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Synthesis and characterization of telechelic polymers obtained by micellar polymerization

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Summary

The synthesis, characterization and rheological properties in aqueous solution of two telechelic polymers of different structures and size are reported: they are water soluble polyacrylamides, hydrophobically modified with linear and di-substituted hydrophobic initiators. The polymers were prepared via free radical micellar polymerization. The results of static light scattering (SLS), showed similar weight-average molecular weights (Mw) in all of the synthesized polymers. No signal corresponding to the presence of the hydrophobic group of the initiator could be observed by 1H NMR; however, the presence of these hydrophobic groups was demonstrated using rheological measurements.

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Authors and Affiliations

  1. Centro de Investigación en Química Aplicada (CIQA), Blvd. Enrique Reyna #140, 25253, Saltillo, Coahuila, Mexico

    Ana C. Lara-Ceniceros, Claudia Rivera-Vallejo & Enrique J. Jiménez-Regalado

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  1. Ana C. Lara-Ceniceros
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  2. Claudia Rivera-Vallejo
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  3. Enrique J. Jiménez-Regalado
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Correspondence to Enrique J. Jiménez-Regalado.

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Lara-Ceniceros, A., Rivera-Vallejo, C. & Jiménez-Regalado, E. Synthesis and characterization of telechelic polymers obtained by micellar polymerization. Polym. Bull. 59, 499–508 (2007). https://doi.org/10.1007/s00289-007-0792-7

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  • DOI: https://doi.org/10.1007/s00289-007-0792-7

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