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Structural properties of poly(ether) macromonomer based hydrogels

Summary

The major part of the present work discusses the synthesis and the properties of a series of hydrogels obtained by free radical copolymerization of α,ω-methacryloyloxy poly(ethylene oxide) (PEO) or poly(1,3-dioxolane) (PDXL) macromonomers. The influence of several parameters such as macromonomer molar mass, comonomer concentration, type of solvent, and crosslinking concentration on the weight degree of equilibrium swelling, the uniaxial compression modulus and the thermodynamic interaction parameter was investigated systematically. Hydrogels whose elastic chains are constituted of a short central PDXL block surrounded by two hydrophilic PEO blocks were prepared according to the same strategy. PDXL is known to be sensitive to acidic degradation due to the presence of acetal groups. Therefore, once placed in acidic media (in water or in an organic solvent) network degradation occurred. The solid-state properties of the different PEO or PDXL co-networks were examined by DSC, and compared to those of linear PEO or PDXL chains and to those of homopolymeric PEO or PDXL networks.

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References

  1. Hild G (1998) Prog. Polym. Sci. 23: 1019

    Google Scholar 

  2. Naraghi K S, Sahli N, Franta E, Belbachir M and Lutz P J (2002) Polym. Int. 51: 912

    Google Scholar 

  3. Schmitt B, Alexandre E, Boudjema K and Lutz P J (2002) Macromol. Biosci. 2: 341

  4. Sahli N, Belbachir M and Lutz P J (2005) Macromol. Chem Phys. 206: 1257

    Google Scholar 

  5. Franta E, Lutz P J, Reibel L, Sahli N, Ould Kada S and Belbachir M (1994) Macromol. Symp. 85: 167

  6. Hild G (1997) Polymer 38: 3279

  7. Lutz P J, Picot C, Hild G and Rempp P (1977) Br. Polym. J. 9: 151

  8. Gnanou Y, Hild G and Rempp P (1984) Macromolecules 17: 945

  9. Buathong S, Isel F, Peruch F and Lutz P J (2004) Des. Monomers Polym. 7: 583

  10. Ashori S (1986) Macromolecules 19: 426

    Google Scholar 

  11. Patrickios C S and Georgiou T (2003) Curr. Opin. Colloid Interface Sci. 8: 76

  12. Erdodi G and Ivan B (2005) Chem. Mater. 16: 959

  13. Carrot G, Schmitt B and Lutz P J (1998) Polym. Bull. 40: 181

  14. De Clerq R R, Goethals E J (1992) Macromolecules 25: 1109

    Google Scholar 

  15. Naraghi K S, Meurer B and Lutz P J (2005) Macromol. Rapid Commun. 26: 537

    Google Scholar 

  16. Bailey F E and Callard R W (1959) Journal of Appied Polymer Science 1: 56

    Google Scholar 

  17. Benkhira A, Franta E, Raviso M and François J (1994) Macromolecules 27: 3963

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Correspondence to Pierre J. Lutz.

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Lutz, P. Structural properties of poly(ether) macromonomer based hydrogels. Polym. Bull. 58, 161–171 (2007). https://doi.org/10.1007/s00289-006-0594-3

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  • DOI: https://doi.org/10.1007/s00289-006-0594-3

Keywords

  • PMMA
  • Molar Mass
  • HEMA
  • Weight Degree
  • Crosslinking Point