Abstract
In this work, the multiwall carbon nanotubes (MWCNTs) were treated with concentrated mixed acid to form oxidized multiwall carbon nanotubes (o-MWCNTs) before using as an additive for enhancing the anticorrosion and mechanical properties of epoxy-based coating. Many characteristics of both o-MWCNTs and its coating were examined in detail such as chemical structure, crystal phase, anticorrosion, morphology, mechanical property. The presence of o-MWCNTs helps to improve anti-corrosion for epoxy coating in comparison with pure epoxy coating and epoxy coating embedded with pristine MWCNTs. The result of mechanical testing indicated that the o-MWCNTs induced the higher hardness and lower modulus when compared with pure epoxy coating and epoxy/MWCNTs coating.
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Yohai L, Schreiner W, Vázquez M, Valcarce MB (2016) Phosphate ions as effective inhibitors for carbon steel in carbonated solutions contaminated with chloride ions. Electrochim Acta 202:231–242
Iravani D, Arefinia R (2020) Effectiveness of one-to-one phosphate to chloride molar ratio at different chloride and hydroxide concentrations for corrosion inhibition of carbon steel. Constr Build Mater 233:117200
Sabouri M, Hoseiny H (2017) Passive layer stability of 2205 duplex stainless steel in oilfield-produced water: potentiostatic critical pitting temperature test and wavelet analysis. Metall Mater Trans B 48:2104–2113
Ibrahim MH, Moussa DT, Naas MHE, Nasser MS (2020) A perforated electrode design for passivation reduction during the electrochemical treatment of produced water. J Water Process Eng 33:101091
Mei Y, Xu J, Jiang L, Tan Q (2019) Enhancing corrosion resistance of epoxy coating on steel reinforcement by aminobenzoate intercalated layered double hydroxides. Prog Org Coat 134:288–296
Akbari V, Najafi F, Vahabi H, Jouyandeh M, Badawi M, Morisset S, Ganjali MR, Saeb MR (2019) Surface chemistry of halloysite nanotubes controls the curability of low filled epoxy nanocomposites. Prog Org Coat 135:555–564
Sari MG, Ramezanzadeh B (2020) Epoxy composite coating corrosion protection properties reinforcement through the addition of hydroxyl-terminated hyperbranched polyamide non-covalently assembled graphene oxide platforms. Constr Build Mater 234:117421
Gao M, Wang J, Zhou Y, Morshed M, Wang Z, Zhao S (2019) Bifunctional oxygen-vacancy abundant perovskite nanosheets for improving protective performance of epoxy coatings. Prog Org Coat 137:105301
Morozov Y, Calado LM, Shakoor RA, Raj R, Kahraman R, Taryba MG, Montemor MF (2019) Epoxy coatings modified with a new cerium phosphate inhibitor for smart corrosion protection of steel. Corros Sci 159:108128
Khodair ZT, Khadom AA, Jasim HA (2019) Corrosion protection of mild steel in different aqueous media via epoxy/nanomaterial coating: preparation, characterization and mathematical views. J Mater Res Technol 8:424–435
Li X, Zhao S, Hu W, Zhang X, Pei L, Wang Z (2019) Robust superhydrophobic surface with excellent adhesive properties based on benzoxazine/epoxy/mesoporous SiO2. Appl Surf Sci 481:374–378
Li Z, Hu J, Li Y, Liu J (2018) Polyaniline/zinc/cerium nitrate pigment for epoxy based anticorrosion coatings. React Funct Polym 131:22–28
Shi Q, Zhu A (2020) Interface regulation of graphene/carbon nanotube on the thermal conductivity and anticorrosion performance of their nanocomposite. Prog Org Coat 140:105480
Lin YT, Don TM, Wong CJ, Meng FC, Lin YJ, Lee SY, Lee CF, Chiu WY (2019) Improvement of mechanical properties and anticorrosion performance of epoxy coatings by the introduction of polyaniline/graphene composite. Surf Coat Technol 374:1128–1138
Xia Y, He Y, Chen C, Wu Y, Chen J (2019) MoS2 nanosheets modified SiO2 to enhance the anticorrosive and mechanical performance of epoxy coating. Prog Org Coat 132:316–327
Atta AM, Mohamed NH, Rostom M, Lohedan HAA, Abdullah MMS (2019) New hydrophobic silica nanoparticles capped with petroleum paraffin wax embedded in epoxy networks as multifunctional steel epoxy coatings. Prog Org Coat 128:99–111
