko NV, Bilyachenko AN, Chirkun NV, Dronova MS, Korlyukov AA, Starikova OM, Levitskii MM, Timofeeva GI (2011) Synthesis of bimetallic cage-like metalloorganosiloxanes from polymeric metallosiloxanes. Izvestiya RAN 8:1621–1627. https://doi.org/10.1007/s11172-011-0246-0 (In Russian)

    Article  CAS  Google Scholar 

  6. Igonin VA, Shchegolikhina OI, Lindeman SV, Struchkov YuT, Zhdanov AA (1991) Structures of complexes of copper with macrocyclic organosiloxanolate ligands. J Organomet Chem 423:351–356

    Article  Google Scholar 

  7. Andrianov KA, Khanashvili LM (1973) Technology of organometallic monomers and polymers. Khimia, Moscow (In Russian)

    Google Scholar 

  8. Feher FI, Blanski RL (1990) Polyhedral oligometallasilsesquioxanes as models for silica-supported catalysts: chromium attached to two vicinal siloxy groups. J Chem Soc Chem Commun 22:1614–1617

    Article  Google Scholar 

  9. Ponomarenko AG, Chigarenko GG, Bicherov AB, Shirgaeva TA, Konoplev BG, Ageev OA, Kolomitzev AS, Panchenko SB, Chetverikova VA, Garnovsky AD, Minkin VI (2010) Study of lubricating compositions based on polyorganosiloxanes involving azomethine metalocomplexes. J Friction Wear 31:387–397. https://doi.org/10.3103/S1068366610050119

    Article  Google Scholar 

  10. Leont’ev LB, Shapkin NP, Makarov VN (2017) Functional nanostructured tribotechnical materials. Solid State Phenom 265:410–415https://doi.org/10.4028/www.scientific.net/SSP.265.410

    Article  Google Scholar 

  11. Leont’ev LB, Toklikishvili AG, Shapkin NP, Ustinov AY (2015) Russian federation patent. 2559077. Bull. 22

  12. Voronkov MG, Alikovskii AV, Zolotar GY (1985) A new method of the polymetallophenylsiloxanes production. Doklady AN SSSR 281:858–860 (In Russian)

    CAS  Google Scholar 

  13. Kapustina AA, Libanov VV, Shapkin NP (2013) Russian federation patent 2483085. Bull. 15

  14. Kapustina AA, Shapkin NP, Ivanova EB, Lyakhina AA (2005) Possibility of synthesis of polygermanium and polytin organosiloxanes in mechanochemical activation conditions. Russ J General Chem 75:610–613. https://doi.org/10.1007/s11176-005-0273-3 (In Russian)

    Article  CAS  Google Scholar 

  15. Kapustina AA, Shapkin NP, Talashkevich ET (2004) Synthesis of polyferro-polychromodimethylsiloxanes based on 1,7 dipotassiumoxyoctamethyltetrasiloxane in mechanochemical activation conditions. Izvestia vuzov 47:93–96 (In Russian)

    Google Scholar 

  16. Kapustina AA, Shapkin NP, Badanova NA (2011) Study of the interaction of cobalt chloride with polyphenylsiloxane in mechanochemical activation conditions. Izvestia vuzov 54:61–65 (In Russian)

    CAS  Google Scholar 

  17. Pliev TN, Zubkova ND, Turskii YI, Dintsess AI (1969) Vysokomelekulyarnye soedineniya 11A(7): 1544–1557. [In Russian]

  18. Shapkin NP, Kapustina AA, Gardionov SV, Khal’chenko IG (2015) Interaction of Polyphenylsiloxane with Magnesium Acetylacetonate. Russ J General Chem 85:1487–1490. https://doi.org/10.1134/S1070363215060225 (In Russian)

    Article  CAS  Google Scholar 

  19. Shapkin NP, Kapustina AA, Gardionov SV, Khalchenko IG, Libanov VV, Tokar EA (2019) Studies of interaction of polyphenylsiloxane with vanadyl bis-acetylacetonate. Silicon 11:2261–2266. https://doi.org/10.1007/s12633-017-9551-z

