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Novel conjugated polymers containing fluorene and 1-(2-benzothiazolyl)-3,5-diphenylpyrazoline Unit with Efficient Photoluminescence

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Summary

Novel conjugated polymers based on fluorene having 1-(2-benzothiazolyl)-3, 5-diphenylpyrazoline unit in the main chain were synthesized in good yields through Suzuki coupling reactions. All polymers were quite soluble in a variety of organic solvents. Transparent and uniform thin films of the polymers were obtained easily by casting or spin-coating from toluene solution. These polymers possessed satisfactory thermal stability. The polymers exhibited strong bluish-green photoluminescence in solution and green photoluminescence in the solid state.

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References

  1. Burrousghes JH, Bradey DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burns PL, Holmes AB (1990) Nature 347:539

    Google Scholar 

  2. Segura JL (1998) Acta Polym 49:319

    Google Scholar 

  3. Kraft A, Grimsdale AC, Holmes AB (1998) Angew Chem Int Ed 37:402

    Google Scholar 

  4. Friend RH, Gymer RW, Holmes AB , Burrousghes JH, Marks RN, Taliani C, Bradey DDC, Dos Satos DA, Bredas JL, Logdlund M, Salaneck WR (1999) Nature 397:121

    Google Scholar 

  5. Hou Q, Zhou QM, Zhang Y, Yang W, Yang RQ, Cao Y (2004) Macromolecules 37:6299

    Google Scholar 

  6. Jenekhe SA, Osaheni JA (1994) Science 265:765

    Google Scholar 

  7. Wang F, Luo J, Yang KX, Chen JW, Huang F, Cao Y (2005) Macromolecules 38:2253

    Google Scholar 

  8. Grell M, Bradley DDC, Inbasekaran M, Woo EP (1997) Adv Mater 9:798

  9. Hwang DH, Kim SK, Park MJ, Lee JH, Koo BW, Kang IN, Kim SH, Zyung TY (2004) Chem Mater 16:1298

  10. Jiang JX, Jiang CY, Yang W, Zhen HY, Huang F, Cao Y (2005) Macromolecules 38:4072

    Google Scholar 

  11. He Y, Gong S, Hattori R, Kanicki J (1999) Appl Phys Lett 74:2265

    Google Scholar 

  12. Yu W, Cao Y, Pei J, Huang W, Heeger AJ (1999) Appl Phys Lett 75:3270

    Google Scholar 

  13. Yu WL, Pei J, Cao Y, Huang W, Heeger AJ (1999) Chem Commun 1837

  14. Yang RQ, Tian RY, Yan JA, Zhang Y, Yang J, Hou Q, Yang W, Zhang C, Cao Y (2005) Macromolecules 38:244

    Google Scholar 

  15. Liu B, Yu W, Lai Y, Huang W (2000) Chem Commun 551

  16. Sainova D, Miteva T, Nothofer H, Scherf U, Glowacki I, Ulanski J, Fujikawa H, Neher D (2000) Appl Phys Lett 76:1810

    Google Scholar 

  17. Peng Q, Peng JB, Kang ET, Neoh KG, Cao Y (2005) Macromolecules 38:7292

    Google Scholar 

  18. Virgili T, Lidzey DG, Bradley DDC (2000) Adv Mater 12:58

  19. Kim JL, Cho JK, Hong SII (1999) Macromolecules 32:2065

  20. Kim JL, Kim JK, Cho HN, Kim DY, Kim CY, Hong SII (2000) Macromolecules 33:5508

    Google Scholar 

  21. Kim JL, Kim JK, Cho HN, Kim DY, Hong SII (2000) Synth Met 114:97

  22. Donat-Bouillud A, Blondin P, Ranger M, Bouchard J, Leclerc M (2000) Chem Mater 12:1931

  23. Beker S, Ego C, Grimsdale AC, List EJW, Marsitzky D, Pogantsch A, Setayesh S, Leising G, Mullen K (2002) Synth Met 125:73

  24. Zhan X, Liu Y, Wu X, Wang S, Zhu D (2002) Macromolecules 35:2529

    Google Scholar 

  25. Inbasekaran M, Woo EP, Wu W, Bernius MT (2000) WO 0046321

  26. Scherf U, List EJW (2002) Adv Mater 14:477

  27. Dorlars A, Schellhammer CW, Schroeder J (1975) Angew Chem Internat Edit 14:665

    Google Scholar 

  28. SanoT, Fujii T, Nishio Y, Hamada Y, Shibata K, Kuroki K (1995) Jpn J Appl Phys 34:3124

  29. Yan ZL, Wu SK (1994) Acta Phys-Chim Sin 10:954

    Google Scholar 

  30. Zhang XH, Wu SK, Gao ZQ, Lee CS, Lee ST, Kwong HL (2000) Thin Solid Films 371:40

    Google Scholar 

  31. Lu ZY, Jiang Q, Zhu WG, Xie MG, Hou YB, Chen XH, Wang ZJ (2000) Synth Met 111:465

  32. Coulson DR (1972) Inorg Synth 13:121

  33. Lu ZY, Zhu WG, Jiang Q, Xie MG (1999) Chin Chem Lett 10:679

    Google Scholar 

  34. Tokito M, Tanaka H, Noda K, Okada A, Taga Y (1997) Appl Phys Lett. 70:1929

  35. Eastman JW (1965) Photochem Photobiol 6:55

  36. Adams MJ, Highfield JG, Kirkbright GF (1977) Anal Chem 49:1850

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Correspondence to Ying Li.

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Zhang, H., Chen, H., Li, Y. et al. Novel conjugated polymers containing fluorene and 1-(2-benzothiazolyl)-3,5-diphenylpyrazoline Unit with Efficient Photoluminescence. Polym. Bull. 57, 121–128 (2006). https://doi.org/10.1007/s00289-006-0541-3

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  • DOI: https://doi.org/10.1007/s00289-006-0541-3

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