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Adsorption of Ag(I) ions from wastewaters using poly(2-aminothiazole): kinetic and isotherm studies

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Abstract

In this study, 2-aminothiazole, (2AT), was polymerized with benzoyl peroxide in 1,4-dioxane solution, and adsorption efficiencies of poly(2-aminothiazole), P-2AT, for the Ag(I) ions to remove from the aqueous solutions were investigated. Adsorption experiments were studied at different pH, contact time and initial Ag(I) ion concentration in a batch system. The optimal pH for Ag(I) adsorption onto P-2AT was found to be 5.0, and the maximum adsorption capacity was determined to be 336.98 mg/g for 1200 mg/L Ag(I) solution at 90 min. P-2AT adsorbents were followed up by recycling in multiple adsorption cycles. The results showed that adsorbent can be used several times. Ag(I) ion adsorption performance of the P-2AT was investigated in conjunction with Cu(II) and Zn(II) ions. The selectivity series of ions were found as Ag(I) > Cu(II) > Zn(II). According to the experimental data, the adsorption reaction fitted the pseudo-second-degree kinetic model and the Langmuir isotherm equation.

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Acknowledgements

This work was supported by the Research Fund of Kirikkale University (2016/138).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Art and Sciences, Kırıkkale University, 71450, Yahşihan, Kirikkale, Turkey

    Mutluhan Bıyıkoğlu

  2. Department of Chemistry and Chemical Processing Technologies, Kırıkkale Vocational High School, Kırıkkale University, 71450, Yahşihan, Kirikkale, Turkey

    Hakan Çiftçi

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Bıyıkoğlu, M., Çiftçi, H. Adsorption of Ag(I) ions from wastewaters using poly(2-aminothiazole): kinetic and isotherm studies. Polym. Bull. 77, 6161–6174 (2020). https://doi.org/10.1007/s00289-019-03073-7

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