    Article  CAS  Google Scholar 

  20. Shapkin NP, Razov VI, Korotchensev VV, Tokar EA, Gardionov SV, Panasenko AE, Khalchenko IG, Balanov MI, Slobodyuk AB (2017) Study of the structure of polyphenylsiloxanes containing the metal-ions by physical–chemical methods. J Molecul Struct 1145:300–308. https://doi.org/10.1016/j.molstruc.2017.05.046

    Article  CAS  Google Scholar 

  21. Shapkin NP, Balanov MI, Razov VI, Gardionov SV, Mayorov VY, Tokar EA, Papynov EK, Korotchensev VV, Leont’ev LB, Slobodyuk AB, Modin EB (2018) Staircase polymetalsilicon nanocomplexes: polymetalphenyl siloxanes: Structure and properties. J Molecul Struct 1156:424–432. https://doi.org/10.1016/j.molstruc.2017.11.119

    Article  CAS  Google Scholar 

  22. Leon’ev LB, Shapkin NP, Leont’ev AL, Makarov VN (2016) Tribotechnical properties of thin-film coatings obtained by the tribomodifcation of crankshaft pins for ship diesel engines. J Frict Wear 38:1–6. https://doi.org/10.3103/S1068366616060088

    Article  Google Scholar 

  23. Leon’ev LB, Makarov VM et al. (2017) Russian federation patent 2634100. Bull 30

  24. Miller RI, Boyer RF (1984) Regularities in x‐ray scattering patterns from amorphous polymers. J Polym Sci Polym Phys 22:2043–2050

    Article  CAS  Google Scholar 

  25. Shapkin NP, Kul’chin YuN, Razov VI, Voznesenskii SS, Bazhenov VV, Tutov MV, Stavnistyi NN, Kuryavyi VG, Slobodyuk AB (2011) Investigation of polyvinylpolyphenylsilseskvioxanes by X-ray diffractometry, positron diagnostics, Si29 NMR spectroscopy and the study of films based on them. Izvestiya RAN Ser Khim 8:1614–1620 (In Russian)

    Google Scholar 

  26. Jaber M, Brendle JM, Roux M, Dentzer J, Dred RI, Guth J-L (2002) A new Al, Mg-organoclay. New J Chem 26:1597–1600

    Article  CAS  Google Scholar 

  27. Bokii GB (1971) Kristallojkhimiya. Nauka, Moscow (In Russian)

    Google Scholar 

  28. Shapkin NP, Kapustina AA, Dombai NV, Libanov VV, Khalchenko IG, Gardionov SV, Gribova VV (2020) Synthesis and physicochemical characteristics of polymolybdenum(VI) phenylsiloxanes by means of different methods. Polym Bull 77:1177–1190. https://doi.org/10.1007/s00289-019-02790-3

    Article  CAS  Google Scholar 

  29. Libanov V, Kapustina A, Shapkin N, Dmitrenok P, Puzyrkov Z (2020) Mechanochemical synthesis of polyboronphenylsiloxanes. Polymer 194:122367

    Article  CAS  Google Scholar 

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Funding

The work was financially supported by State Assignment of the Ministry of Science and Higher Education of the Russian Federation topic No. 00657–2020-0006.

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Authors and Affiliations

  1. Far Eastern Federal University, Vladivostok, Russia

    N. P. Shapkin, E. K. Papynov, A. A. Kapustina, V. V. Libanov & A. B. Slobodyuk

  2. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    E. K. Papynov & A. B. Slobodyuk

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  1. N. P. Shapkin
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  2. E. K. Papynov
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  3. A. A. Kapustina
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  4. V. V. Libanov
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  5. A. B. Slobodyuk
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Correspondence to N. P. Shapkin.

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Shapkin, N.P., Papynov, E.K., Kapustina, A.A. et al. Polymeric nanocomplexes based on polyaluminophenylsiloxanes. Polym. Bull. 79, 7429–7441 (2022). https://doi.org/10.1007/s00289-021-03819-2

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  • DOI: https://doi.org/10.1007/s00289-021-03819-2

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