Abstract
Blends of polyamide 6 with metallocene rubber as dispersed phase and grafted rubber as compatibilizer were prepared by two methods of compounding, extruder and internal mixer. Rheological measurements and morphological analysis were made in order to study the influence of compounding. The ternary blends with the same maleic anhydride content displayed similar rheological behaviour. On the other hand, the developed morphology is related to the compounding process and blend formulation. The better particle size distribution is achieved in both methods of compounding for blends with 20 wt% of EPDM-g-MA. The addition of EPDM-g-MA improves the mechanical properties compared to blends without compatibilizer. The results confirm that the mechanical properties are more influenced by the compounding process than by the blend composition.
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References
Burgisi G, Paternoster M, Peduto N, Saracen A (1997) J App Polym Sci 66:777
Cimmino S, Coppola F, D’Orazio L, Greco R, Maglio G, Malinconico M, Mancarella C, Martuscelli E, Ragosta G (1996) Polymer 27:1874
Oshinski AJ, Keskkula H, Paul DR (1996) Polymer 37:4891
Horiuchi S, Matchariyakul N, Yase K, Kitano T, Choi HK, Lee YM (1996) Polymer 37:3065
Horiuchi S, Matchariyakul N, Yase K, Kitano T, Choi HK, Lee YM (1997) Polymer 38:59
Orderkerk J, Groeninckx G (2002) Polymer 43:2219
Wilkinson AN, Clemens ML, Harding VM (2004) Polymer 45:5239
Huang JJ, Keskkula H, Paul DR (2004) Polymer 45:4203
Wang C, Su JX, Li J, Yang H, Zhang Q, Du RN, Fu Q (2006) Polymer 47:3197
Huang JJ, Keskkula H, Paul DR (2006) Polymer 47:639
Horiuchi S, Matchariyakul N, Yase K, Kitano T, Choi HK, Lee M (1997) Polymer 38:6317
González-Montiel A, Keskkula H, Paul DR (1995) Polymer 36:4587
Thomas S, Groeninckx G (1999) J App Polym Sci 71:1405
Thomas S, Groeninckx G (1999) Polymer 40:5799
Huang JJ, Keskkula H, Paul DR (2006) Polymer 47:624
Yu ZZ, Ou YC, Hu GH (1998) J App Polym Sci 69:1711
Tjong SC, Ke YC (1998) Eur Polym J 34:1565
Okada O, Keskkula H, Paul DR (2001) Polymer 42:8715
Okada O, Keskkula H, Paul DR (2000) Polymer 41:8061
López-Quintana S, Rosales C, Gobernado-Mitre I, Merino JC, Pastor JM (2004) Polymer 45:8041
Sundararaj U, Wacosko CW (1995) Macromolecules 28:2647
Lee JL, Han CD (1999) Polymer 40:6277
Bai SL, Wang GT, Hiver JM, G’Sell C (2004) Polymer 45:3063
López-Quintana S, Rosales C, Gobernado-Mitre I, Merino JC, Pastor JM (2005) PPS-21-Leipzig Oral Contr 3787
Wilkinson AN, Laugel L, Clemens ML, Harding VM, Marin M (1999) Polymer 40:4971
Ohlsson B, Hassander H, Törnell B (1998) Polymer 39:4715
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Gallego, R., García-López, D., López-Quintana, S. et al. Toughening of PA6/mEPDM Blends by two Methods of Compounding, Extruder and Internal Mixer: Rheological, Morphological and Mechanical Characterization . Polym. Bull. 60, 665–675 (2008). https://doi.org/10.1007/s00289-008-0902-1
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DOI: https://doi.org/10.1007/s00289-008-0902-1