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Effect of AE-POSS content on the compatibility and mechanical properties of GER/DOPO-POSS composites

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Abstract

In this work, the bio-based epoxy nanocomposites (GER/DOPO-POSS) were prepared, and AE-POSS was synthesized and used as compatibilizer for GER/DOPO-POSS nanocomposites. The effects of AE-POSS content on mechanical properties, thermal stability, compatibility and flame retardancy of GER/DOPO-POSS nanocomposites were discussed. The results showed that the addition of AE-POSS significantly improved the dispersity of DOPO-POSS in gallic epoxy matrix. AE-POSS can improve both the thermal stability and flame retardancy of GER/DOPO-POSS nanocomposites. When 6.0 wt % AE-POSS was added in GER/DOPO-POSS, the limiting oxygen index of it was 25.6%, and the initial thermal degradation temperature of it was 36 °C higher than that without AE-POSS.

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Acknowledgements

The authors gratefully acknowledge the financial support from Natural Science Foundation of Hebei Province (No: B2019210221), High School Science and Technology Research Projects of Hebei Province (No: QN2017136) and Undergraduate Research Training Program of Hebei Province (No: 201910107012).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shijiazhuang Tiedao University, No. 17 North 2nd Ring East Road, Shijiazhuang, 050043, Hebei Province, China

    Yonggang Du, Yiming Wang, Yueru Yu, Gonghui Shi, Shuai Zhou, Mei Liu, Shitong Ren, Xiangxiang Jia & Ge Zhao

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  1. Yonggang Du
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Correspondence to Yonggang Du.

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Du, Y., Wang, Y., Yu, Y. et al. Effect of AE-POSS content on the compatibility and mechanical properties of GER/DOPO-POSS composites. Polym. Bull. 79, 3541–3553 (2022). https://doi.org/10.1007/s00289-021-03616-x

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  • DOI: https://doi.org/10.1007/s00289-021-03616-x

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