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Complex-radical copolymerization of N-vinyl pyrrolidone with isostructural analogs of maleic anhydride

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Abstract

Radical copolymerizations of N-vinyl-2-pyrrolidone (VP) with isostructural analogs of maleic anhydride (MA), such as citraconic anhydride (CA) and N-substituted maleimides [maleimide (MI), N-ethylmaleimide (EMI) and N-phenylmaleimide (PhMI)] were studied. Compositions of copolymers synthesized in a wide range of monomer feed ratios were determined by alkali titration (for anhydride copolymers), FTIR and 1H NMR spectroscopy using 1495 and 630 cm-1 (for VP-MI), 1289 and 1225 cm-1 (for VP-EMI) and 1050 and 3067 cm-1 (for VP-PhMI) analytical bands and integral areas of CH2 (pyrrolidone ring) and CH (MI), CH3 (EMI) and CH= (benzene ring in PhMI) groups, respectively. Electron-donor VP monomer was found to have substantially different reactivities in the radical copolymerization with MA, CA and N-substituted (H, C2H5 and phenyl) malemides as electron-acceptor comonomers. Effects of H-bonding and N→O=C coordination on the monomer reactivity ratios were evaluated. Tendency to alternation of the monomer pairs increases in the order of VP–MA > VP–CA > VP-MI > VP-PhMI > VP-EMI. Structure-thermal property-relationship for the synthesized copolymers was also studied.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering, Hacettepe University, Beytepe, 06800, Ankara, Turkey

    Güldem Güven & Zakir M. O. Rzaev

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  1. Güldem Güven
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  2. Zakir M. O. Rzaev
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Correspondence to Zakir M. O. Rzaev.

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Güven, G., Rzaev, Z.M.O. Complex-radical copolymerization of N-vinyl pyrrolidone with isostructural analogs of maleic anhydride . Polym. Bull. 60, 741–752 (2008). https://doi.org/10.1007/s00289-008-0909-7

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  • DOI: https://doi.org/10.1007/s00289-008-0909-7

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