The retardation of polyacrylamide by ammonium chloride in high-salinity and high-temperature conditions: molecular analysis

Abstract

Salinity effects on retardation efficiency of ammonium chloride (NH4Cl) on the polyacrylamide (PAM) that influences the gelation time of PAM-based polymer gel are an interesting phenomenon. This paper presents a concise investigation by quantifying molecular interaction of PAM with NH4Cl in high-salinity and high-temperature conditions. This study quantified the ionic bonding of carboxylate group of PAM with ammonium ion of NH4Cl using zeta-potential, hydrodynamic radius, and hydrolysis degree. Experimental results show that in the absence of NaCl and NH4Cl, the overall magnitude absolute values of zeta-potential, hydrodynamic radius, and hydrolysis degree of PAM show a significant increase. The absolute value of zeta-potential reduces with the concentration of NH4Cl as retarder. On the other hand, the hydrodynamic radius and hydrolysis degree tend to increase with the concentration of NH4Cl, even in high salinity. The retardation process is also fairly affected by the exposure time of polymer to high temperature. These results give better understanding and provide additional knowledge as the conventional research did not fully reveal the efficiency of polymer gel with retarder that was prepared with high salinity for high-temperature application.

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References

  1. 1.

    Sydansk RD, Romero-Zern̤ L (2011) Reservoir conformance improvement. Society of Petroleum Engineers, Richardson, Texas

    Google Scholar 

  2. 2.

    Bailey B, Crabtree M, Tyrie J, Elphick J, Kuchuk F, Romano C, Roodhart L (2000) Water Control. Oilfield Rev 12(1):30–51

    Google Scholar 

  3. 3.

    Sydansk RD, Southwell GP (2000) More than 12 years of experience with a successful conformance-control polymer gel technology. Paper presented at the SPE/AAPG Western Regional Meeting, Society of Petroleum Engineers, 19–22 June, Long Beach, California

  4. 4.

    Sydansk RD, Seright RS (2007) When and where relative permeability modification water-shutoff treatments can be successfully applied. SPE Prod Oper 22(2):236–247

    CAS  Google Scholar 

  5. 5.

    Seright RS, Lane RH, Sydansk RD (2003) A strategy for attacking excess water production. SPE Prod Facil 18(3):158–169

    CAS  Google Scholar 

  6. 6.

    Hirsch RL, Bezdek R, Wendling R (2007) Peaking of world oil production and its mitigation. Driving climate change. Academic Press, Cambridge, pp 9–27

    Google Scholar 

  7. 7.

    Seright RS (2003) Washout of Cr(III)-acetate-HPAM gels from fractures. Paper presented at the international symposium on oilfield chemistry, Society of Petroleum Engineers, 5–7 February, Houston, Texas

  8. 8.

    Kabir AH (2001) Chemical water and gas shutoff technology—an overview. Paper presented at the SPE Asia Pacific improved oil recovery conference, Society of Petroleum Engineers, 6–9 October, Kuala Lumpur, Malaysia

  9. 9.

    Prada A, Civan F, Dalrymple ED (2000). Evaluation of gelation systems for conformance control. Paper presented at the SPE/DOE improved oil recovery symposium, Society of Petroleum Engineers, 3–5 April, Tulsa, Oklahoma

  10. 10.

    Al-Muntasheri GA, Nasr-El-Din HA, Peters J, Zitha PLJ (2006) Investigation of a high temperature organic water shutoff gel: reaction mechanisms. SPE J 11(4):497–504

    CAS  Google Scholar 

  11. 11.

    El-Karsani KSM, Al-Muntasheri GA, Hussein IA (2014) Polymer systems for water shutoff and profile modification: a review over the last decade. SPE J 19(1):135–149

    Google Scholar 

  12. 12.

    Moradi-Araghi A (2000) A review of thermally stable gels for fluid diversion in petroleum production. J Pet Sci Eng 26(1–4):1–10

    CAS  Google Scholar 

  13. 13.

    Al-Muntasheri GA, Nasr-El-Din HA, Hussein IA (2007) A rheological investigation of a high temperature organic gel used for water shut-off treatments. J Pet Sci Eng 59(1–2):73–83

    CAS  Google Scholar 

  14. 14.

    El-Karsani KSM, Al-Muntasheri GA, Sultan AS, Hussein IA (2015) Gelation of a water-shutoff gel at high pressure and high temperature: rheological investigation. SPE J 20(5):1103–1112

    CAS  Google Scholar 

  15. 15.

    Seright RS, Martin FD (1993) Impact of gelation pH, rock permeability, and lithology on the performance of a monomer-based gel. SPE Reserv Eng 8(1):43–50

    CAS  Google Scholar 

  16. 16.

    Zolfaghari R, Katbab AA, Nabavizadeh J, Tabasi RY, Nejad MH (2006) Preparation and characterization of nanocomposite hydrogels based on polyacrylamide for enhanced oil recovery applications. J Appl Polym Sci 100(3):2096–2103

    CAS  Google Scholar 

  17. 17.

