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Quaternized poly(1-vinylimidazole) hydrogel for anion adsorption

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Abstract

Poly(1-vinylimidazole) (PVIm) hydrogels were synthesized through free radical polymerization/crosslinking of 1-vinylimidazole (VIm) in aqueous solutions with azobisisobutyronitrile (AIBN) used as the initiator and N,N′-methylenebisacrylamide (MBAAm) as the crosslinking agent. To quaternize PVIm, dimethylsulfate was used as the methylating agent. Pristine and quaternized PVIm hydrogels were characterized by spectroscopic techniques. Finally, ground hydrogels were used in anion adsorption. The amount of anion adsorbed (in m-eq. anion/g polymer) and adsorption% was determined for fluoride, bromide, nitrite, nitrate, phosphate and sulfate anions using ion chromatography techniques. The amount of phosphate adsorbed on QPVIm hydrogel was the highest and the amount of fluoride adsorbed on QPVIm hydrogel was the lowest. Ion chromatographic study showed that when 1/1 mol ratio of anion to polymer (on a repeating unit basis) was used, 24.7 % of fluoride, 60.6 % of nitrite, 61.6 % of bromide, 63.0 % of nitrate, 99.3 % of phosphate and 98.2 % of sulfate were removed from the medium.

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References

  1. Chang MF, Liu JC (2007) Precipitation removal of fluoride from semiconductor wastewater. J Environ Eng 133:419–425

    Article  CAS  Google Scholar 

  2. Vaaramaa K, Lehto J (2003) Removal of metals and anions from drinking water by ion exchange. Desalination 155:157–170

    Article  CAS  Google Scholar 

  3. Karcher S, Kornmüller A, Jekel M (2002) Anion exchange resins for removal of reactive dyes from textile wastewaters. Water Res 36:4717–4724

    Article  CAS  Google Scholar 

  4. Blaney LM, Cinar S, SenGupta AK (2007) Hybrid anion exchanger for trace phosphate removal from water and wastewater. Water Res 41:1603–1613

    Article  CAS  Google Scholar 

  5. Lazaridis NK (2003) Sorption removal of anions and cations in single batch systems by uncalcined and calcined Mg–Al–CO3 hydrotalcite. Water Air Soil Pollut 146:127–139

    Article  CAS  Google Scholar 

  6. Rozanska A, Wisniewski J, Winnicki T (2006) Donnan dialysis with anion-exchange membranes in a water desalination system. Desalination 198:236–246

    Article  CAS  Google Scholar 

  7. Darder M, Colilla M, Ruiz-Hitzky E (2003) Biopolymer–clay nanocomposites based on chitosan intercalated in montmorillonite. Chem Mater 15:3774–3780

    Article  CAS  Google Scholar 

  8. Ruiz D, Martinelli M, Bertorello H (2001) Binding metal cations and nitrate anions by new synthetic support: castor oil-AAc–AAm. Polym Bull 46:331–338

    Article  CAS  Google Scholar 

  9. Molina MJ, Gomez-Anton MR, Rivas BL, Maturana HA, Pierola IF (2001) Removal of Hg(II) from acid aqueous solutions by poly(N-vinylimidazole) hydrogel. J Appl Polym Sci 79:1467–1475

    Article  CAS  Google Scholar 

  10. Cabot B, Deratani A, Foissy A (1998) Adsorption of poly(vinylimidazoles) onto silica surfaces. Colloids Surf A 139:287–297

    Article  CAS  Google Scholar 

  11. Pekel N, Güven O (1999) Investigation of complex formation between poly(N-vinyl imidazole) and various metal ions using the molar ratio method. J. Colloid Polym Sci 277:570–573

    Article  CAS  Google Scholar 

  12. Lemque R, Vidal-Madjar C, Racine M, Piquion J, Sebille B (1991) Anion-exchange chromatographic properties of α-lactalbumin eluted from quaternized polyvinylimidazole: study of the role of the polymer coating. J Chromatogr 553:165–177

    Article  CAS  Google Scholar 

  13. Cysewski P, Jaulmes A, Lemque R, Sebille B, Vidal-Madjar C, Jilde G (1991) Multivalent ion-exchange model of biopolymer chromatography for mass overload conditions. J Chromatogr 548:61–79

    Article  CAS  Google Scholar 

  14. Jilde G, Sebille B, Vidal-Madjar C, Lemque R, Unger KK (1993) Optimization of fast protein separations on non-porous silica-based strong anion exchangers. Chromatographia 37:603–607

    Article  Google Scholar 

  15. Bay RFC, Armes SP, Pickett CJ, Ryder KS (1991) Poly(1-vinylimidazole-co-4 aminostyrene): steric stabilizer for polyaniline colloids. Polymer 32:2456–2460

    Article  CAS  Google Scholar 

  16. Pekel N, Rzaev ZMO, Guven O (2004) Synthesis and characterization of poly(N-vinylimidazole-co-acrylonitrile) and determination of monomer reactivity ratios. Macromol Chem Phys 205:1088–1095

    Article  CAS  Google Scholar 

  17. Evsyukov SE, Gautheron F, Höffken HW, Böhn K (2001) Synthesis, X-ray structure, and polymerization of 1-vinyl-3-cyanomethylimidazolium chloride. J Appl Polym Sci 82:499–509

    Article  CAS  Google Scholar 

  18. Chang H, Jiang J, Tsai W, Chen G, Lin S (2006) The role of charge-enhanced C–H–O interactions in gel-like mixtures prepared from ionic liquids and tungsten(VI) oxidenanoparticle. Chem Phys Lett 427:310–316

    Article  CAS  Google Scholar 

  19. Küçükyavuz Z, Küçükyavuz S, Abbasnejad N (1996) Electrically conductive polymers from poly(N-vinylimidazole). Polymer 37(15):3215–3218

    Article  Google Scholar 

  20. Pekel N, Güven O (2002) Synthesis and characterization of poly(N-vinylimidazole) hydrogels crosslinked by gamma irradiation. Polym Int 51:1404–1410

    Article  CAS  Google Scholar 

  21. Böhmer MR, William HA, Heesterbeek WH, Deratani A, Renard E (1995) Adsorption of partially quarternised poly(vinyl imidazoles) onto SiO2 and Y2O3. Colloids Surf A 99:53–64

    Article  Google Scholar 

  22. Henrichs PM, Whitlock LR, Sochor AR, Tan JS (1980) Conformational behavior of poly(N-vinylimidazole). Potentiometric titration, viscosity, and proton nuclear magenetic resonance studies. Macromolecules 13:1375–1381

    Article  CAS  Google Scholar 

  23. Kioussis DR, Wheaton FW, Kofinas P (2000) Reactive nitrogen and phosphorus removal from aquaculture wastewater effluents using polymer hydrogels. Aquac Eng 23:315–332

    Article  Google Scholar 

  24. Namasivayam C, Höll WH (2004) Quaternized biomass as an anion exchanger for the removal of nitrate and other anions from water. J Chem Technol Biotechnol 80:164–168

    Article  Google Scholar 

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Correspondence to Olgun Güven.

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Genç, F., Uzun, C. & Güven, O. Quaternized poly(1-vinylimidazole) hydrogel for anion adsorption. Polym. Bull. 73, 179–190 (2016). https://doi.org/10.1007/s00289-015-1479-0

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  • DOI: https://doi.org/10.1007/s00289-015-1479-0

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