Skip to main content
SpringerLink
Log in

Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The reaction of the carboxymethyl cellulose sodium salt (Na-CMC) (degrees of substitution (DS) = 1.2) with N-hydroxysuccinimide (Su-OH) in the presence of 1-hydroxybenzotriazole and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) was carried out in water to obtain the Su-OH ester of carboxymethyl cellulose, Su-CMC, with the DS values of 0.19 – 1.04. N-Allylcarbamoylmethyl cellulose (Allyl-CMC), which was prepared from the reaction of Su-CMC with an excess amount of allylamine, was crosslinked by UV-irradiation. In addition, the photocrosslinked Allyl-CMC film was swollen with water to form a hydrogel having a relatively high water-swelling property, e.g., the degree of swelling (ds) was ca. 360% for Allyl-CMC with the DS of 0.93.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wagenknecht W, Nehls I, Philipp B (1992) Carbohydr Res 237:211.

  2. Edgar KJ, Buchanan CM, Debenham JS, Rundquist PA, Seiler BD, Shelton MC, Tindall D (2001) Prog Polym Sci 26:1605.

    Google Scholar 

  3. McCormick CL, Dawsey TR (1990) Macromolecules 23:3606.

    Google Scholar 

  4. McCormick CL, Callais PA (1987) Polymer 28:2317.

    Google Scholar 

  5. Isogai A, Ishizu A, Nakano J, Eda S, Kato K (1985) Carbohydr Res 138:99.

  6. Isogai A, Ishizu A, Nakano J (1986) J Appl Polym Sci 31:341.

    Google Scholar 

  7. Isogai A, Ishizu A, Nakano J (1984) J Appl Polym Sci 29:2097.

  8. Mornann W, Michel U (2002) Carbohydr Polym 50:201.

  9. Hearon WM, Hiatt GD, Fordyce CR (1943) J Am Chem Soc 65:829.

    Google Scholar 

  10. Heinze T, Liebert T (2001) Prog Polym Sci 26:1689.

    Google Scholar 

  11. Olaru N, Olaru L, Stoleriu A, Timpu D (1998) J Appl Polym Sci 67:481.

    Google Scholar 

  12. Barbucci R, Leone G, Vecchiullo A (2004) J Biomater Sci Polymer Edn 15:607.

    Google Scholar 

  13. Carrigan SD, Scott G, Tabrizian M (2005) Langmuir 21:5966.

    Google Scholar 

  14. Hara K, Iida M, Yano K, Nishida T (2004) Colloid Surf B: Biointerfaces 38:227.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Division of Biotechnology and Macromolecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, 060-8628, Japan

    Xiande Shen, Yoshikazu Kitajyo, Qian Duan, Toshifumi Satoh & Toyoji Kakuchi

  2. National Institute of Advanced Industrial Science and Technology (AIST), Sapporo, 062-8517, Japan

    Atsushi Narumi & Harumi Kaga

  3. MACROTEC Co., Sapporo, 062-8517, Japan

    Noriaki Kaneko

Authors
  1. Xiande Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yoshikazu Kitajyo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Qian Duan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Atsushi Narumi
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Harumi Kaga
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Noriaki Kaneko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Toshifumi Satoh
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Toyoji Kakuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Toyoji Kakuchi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shen, X., Kitajyo, Y., Duan, Q. et al. Synthesis and Photocrosslinking Reaction of N-Allylcarbamoylmethyl Cellulose Leading to Hydrogel. Polym. Bull. 56, 137–143 (2006). https://doi.org/10.1007/s00289-005-0482-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00289-005-0482-2

Keywords

Search

Navigation