Gharagozlou M, Ramezanzadeh B, Baradaran Z (2016) Synthesize and characterization of a novel anticorrosive cobalt ferrite nanoparticles dispersed in silica matrix (CoFe2O4–SiO2) to improve the corrosion protection performance of epoxy coating. Appl Surf Sci 377:86–98
Zheng H, Shao Y, Wang Y, Meng G, Liu B (2017) Reinforcing the corrosion protection property of epoxy coating by using graphene oxide–poly(urea–formaldehyde) composites. Corros Sci 123:267–277
Liu C, Wang L, Guo Y, Gao X, Xu Y, Wei Q, Man B, Yang C (2019) Suspended 3D AgNPs/CNT nanohybrids for the SERS application. Appl Surf Sci 487:1077–1083
Abitkar SB, Jadhav PR, Tarwal NL, Moholkar AV, Patil CE (2019) A facile synthesis of α-Ni(OH)2-CNT composite films for supercapacitor application. Adv Powder Technol 30:2285–2292
Yao C, Bai W, Geng L, He Y, Wang F, Lin Y (2019) Experimental study on microreactor-based CNTs catalysts: preparation and application. Colloid Surface A 583:124001
Eltayeb NE, Khan A (2019) Design and preparation of a new and novel nanocomposite with CNTs and its sensor applications. J Mater Res Technol 8:2238–2246
Cui M, Ren S, Qiu S, Zhao H, Wang L, Xue Q (2018) Non-covalent functionalized multi-wall carbon nanotubes filled epoxy composites: effect on corrosion protection and tribological performance. Surf Coat Technol 340:74–85
More AP, Mhaske ST (2016) Anticorrosive coating of polyesteramide resin by functionalized ZnO-Al2O3-Fly ash composite and functionalized multiwalled carbon nanotubes. Prog Org Coat 99:240–250
Nayini MMR, Ranjbar SBZ (2014) Synthesis and characterization of functionalized carbon nanotubes with different wetting behaviors and their influence on the wetting properties of carbon nanotubes/polymethylmethacrylate coatings. Prog Org Coat 77:1007–1014
Rezazadeh V, Pourhossaini MR, Salimi A (2017) Effect of amine-functionalized dispersant on cure and electrical properties of carbon nanotube/epoxy nanocomposites. Prog Org Coat 111:389–394
Li Y, Hu N, Kojima T et al (2012) Experimental study on mechanical properties of epoxy/MWCNT nanocomposites—effects of acid treatment, pressured curing, and liquid rubber. J Nanotechnol Eng Med 3:011004
Chen Y, Mitra S, Nanosci J (2008) Fast microwave-assisted purification, functionalization and dispersion of multi-walled carbon nanotubes. J Nanosci Nanotechnol 8:5770–5775
Gojny FH, Wichmann MH, Fiedler B, Schulte K (2005) Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites—a comparative study. Compos Sci Technol 65:2300–2313
Silva LRR, Avelino F, Diogenes OBF et al (2020) Development of BPA-free anticorrosive epoxy coatings from agroindustrial waste. Prog Org Coat 139:105449
Zhu Q, Li E, Liu X et al (2020) Epoxy coating with in-situ synthesis of polypyrrole functionalized graphene oxide for enhanced anticorrosive performance. Prog Org Coat 140:105488
Touazi Y, Abdi A, Leshaf A, Khimeche K (2020) Influence of heat treatment of iron oxide on its effectiveness as anticorrosion pigment in epoxy based coatings. Prog Org Coat 139:105458
Xia Y, He Y, Chen C et al (2019) MoS2 nanosheets modified SiO2 to enhance the anticorrosive and mechanical performance of epoxy coating. Prog Org Coat 132:316–327
Khodaei P, Nooshabadi MS, Behpour M (2019) Epoxy-based nanocomposite coating reinforced by a zeolite complex: its anticorrosion properties on mild steel in 3.5 wt% NaCl media. Prog Org Coat 136:105254
Xiong G, Kang P, Zhang J et al (2019) Improved adhesion, heat resistance, anticorrosion properties of epoxy resins/POSS/methyl phenyl silicone coatings. Prog Org Coat 135:454–464
Cao K, Yu Z, Yin D (2019) Preparation of Ce-MOF@TEOS to enhance the anti-corrosion properties of epoxy coatings. Prog Org Coat 135:613–621
Acknowledgement
This research was funded by the Vietnam National Foundation for Science and Technology Development (NAFOSTED) under Grant Number 104.02-2017.15.
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Vu, C.M., Bach, QV. Oxidized multiwall carbon nanotubes filled epoxy-based coating: fabrication, anticorrosive, and mechanical characteristics. Polym. Bull. 78, 2329–2339 (2021). https://doi.org/10.1007/s00289-020-03218-z
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DOI: https://doi.org/10.1007/s00289-020-03218-z