Abstract
Microcomposites of polypropylene (PP) and magnetite (Fe3O4) in different concentration were prepared by one-step melt blending of magnetite powders and polypropylene. Morphology of the composites was studied by means of scanning electron microscope (SEM) to investigate magnetite dispersion within the polypropylene matrix. Thermoxidative stability and mechanical properties were investigated, showing improved thermal stability and enhanced stiffness. Magnetic properties characterization showed a ferromagnetic behavior with coercive field of 116 Oe and saturation magnetizations linearly dependent on the content of magnetic phase.
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Mataga N (1968) Possible “ferromagnetic states” of some hypothetical hydrocarbons Theor. Chim Acta 10:372–376. doi:10.1007/BF00526505
Korshak YV, Medvedeva TV, Ovchinnikov AA (1987) Organic polymer ferromagnet. Nature 326:370–372. doi:10.1038/326370a0
Ovchinnikov AA, Spector VN (1988) Organic ferromagnets. New results. Synth Met 27:615–624. doi:10.1016/0379-6779(88)90208-1
Torrance JB, Oostra S, Nazzal A (1987) A new, simple model for organic ferromagnetism and the first organic ferromagnet. Synth Met 19:709–714. doi:10.1016/0379-6779(87)90440-1
Iwamura H (1986) High-spin polycarbenes as models for organic ferromagnets. Pure Appl Chem 58:187–196. doi:10.1351/pac198658010187
Iwamura H (1991) High-spin organic molecules and spin alignment in organic molecular assemblies. Adv Phys Org Chem 26:179–253. doi:10.1016/S0065-3160(08)60046-5
Miller JS (1992) The quest for magnetic polymers. Adv Mater 4:298–300. doi:10.1002/adma.19920040414
Rajca A, Wongsriratanakul J, Rajca S (2001) Magnetic ordering in an organic polymer. Science 294:1503–1505. doi:10.1126/science.1065477
Shokrollahi H, Janghorban K (2007) Soft magnetic composite materials (SMCs). J Mater Process Technol 189:1–12. doi:10.1016/j.jmatprotec.2007.02.034
Reimers GW, Khalafalla SE (1972) Preparing magnetic fluids by a peptizing method. Can Min J
Massart R (1981) Preparation of aqueous magnetic liquids in alkaline and acidic media. IEEE Trans Magn 2:1247–1248
Montagne F, Mondain-Monval O, Pichot C, Mozzanega H, Elaïssari A (2002) Preparation and characterization of narrow sized (o/w) magnetic emulsion. J Magn Magn Mater 250:302–312
Dobrzański LA, Ziębowicz B, Drak M (2006) Mechanical properties and the structure of magnetic composite materials. J Achiev Mater Manuf Eng 18:79–82
Drak M, Ziębowicz B, Dobrzański LA (2008) Manufacturing of hard magnetic composite materials Nd–Fe–B. J Achiev Mater Manuf Eng 31:91–96
Dobrzanski LA, Drak M (2004) Structure and properties of composite materials with polymer matrix reinforced Nd–Fe–B hard magnetic nanostructured particles. J Mater Process Technol 157–158: 650–657. doi:10.1016/j.jmatprotec.2004.07.139
Ziebowicz B, Szewieczek D, Dobrzanski LA (2006) Structure and properties of the Fe73.5Cu1Nb3Si13.5B9 alloy powders, bound with polyethylene. J Mater Process Technol 175:457–462. doi:10.1016/j.jmatprotec.2005.04.044
ISO 527-2 (1993) Plastics—determination of tensile properties. Part 2: test conditions for moulding and extrusion plastics
Rocchiccioli-Deltcheff C, Franck R, Cabuil V, Massart R (1987) Surfacted ferrofluids: interactions at the surfactant-magnetic iron oxide interface. J Chem Res 5:126–127
Montagne F, Braconnot S, Mondain-Monval O, Pichot C, Elaïssari A (2003) Colloidal and physicochemical characterization of highly magnetic O/W magnetic emulsions. J Dispers Sci Technol 24:821–832. doi:10.1081/DIS-120025550
Montagne F, Mondain-Monval O, Pichot C, Elaïssari A (2006) Highly magnetic latexes from submicrometer oil in water ferrofluid emulsions. J Polym Sci A 44: 2642–2656. doi:10.1002/pola.21391
Tang Y, Lewin M, Pearce EM (2006) Effects of annealing on the migration behavior of PA6/Clay nanocomposites. Macromol Rapid Commun 27:1545–1549. doi:10.1002/marc.200600356
Hao J, Lewin M, Wilkie CA, Wang J (2006) Additional evidence for the migration of clay upon heating of clay–polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS). Polym Degrad Stab 91:2482–2485. doi:10.1016/j.polymdegradstab.2006.03.023
Tang Y, Lewin M (2007) Maleated polypropylene OMMT nanocomposite: annealing, structural changes, exfoliated and migration. Polym Degrad Stab 92:53–60. doi:10.1016/j.polymdegradstab.2006.09.013
Lewin M, Tang Y (2008) Oxidation–migration cycle in polypropylene-based nanocomposites. Macromolecules 41:13–17. doi:10.1021/ma702094e
Grassie N, Scott G (1985) Polymer degradation and stabilization. Cambridge University Press, Cambridge, pp 17–67
Móczó J, Pukánszky B (2008) Polymer micro and nanocomposites: structure, interactions, properties. J Ind Eng Chem 14:535–563. doi:10.1016/j.jiec.2008.06.011
Lima E, Brandl AL, Arelaro AD, Goya GF (2006) Spin disorder and magnetic anisotropy in Fe3O4 nanoparticles. J Appl Phys 99:083908. doi:10.1063/1.2191471
Marguiles DT, Parku FT, Spada FE, Goldman RS, Li J, Berkowitz A, Sinclair E (1996) Anomalous moment and anisotropy behavior in Fe3O4 films. Phys Rev B 53:9175–9178. doi:10.1103/PhysRevB.53.9175
Cullity BD (1972) Introduction to magnetic materials. Addison Wesley Publishing Company, Reading, MA, pp 290–310
Acknowledgments
The authors are grateful to Prof. Giovanni Camino at Politecnico di Torino for the scientific discussion and support provided during this research work.
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Carosio, F., Fina, A. & Coïsson, M. Polypropylene-based ferromagnetic composites. Polym. Bull. 65, 681–689 (2010). https://doi.org/10.1007/s00289-010-0282-1
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DOI: https://doi.org/10.1007/s00289-010-0282-1