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Organic/Inorganic Hybrid Composite Films from Polyimide and Organosilica: Effect of the Type of Organosilica Precursors

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Abstract

We report the influence of the type of organosilica precursors on the growth of organosilica domains and the interfacial interaction between polyimide (PI) and organosilica in PI/organosilica hybrid composite films. The organosilica precursors used are tetraethoxysilane (TEOS), triethoxy(ethyl)silane (TEES), and 1,2-bis(triethoxysilyl)ethane (BTSE). The hybrid composite films were prepared by thermal imization of the precursor films that were made via sol-gel process of the mixture of poly(4,4’-oxydianiline benzenetetracarboxamic acid) (PMDA-ODA PAA) and organosilica precursors. The hybrid composite films were characterized using Fourier transform infrared (FT-IR) spectra, 29Si cross polarization (CP) MAS-NMR spectra, field emission-scanning electron microscopy (FE-SEM), UV-visible spectra, small angle x-ray scattering (SAXS), dynamic mechanical analysis (DMA), and thermogravimetric analysis (TGA). The results showed that the TEES precursor was more pronounced in improving the interaction of corresponding organosilica with PI than other precursors.

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References

  1. Seino H, Mochizuki A, Ueda M (1999) J Polym Chem 37:3584

    Article  CAS  Google Scholar 

  2. Hedrick JL, Cha HJ, Miller RD, Yoon DY, Brown HR, Srinivasan S, Di Pietro R (1997) Macromolecules 30:8512

    Article  CAS  Google Scholar 

  3. Ha CS, Cho WJ (2000) Polym Adv Technol 11:145

    Article  CAS  Google Scholar 

  4. Huang JC, He CB, Xiao Y, Mya KY, Dai J, Siow YP (2003) Polymer 44:4491

    Article  CAS  Google Scholar 

  5. Wu KH, Chang TC, Yang JC, Chen HB (2001) J Appl Polym Sci 79:965

    Article  CAS  Google Scholar 

  6. XD, Zhong ZX, Jin G (2006) Macrmol Res 14(3):257

    Google Scholar 

  7. Jang YM, Seo JY, Chae KH, Yi M H (2006) Macrmol Res 14(3):300

    CAS  Google Scholar 

  8. Mathews AS, Kim I, Ha CS (2007) Macromol Res 15(2):114

    CAS  Google Scholar 

  9. Ogoshi T, Chujo Y (2005) Compos Interf 11:539

    Article  CAS  Google Scholar 

  10. Salomone JC (1996) Polymeric Materials Encyclopedia, CRC Press, New York, 8:6253

    Google Scholar 

  11. Takeichi T, Tanikawa M, Zuo M (1997) J Polym Sci Part A: Polym Chem 35:2395

    Article  CAS  Google Scholar 

  12. Wahab MA, Kim I, Ha CS (2003) Polymer 44:4705

    Article  CAS  Google Scholar 

  13. Choi SW, Kim YK, Kim I, Ha CS (2007) J Appl Polym Sci 103:2507

    Article  CAS  Google Scholar 

  14. Im JS, Lee JH, An SK, Song KW, Jo NJ, Lee JO, Yoshinaga KJ (2006) J Appl Polym Sci 100:2053

    Article  CAS  Google Scholar 

  15. Zhu ZK, Yin J, Cao F, Shang XY, Lu QH (2000) Adv Mater 12:1055

    Article  CAS  Google Scholar 

  16. Cornelius CJ, Marand E (2002) Polymer 43:2385

    Article  CAS  Google Scholar 

  17. Kioul A, Mascia L (1994) J Non-Cryst Solids 175:169

    Article  CAS  Google Scholar 

  18. Kim Y, Lee WK, Cho WJ, Ha CS, Ree M, Chang T (1997) Polym Int 43:129

    Article  CAS  Google Scholar 

  19. Choi SW (2006) M. S. Thesis, Pusan National University, Korea

  20. Mascia L, Kioul A (1995) Polymer 36:3649

    Article  CAS  Google Scholar 

  21. Ha Y, Kim Y, Ha CS (2008) Polymer Bulletin 59:833

    Article  CAS  Google Scholar 

  22. Chang CC, Chen WC (2002) Chem Mater 14:4242

    Article  CAS  Google Scholar 

  23. Srinivasan SA, Hedrick JL, Miller RD, Di Pietro R (1997) Polymer 38:3129

    Article  CAS  Google Scholar 

  24. Glaser RH, Wilkes GL, Bronnimann CE (1989) J Non-Cryst Solids 113:73

    Article  CAS  Google Scholar 

  25. Joseph R, Zhang S, Ford WT (1996) Macromolecules 29:1305

    Article  CAS  Google Scholar 

  26. Young SK, Jarrett WL, Mauritz KA (2002) Polymer 43:2311

    Article  CAS  Google Scholar 

  27. Kim Y (1996) Ph.D. Dissertation, Pusan National University, Korea

  28. Kim Y, Ree M, Chang T, Ha CS, Nunes TL, Lin LS (1995) J Polym Sci Part B: Polym Phys 33:2075

    Article  CAS  Google Scholar 

  29. Kim Y, Goh WH, Chang T, Ha CS, Ree M (2004) Adv Eng Mater 6:39

    Article  CAS  Google Scholar 

  30. Jeng U, Hsu CH, Lai YH, Chung WT, Shen HS, Lee HY, Song YF, Liang KS, Liu TL (2005) Macromol Res 13(6):506

    CAS  Google Scholar 

  31. Russel TP, Brown HR (1987) J Polym Sci: Part B: Polym Phys 25:1129

    Article  Google Scholar 

  32. Ochi M, Takahashi R (2001) J Polym Sci: Part B: Polym Phys 39:1071

    Article  CAS  Google Scholar 

  33. Kweon JO, Noh ST (2001) J Appl Polym Sci 81:2471

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, Pusan National University, 609-735, Busan, South Korea

    Minsoo Son, Jihan Lim, Il Kim & Chang-Sik Ha

  2. Advanced Materials and Application Research Lab., Korea Electrotechnology Research Institute, P.O.Box 20, 641-600, Changwon, South Korea

    Sewon Han & Donghee Han

  3. Organic Nanoelectronics Laboratory, Department of Chemical Engineering, Kyungpook National University, 702-701, Daegu, South Korea

    Youngkyoo Kim

Authors
  1. Minsoo Son
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  2. Sewon Han
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  3. Donghee Han
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  4. Youngkyoo Kim
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  5. Jihan Lim
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  6. Il Kim
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  7. Chang-Sik Ha
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Correspondence to Chang-Sik Ha.

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Son, M., Han, S., Han, D. et al. Organic/Inorganic Hybrid Composite Films from Polyimide and Organosilica: Effect of the Type of Organosilica Precursors . Polym. Bull. 60, 713–723 (2008). https://doi.org/10.1007/s00289-008-0904-z

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  • DOI: https://doi.org/10.1007/s00289-008-0904-z

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