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Preparation and properties of a new polytriazole resin made from dialkyne and triazide compounds and its composite

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Abstract

A new kind of polytriazole resins were prepared from a triazide and a dialkyne compounds and characterized. These resins can be cured at 80 °C. The curing process for a resin was traced by FT-IR. The glass transition temperature Tg and thermal decomposition temperature Td5 of the cured resin with the molar ratio of azide group to alkyne group [a]/[b]=1.0:1.0 reach 216 °C and 360 °C, respectively. The flexural strength of the cured resin and its glass fiber reinforced composite arrive at 183.6 MPa and 963.4 MPa, respectively. The resin would be a good candidate for the matrices of advanced composites.

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Authors and Affiliations

  1. The School of Material Science and Engineering, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, 200237, Shanghai, P.R. China

    Jianjun Tian, Liqiang Wan, Jianzhi Huang, Yanhong Hu & Farong Huang

  2. Shanghai Bureau of Astronautics, 200233, Shanghai, P.R. China

    Lei Du

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  1. Jianjun Tian
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  2. Liqiang Wan
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  3. Jianzhi Huang
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  4. Yanhong Hu
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  5. Farong Huang
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  6. Lei Du
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Correspondence to Farong Huang.

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Tian, J., Wan, L., Huang, J. et al. Preparation and properties of a new polytriazole resin made from dialkyne and triazide compounds and its composite . Polym. Bull. 60, 457–465 (2008). https://doi.org/10.1007/s00289-007-0878-2

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  • DOI: https://doi.org/10.1007/s00289-007-0878-2

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