Skip to main content
SpringerLink
Log in

Effect of the polymer matrix on the thermal behaviour of a furan-maleimide type adduct in the molten state

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Abstract

The effect of three different polymer matrices on the stability of the exo-adduct formed from N-Phenylmaleimide (PM) and furfuryl alcohol (FAl) toward retro Diels-Alder reaction was studied. First, a stereospecific synthesis of the exo-adduct was carried out at the condensed state and for a best understanding, its thermal properties was reported. The temperature of the rDA reaction of the exo-adduct in polyolefins (a low density polyethylene and a random copolymer of ethylene and glycidyl methacrylate) was found similar to the pure exo-adduct rDA reaction temperature. In a poly(vinylacetate)-g-polycaprolactone matrix this temperature was distinctly lower. In this last matrix, the reversibility of the rDA reaction was proved by the formation of the endo-adduct FAlPM during cooling.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Goussé C, Gandini A (1999) Polym Int 48:723

    Article  Google Scholar 

  2. Goussé C (1997) Ph.D Thesis INP Grenoble ‘‘Applications de la réaction de Diels-Alder aux polymères furaniques’’

  3. Tobia D, Harrison R, Phillips B, White TL, Di Mare M, Rickborn B (1993) J Org Chem 58:6701

    Article  CAS  Google Scholar 

  4. Rulisek L, Sebek P, Havlas Z, Hrabal R, Capek P, Svatos A (2005) J Org Chem 70:6295

    Article  CAS  Google Scholar 

  5. McElhanon JR, Zifer T, Kline SR, Wheeler DR, Loy DA, Jamison GM, Long TM, Rahimian K, Simmons BA (2005) Langmuir 21:3259

    Article  CAS  Google Scholar 

  6. Watanabe M, Yoshie N (2006) Polymer 47:4946

    Article  CAS  Google Scholar 

  7. Teramoto N, Arai Y, Shibata M (2006) Carbohydrate Polymers 64:78

    Article  CAS  Google Scholar 

  8. Liu YL, Chen YW (2007) Macromol Chem Phys 208:224

    Article  CAS  Google Scholar 

  9. Gheneim R, Perez-Berumen C, Gandini A (2002) Macromolecules 35:7246

    Article  CAS  Google Scholar 

  10. Goiti E, Huglin MB, Rego JM (2004) Eur Polym J 40:219

    Article  CAS  Google Scholar 

  11. Goiti E, Heatley F, Huglin MB, Rego JM (2004) Eur Polym J 40:1451

    Article  CAS  Google Scholar 

  12. Chang BTA, Dubois DA, Fan M, Gelles DL, Iyer SR, Mohindra S, Tutunjian PN, Wong PK, Wright WJ (1999) Electronic Components and Technology Conference, vol 49

  13. Kim TD, Luo J, Tian Y, Ka JW, Tucker NM, Haller M, Kang JW, Jen AKY (2006) Macromolecules 39:1676

    Article  CAS  Google Scholar 

  14. Chen X, Dam MA, Ono K, Mal A, Shen H, Nutt SR, Sheran K, Wudl F (2002) Science 295:1698

    Article  CAS  Google Scholar 

  15. Chen X, Wudl F, Mal AK, Shen H, Nutt SR (2003) Macromolecules 36:1802

    Article  CAS  Google Scholar 

  16. Liu YL, Hsieh CY (2006) J Polym Sci, Part A, Polym Chem 44:9058

    Google Scholar 

  17. Adachi K, Achimuthu AK, Chujo Y (2004) Macromolecules 37:9793

    Article  CAS  Google Scholar 

  18. Durmaz H, Dag A, Altintas O, Erdogan T, Hizal G, Tunca U (2007) Macromolecules 40:191

    Article  CAS  Google Scholar 

  19. Costanzo PJ, Beyer FL (2007) Macromolecules 40:3996

    Article  CAS  Google Scholar 

  20. Becquart F, Taha M, Zerroukhi A, Chalamet Y, Kaczun J, Llauro MF (2007) J Appl Polym Sci 105:2525

    Article  CAS  Google Scholar 

  21. Becquart F, Taha M, Zerroukhi A, Kaczun J, Llauro MF (2007) Eur Polym J 43:1549

    Article  CAS  Google Scholar 

  22. Mironov VA, Fadeeva TM, Stephanyants, Akhrem AA (1966) Russ Chem Bull 15:2142

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ingénierie des Matériaux Polymères, Laboratoire de Rhéologie des Matières Plastiques, UMR CNRS 5223, Faculté des Sciences, Université Jean Monnet, 23 rue du Docteur Paul Michelon, 42023, Saint-Etienne cedex 2, France

    Corinne Jegat & Nathalie Mignard

Authors
  1. Corinne Jegat
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nathalie Mignard
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Corinne Jegat or Nathalie Mignard.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jegat, C., Mignard, N. Effect of the polymer matrix on the thermal behaviour of a furan-maleimide type adduct in the molten state . Polym. Bull. 60, 799–808 (2008). https://doi.org/10.1007/s00289-008-0913-y

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-008-0913-y

Keywords

Search

Navigation