Abstract
The density (ρ), viscosity (η) and ultrasonic speed (U) of pure solvents: 1,4-dioxane (DO), tetrahydrofuran (THF), chloroform (CF) and (2E,6E)-bis(4-hydroxybenzylidene)cyclohexanone (EBHBC) solutions of different concentrations were investigated at four different temperatures: 298, 303, 308 and 313 K to understand the effect of solvents on molecular interactions in these solutions. Various acoustical and thermodynamic activation parameters such as specific acoustical impedance (Z), adiabatic compressibility (κa), Rao’s molar sound function (Rm), van der Waals constant (b), internal pressure (π), free volume (Vf), intermolecular free path length (Lf), classical absorption coefficient (α/f2)cl, viscous relaxation time (τ), Gibbs free energy of activation (ΔG*), enthalpy of activation (ΔH*) and entropy of activation (ΔS*) were determined using the ρ, η and U data and correlated with concentration (C) at different temperatures (T). Very good to excellent correlation between a given parameter and concentration is observed at different T. Linear/nonlinear increase or linear/nonlinear decrease in acoustical parameters, solvation number and thermodynamic activation parameters suggested structure-forming tendency of EBHBC in the selected solvent systems.
Similar content being viewed by others
References
Syal VK, Chauhan A, Chauhan S (2005) Ultrasonic velocity, viscosity and density studies of poly (ethylene glycols) (PEG-8,000, PEG-20,000) in acetonitrile (AN) and water (H2O) mixtures at 25 °C. J Pure Appl Ultrason 27(2/3):61–69
Naidu SV, John K, Brahmam PV, Challa PK (2004) Ultrasonic studies of poly(vinyl acetate) solution in dimethylformamide. Int J Polym Anal Charact 9:351–359
Mason TJ (1990) Sonochemistry: the uses of ultrasounds in chemistry. Royal Society of Chemistry, Cambridge
Pethrick RA (1973) Acoustic studies of polymer solutions. J Macromol Sci Part C Polym Rev 9:91–121
Ashokkumar M (2015) Applications of ultrasound in food and bioprocessing. Ultrason Sonochem 25:17–23
Xia H, Zhao Y, Tong R (2016) Ultrasound-mediated polymeric micelle drug delivery. Ther Ultrasound 880:365–384
Proctor A (ed) (2018) Alternatives to conventional food processing, vol 53, 2nd edn. Royal Society of Chemistry, Cambridge
Ferraioli G, Wong VWS, Castera L, Berzigotti A, Sporea I, Dietrich CF, Choi BI, Wilson SR, Kudo M, Barr RG (2018) Liver ultrasound elastography: an update to the world federation for ultrasound in medicine and biology guidelines and recommendations. Ultrasound Med Biol 44:2419–2440
Ince NH (2018) Ultrasound-assisted advanced oxidation processes for water decontamination. Ultrason Sonochem 40:97–103
Huang Q, Zhang F, Li X (2018) Machine learning in ultrasound computer-aided diagnostic systems: a survey. BioMed Research Int 2018:1–10
Kocasarac HD, Angelopoulos C (2018) Ultrasound in dentistry: toward a future of radiation-free imaging. Dent Clin North Am 62(3):481–489
Rodríguez Ó, Eim V, Rosselló C, Femenia A, Cárcel JA, Simal S (2017) Application of power ultrasound on the convective drying of fruits and vegetables: effects on quality. J Sci Food Agric 98:1660–1673
Xu C, Zhang H, Shi J, Zheng M, Xiang X, Huang F, Xiao J (2018) Ultrasound irradiation promoted enzymatic alcoholysis for synthesis of monoglyceryl phenolic acids in a solvent-free system. Ultrason Sonochem 41:120–126
Xu YJ, Wang J, Tan Y, Qi M, Chen L, Wang YZ (2018) A novel and feasible approach for one-pack flame-retardant epoxy resin with long pot life and fast curing. Chem Eng J 337:30–39
