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Synthesis of the Optically Active Polymer Consisting of Chiral Phosphorus Atoms and p-Phenylene-ethynylene Units

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Summary

We successfully synthesized optically active polymer 4 by using chiral bisphosphine, (S,S)-1,2-bis(boranato(t-butyl)methylphosphino)ethane (S,S)-1, as a key building block. The structure of the polymer was characterized by 1H, 13C, and 31P NMR spectra. According to the CD spectra, the p-phenylene-ethynylene unit in the polymer main chain exhibited Cotton signals around the area of π-π* transition band.

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Authors and Affiliations

  1. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan

    Yasuhiro Morisaki, Yuko Ouchi, Kazuhiko Tsurui & Yoshiki Chujo

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  1. Yasuhiro Morisaki
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  2. Yuko Ouchi
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  3. Kazuhiko Tsurui
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  4. Yoshiki Chujo
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Correspondence to Yoshiki Chujo.

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Morisaki, Y., Ouchi, Y., Tsurui, K. et al. Synthesis of the Optically Active Polymer Consisting of Chiral Phosphorus Atoms and p-Phenylene-ethynylene Units. Polym. Bull. 58, 665–671 (2007). https://doi.org/10.1007/s00289-006-0703-3

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  • DOI: https://doi.org/10.1007/s00289-006-0703-3

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