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Three different types of quasi-model networks: synthesis by group transfer polymerization and characterization

Summary

Group transfer polymerization (GTP) chemistry was employed for the preparation of polymethacrylate networks of controlled structure (quasi-model networks) of three different types: (a) regular quasi-model networks, in which all polymer chains were linked at their ends, leaving, in principle, no free chain ends, (b) crosslinked star polymer quasi-model networks, in which star polymers were interlinked via half of their chains, letting the other half free (dangling), and (c) shell-crosslinked polymer quasi-model networks, in which the outer part of the network contained polymer arms (dangling chains). Combination of hydrophilic and hydrophobic monomers led to amphiphilic networks whose aqueous swelling behavior was characterized gravimetrically.

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References

  1. Dušek K (1967) Adv Polym Sci 5:113

    Google Scholar 

  2. Dušek K (1969) Adv Polym Sci 6:1

    Google Scholar 

  3. Tanaka T (1981) Sci Am 244:24

  4. Buchholz FL, Graham AT (1998) Eds. Modern Superabsorbent Polymer Technology, Wiley: New York

  5. Hild G (1998) Prog Polym Sci 23:1019

    Google Scholar 

  6. Simmons MR, Yamasaki EN, Patrickios CS (2000) Polymer 41:8523

    Google Scholar 

  7. Webster OW (1991) Science 251:887

    Google Scholar 

  8. Webster OW, Hertler WR, Sogah DY, Farnham WB, RajanBabu TV (1983) J Am Chem Soc 105:5706

    Google Scholar 

  9. Webster OW (2004) Adv Polym Sci 167:1

    Google Scholar 

  10. Steinbrecht K, Bandermann F (1989) Makromol Chem 190:2183

  11. Dicker IB, Cohen GM, Farnham WB, Hertler WR, Laganis ED, Sogah DY (1990) Macromolecules 23:4034

    Google Scholar 

  12. Hertler WR (1994) Macromol Symp 88:55

  13. Simmons MR, Yamasaki EN, Patrickios CS (2000) Macromolecules 33:3176

    Google Scholar 

  14. Triftaridou AI, Hadjiyannakou SC, Vamvakaki M, Patrickios CS (2002) Macromolecules 35:2506

    Google Scholar 

  15. Vamvakaki M, Hadjiyannakou SC, Loizidou E, Patrickios CS, Armes SP, Billingham NC (2001) Chem Mater 13:4738

  16. Vamvakaki M, Patrickios CS (2002) Chem Mater 14:1630

  17. Hadjichristidis N, Pitsikalis M, Pispas S, Iatrou H (2001) Chem Rev 101:3747

  18. Thurmond KB, Kowalewski T, Wooley KL (1996) J Am Chem Soc 118:7239

    Google Scholar 

  19. Patrickios CS, Georgiou TK (2003) Curr Opin Colloid Interface Sci 8:76

    Google Scholar 

  20. Siegel RA, Firestone BA (1988) Macromolecules 21:3254

    Google Scholar 

Download references

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Correspondence to Costas S. Patrickios.

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Triftaridou, A., Kafouris, D., Vamvakaki, M. et al. Three different types of quasi-model networks: synthesis by group transfer polymerization and characterization. Polym. Bull. 58, 185–190 (2007). https://doi.org/10.1007/s00289-006-0611-6

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  • DOI: https://doi.org/10.1007/s00289-006-0611-6

Keywords

  • EGDMA
  • Network Type
  • DMAEMA
  • Star Polymer
  • Hydrophobic Monomer