Chen S, Xu Z, Zhang D (2018) Synthesis and application of epoxy-ended hyper branched polymers. Chem Eng J 343:283–302
Ashraf B, Radwan MA, Sadek MA, Elazab HA (2018) Preparation and characterization of decorative and heat insulating floor tiles for buildings roofs. Int J Eng Technol 7:1295–1298
Duan Y, Huo Y, Duan L (2017) Preparation of acrylic resins modified with epoxy resins and their behaviors as binders of waterborne printing ink on plastic film. Colloids Surf A Physicochem Eng Asp 535:225–231
Vogel AI, Tatchell AR, Furnis BS, Hannaford AJ, Smith PWG (1998) Vogel’s textbook of practical organic chemistry, 5th edn. Addison-Wesley, Boston, p 395
Koneti AK, Chintalapati S (2014) Speeds of sound and excess molar volume for binary mixture of 1,4-dioxane with 1-heptanol at five temperatures. Adv Chem. https://doi.org/10.1155/2014/343012
Dhaduk BB, Patel CB, Parsania PH (2015) Ultrasonic speed and related thermo-acoustical parameters of solutions of 1,1′-bis(3-methyl-4-ethoxyacetylphenoxy)cyclohexane at four different temperatures. J Sol Chem 44:1976–1996
Živković EM, Bajić DM, Radović IR, Šerbanović SP, Kijevčanin ML (2014) Volumetric and viscometric behavior of the binary systems ethyl lactate + 1, 2-propanediol, + 1, 3-propanediol, + tetrahydrofuran and + tetraethylene glycol dimethyl ether. New UNIFAC–VISCO and ASOG–VISCO parameters determination. Fluid Phase Equilib 373:1–19
Kagathara VM, Parsania PH (2002) Studies on ultrasonic velocity and acoustical parameters of bromo epoxy resins of bisphenol-C solutions at different temperatures. Eur Polym J 38(3):607–610
Bhuva BD, Parsania PH (2011) Synthesis, speed of ultrasound and associated acoustical parameters of epoxy acrylate of 9,9′-bis(4-hydroxyphenyl)anthrone-10 solutions. J Appl Polym Sci 121:1304–1310
Suryanarayana CV, Kuppuswamy JJ (1976) Free volume and internal pressure of liquids from ultrasonic velocity. J Acoust Soc India 4:75–82
Jacobson B, Anderson WA, Arnold JT (1954) A proton magnetic resonance study of the hydration of deoxyribonucleic acid. Nature 173:772–773
Vigoureux P (1952) Ultrasonic. Chapman and Hall, London, pp 99–115
Subrahmanyam TVS, Viswanatha Sarma A (1993) Ultrasonic absorption studies in binary mixtures of ethanolamine. Acustica 79(1):88–92
Bagchi S, Nema S, Singh R (1986) Ultrasonic and viscometric investigation of ISRO polyol in various solvents and its compatibility with polypropylene glycol. Eur Polym J 22:851–860
Gangani BJ, Parsania PH (2009) Density, viscosity and ultrasonic velocity studies of cardo group containing symmetric double Schiff bases solutions at 303, 308 and 313 K. J Ind Chem Soc 86:942–949
Acknowledgements
The authors are thankful to FIST-DST and SAP-UGC for their generous financial support for instrumentation support to Department of Chemistry, P. H. Parsania and Dharmesh are also thankful to University Grants Commission—New Delhi, for BSR Faculty Fellowship (F.No.18-1/2011 (BSR), Feb 15, 2016) and Junior Research Fellowship.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Parsania, P.H., Sankhavara, D.B., Chopda, J.V. et al. Effect of temperature and solvents on ultrasonic speed and related acoustical thermodynamic parameters of epoxy resin of (2E,6E)-bis(4-hydroxybenzylidene)cyclohexanone solutions. Polym. Bull. 78, 1489–1504 (2021). https://doi.org/10.1007/s00289-020-03167-7
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00289-020-03167-7