    Zhang J, He H, Wang YF, Xu XL, Zhu YJ, Li RY (2014) Gelation performance and microstructure study of chromium gel and phenolic resin gel in bulk and porous media. J Energy Res Technol 136(4):042910

    Google Scholar 

  18. 18.

    Burns LD, McCool CS, Willhite GP, Burns M, Oglesby KD, Glass J (2008) New generation silicate gel system for casing repairs and water shutoff. Paper presented at the SPE symposium on improved oil recovery, Society of Petroleum Engineers, 20–23 April, Tulsa, Oklahoma

  19. 19.

    Bryant SL, Borghi GP, Bartosek M, Lockhart TP (1997) Experimental investigation on the injectivity of phenol-formaldehyde/polymer gelants. Paper presented at the international symposium on oilfield chemistry, Society of Petroleum Engineers, 8–21 February, Houston, Texas

  20. 20.

    Al-Muntasheri GA, Sierra L, Garzon FO, Lynn JD, Izquierdo GA (2010) Water shut-off with polymer gels in a high temperature horizontal gas well: a success story. Paper presented at the SPE improved oil recovery symposium, Society of Petroleum Engineers, 24–28 April, Tulsa, Oklahoma

  21. 21.

    Al-Muntasheri GA, Sierra L, Bakhtyarov A (2014) Ammonium halide as gelation retarder for crosslinkable polymer compositions. U.S. Patent/Patent Application No. US20140224489A1

  22. 22.

    Kherb J, Flores SC, Cremer PS (2012) Role of carboxylate side chains in the cation hofmeister series. J Phys Chem B 116(25):7389–7397

    CAS  PubMed  Google Scholar 

  23. 23.

    Zhao H, Zhao P, Bai B, Xiao L, Liu L (2006) Using associated polymer gels to control conformance for high temperature and high salinity reservoirs. J Can Pet Technol 45(05):49–54

    CAS  Google Scholar 

  24. 24.

    Sharqawy MH, Lienhard JH, Zubair SM (2010) Thermophysical properties of seawater: a review of existing correlations and data. Desalin Water Treat 16(1–3):354–380

    CAS  Google Scholar 

  25. 25.

    Wang J, AlSofi AM, AlBoqmi AM (2016) Development and evaluation of gel-based conformance control for a high salinity and high temperature carbonate. Paper presented at the SPE EOR conference at oil and gas West Asia, Society of Petroleum Engineers

  26. 26.

    Kujawa P, Audibert-Hayet A, Selb J, Candau F (2006) Effect of ionic strength on the rheological properties of multisticker associative polyelectrolytes. Macromolecules 39(1):384–392

    CAS  Google Scholar 

  27. 27.

    Amir Z, Mohd Saaid I, Mohamed Jan B (2018) An optimization study of polyacrylamide–polyethylenimine-based polymer gel for high temperature reservoir conformance control. Int J Polym Sci. https://doi.org/10.1155/2018/2510132

    Article  Google Scholar 

  28. 28.

    Romero-Zeron LB, Hum FM, Kantzas A (2008) Characterization of crosslinked gel kinetics and gel strength by use of NMR. SPE Reserv Eval Eng 11(3):439–453

    CAS  Google Scholar 

  29. 29.

    El-Karsani KSM, Al-Muntasheri GA, Sultan AS, Hussein IA (2014) Impact of salts on polyacrylamide hydrolysis and gelation: new insights. J Appl Polym Sci. https://doi.org/10.1002/app.41185

    Article  Google Scholar 

  30. 30.

    Al-Muntasheri GA, Nasr-El-Din HA, Peters JA, Zitha PLJ (2008) Thermal decomposition and hydrolysis of polyacrylamide-co-tert-butyl acrylate. Eur Polym J 44(4):1225–1237

    CAS  Google Scholar 

  31. 31.

    Moradi-Araghi A, Doe PH (1987) Hydrolysis and precipitation of polyacrylamides in hard brines at elevated temperatures. SPE Reserv Eng 2(2):189–198

    CAS  Google Scholar 

  32. 32.

    Kurenkov VF, Hartan H-G, Lobanov FI (2001) Alkaline hydrolysis of polyacrylamide. Russ J Appl Chem 74(4):543–554

    CAS  Google Scholar 

  33. 33.

    Al-Muntasheri GA (2008) Polymer gels for water control: NMR and CT scan studies. Doctoral Thesis, Delft University of Technology

  34. 34.

    Truong ND, Galin JC, Francois J, Pham QT (1986) Microstructure of acrylamide-acrylic acid copolymers: 1. As obtained by alkaline hydrolysis. Polymer 27(3):459–466

    CAS  Google Scholar 

  35. 35.

    Kudryavtsev YV, Litmanovich AD, Platé NA (1998) On the kinetics of polyacrylamide alkaline hydrolysis. Macromolecules 31(14):4642–4644

    CAS  Google Scholar 

  36. 36.

