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Non-isothermal Crystallization Kinetics of Poly (Ethylene Terephthalate)/Grafted Carbon Black Composite

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Summary

The grafted carbon black (GCB) was prepared by in-situ grafting low molecular weight compound on the surface of carbon black (CB) using a new technique. Poly(ethylene terephthalate)/grafted carbon black (PET/GCB) and poly(ethylene terephthalate)/ carbon black (PET/CB) composites were prepared by melt blending. The non-isothermal crystallization process of virgin Poly(ethylene terephthalate)(PET), PET/CB, and PET/GCB composites were investigated by differential scanning calorimetry (DSC), and the non-isothermal crystallization kinetics was analyzed using different approaches, i.e. modified Avrami equation, Ozawa equation and the method developed by Liu. The effective energy barrier ΔE of virgin PET, PET/CB, and PET/GCB composites were calculated using the differential iso-conversional method. All of the results showed that GCB and CB acted as nucleating agents and increased the crystallization rate of PET. Compared with CB, GCB was a more effective nucleator for PET.

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Authors and Affiliations

  1. Polymer Alloy Laboratory, School of Materials Science and Engineering, East China University of Science and Technology, 200237, Shanghai, P.R. China

    Xianhui Li, Weihong Guo, Qilin Zhou, Shiai Xu & Chifei Wu

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  1. Xianhui Li
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  2. Weihong Guo
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  3. Qilin Zhou
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  4. Shiai Xu
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  5. Chifei Wu
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Correspondence to Chifei Wu.

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Li, X., Guo, W., Zhou, Q. et al. Non-isothermal Crystallization Kinetics of Poly (Ethylene Terephthalate)/Grafted Carbon Black Composite. Polym. Bull. 59, 685–697 (2007). https://doi.org/10.1007/s00289-007-0798-1

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  • DOI: https://doi.org/10.1007/s00289-007-0798-1

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