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Influence of selected photoinitiators type II on tack, peel adhesion, and shear strength of UV-crosslinked solvent-borne acrylic pressure-sensitive adhesives used for medical applications

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Abstract

This article describes the photoreactive UV-crosslinkable solvent-borne acrylic pressure-sensitive adhesives (PSA) containing unsaturated copolymerizable photoinitiators and their synthesis. The solvent-borne acrylic PSA were synthesized in ethyl acetate as a solvent, and the copolymerizable photoinitiators type II, known as hydrogen abstractors, were incorporated into acrylic polymer chain during conducted radical polymerization process. The synthesized solvent-borne acrylic PSA containing different unsaturated photoinitiators were investigated to evaluate their relevant and significant properties such as tack, peel adhesion, and shear strength after UV exposure.

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References

  1. Czech Z (1999) Crosslinking of pressure-sensitive adhesives based on acrylic. Technical University of Szczecin, Szczecin

    Google Scholar 

  2. Foreman BP (1987) EP Patent 0 212 358

  3. Chen SJ (1990) DE Patent 38 10 307

  4. McKenna LW, Mass W (1975) US Patent 3 886 126

  5. Technical Bulletin Carbodiimide (2002) Stahl Company, Waalwijk, Holland

  6. Kenneth DW, Meixner LA (1992) US Patent 5 296 277

  7. Rehfuss JW (1992) EP Patent 0 544 183

  8. Oemke R (1991) A survey of the field of radiation cured PSAs. AFERA, Jahrestagung, Amsterdam, Holland, pp 47–61

    Google Scholar 

  9. Czech Z, Kurzawa R (2007) Acrylic pressure-sensitive adhesive for transdermal drug delivery systems. J Appl Polym Sci 106:2398–2404

    Article  CAS  Google Scholar 

  10. Czech Z, Loclair H, Wesołowska M (2007) Photoreactivity adjustment of acrylic PSA. Rev Adv Mater Sci 14:141–150

    CAS  Google Scholar 

  11. Czech Z, Milker R, Butwin A, Herko E (2008) Removal of organic solvents for the purpose of manufacturing of solvent-free pressure-sensitive adhesives. Polish J Chem Technol 1:37–40

    Article  Google Scholar 

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Correspondence to Zbigniew Czech.

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Czech, Z., Kowalczyk, A., Kabatc, J. et al. Influence of selected photoinitiators type II on tack, peel adhesion, and shear strength of UV-crosslinked solvent-borne acrylic pressure-sensitive adhesives used for medical applications. Polym. Bull. 68, 441–452 (2012). https://doi.org/10.1007/s00289-011-0563-3

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  • DOI: https://doi.org/10.1007/s00289-011-0563-3

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