    Zeynali ME, Rabbii A (2002) Alkaline hydrolysis of polyacrylamide and study on poly(acrylamide-co-sodium acrylate) properties. Iran Polym J 11(4):269–275

    CAS  Google Scholar 

  37. 37.

    Mandel M (1970) The potentiometric titration of weak polyacids. Eur Polym J 6(6):807–822

    CAS  Google Scholar 

  38. 38.

    Sawant S, Morawetz H (1984) Microstructure, neighboring group inhibition, and electrostatic effects in the base-catalyzed degradation of polyacrylamide. Macromolecules 17(11):2427–2431

    CAS  Google Scholar 

  39. 39.

    Kheradmand H, François J, Plazanet V (1988) Hydrolysis of polyacrylamide and acrylic acid-acrylamide copolymers at neutral pH and high temperature. Polymer 29(5):860–870

    CAS  Google Scholar 

  40. 40.

    Hunter RJ (1988) Zeta potential in colloid science: principles and applications. Academic Press, Cambridge

    Google Scholar 

  41. 41.

    Chapman DL (1913) LI. A contribution to the theory of electrocapillarity. Lond Edinb Dublin Philos Mag J Sci 25(148):475–481

    Google Scholar 

  42. 42.

    Grahame DC (1947) The electrical double layer and the theory of electrocapillarity. Chem Rev 41(3):441–501

    CAS  PubMed  Google Scholar 

  43. 43.

    Pashley RM (1982) Hydration forces between mica surfaces in electrolyte solutions. Adv Colloid Interface Sci 16(1):57–62

    CAS  Google Scholar 

  44. 44.

    Linegar KL, Adeniran AE, Kostko AF, Anisimov MA (2010) Hydrodynamic radius of polyethylene glycol in solution obtained by dynamic light scattering. Colloid J 72(2):279–281

    CAS  Google Scholar 

  45. 45.

    Kaszuba M, McKnight D, Connah MT, McNeil-Watson FK, Nobbmann U (2008) Measuring sub nanometre sizes using dynamic light scattering. J Nanopart Res 10(5):823–829

    CAS  Google Scholar 

  46. 46.

    Pecora R (2013) Dynamic light scattering: applications of photon correlation spectroscopy. Springer, Berlin

    Google Scholar 

  47. 47.

    Strobl GR (2007) The physics of polymers-concepts for understanding their structures and behavior. Springer, Berlin

    Google Scholar 

  48. 48.

    Ji Y, Lu Q, Liu Q, Zeng H (2013) Effect of solution salinity on settling of mineral tailings by polymer flocculants. Colloids Surf A Physicochem Eng Asp 430:29–38

    CAS  Google Scholar 

  49. 49.

    Time PA (2017) Rheological properties of hydrophobically modified anionic polymers: the effect of varying salinity in polymer solution. Master Thesis, The University of Bergen

  50. 50.

    Baalousha M, Motelica-Heino M, Le Coustumer P (2006) Conformation and size of humic substances: effects of major cation concentration and type, pH, salinity, and residence time. Colloids Surf A Physicochem Eng Asp 272(1–2):48–55

    CAS  Google Scholar 

  51. 51.

    Wever DAZ, Picchioni F, Broekhuis AA (2011) Polymers for enhanced oil recovery: a paradigm for structure–property relationship in aqueous solution. Progr Polym Sci 36(11):1558–1628

    CAS  Google Scholar 

  52. 52.

    Sorbie KS (2013) Polymer-improved oil recovery. Springer, Berlin

    Google Scholar 

  53. 53.

    Stokes RJ, Evans DF (1996) Fundamentals of interfacial engineering. Wiley, New York

    Google Scholar 

  54. 54.

    Sada K, Tani T, Shinkai S (2006) Organic ammonium carboxylates as supramolecular building blocks: the role of ionic hydrogen bonding. Synlett 2006(15):2364–2374

    Google Scholar 

  55. 55.

    Breite D, Went M, Prager A, Schulze A (2016) The critical zeta potential of polymer membranes: how electrolytes impact membrane fouling. RSC Adv 6(100):98180–98189

    CAS  Google Scholar 

Download references

Acknowledgements

The authors appreciate the contributions and financial supports from Universiti Teknologi PETRONAS (YUTP 0153AAH05), PETRONAS (GR&T 0153CB019), and University of Malaya (FRGS FP050-2019A and GPF078A-2018), and SLAI Fellowship Scheme from Ministry of Education Malaysia and University of Malaya.

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Amir, Z., Mohd Saaid, I., Mohamed Jan, B. et al. The retardation of polyacrylamide by ammonium chloride in high-salinity and high-temperature conditions: molecular analysis. Polym. Bull. 77, 5469–5487 (2020). https://doi.org/10.1007/s00289-019-03023-3

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Keywords

  • Polymer gel
  • Polyacrylamide
  • High salinity
  • Hydrolysis degree
  • Zeta-potential
  • Hydrodynamic radius